{"title":"The cyclobutene diester approach to alkyl citrate natural products","authors":"Nikolai P. Rossouw, Mark A. Rizzacasa","doi":"10.1071/ch24088","DOIUrl":null,"url":null,"abstract":"<p>This review outlines the synthesis of alkyl citrate natural products using cyclobutene diester precursors. The approach is efficient and stereoselective and provides the correct oxidation state of the citrate core of these compounds. The synthesis of a number of alkyl citrates along with some higher oxidised members of this family is detailed.</p>","PeriodicalId":8575,"journal":{"name":"Australian Journal of Chemistry","volume":null,"pages":null},"PeriodicalIF":1.0000,"publicationDate":"2024-08-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Australian Journal of Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1071/ch24088","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
This review outlines the synthesis of alkyl citrate natural products using cyclobutene diester precursors. The approach is efficient and stereoselective and provides the correct oxidation state of the citrate core of these compounds. The synthesis of a number of alkyl citrates along with some higher oxidised members of this family is detailed.
期刊介绍：
Australian Journal of Chemistry - an International Journal for Chemical Science publishes research papers from all fields of chemical science. Papers that are multidisciplinary or address new or emerging areas of chemistry are particularly encouraged. Thus, the scope is dynamic. It includes (but is not limited to) synthesis, structure, new materials, macromolecules and polymers, supramolecular chemistry, analytical and environmental chemistry, natural products, biological and medicinal chemistry, nanotechnology, and surface chemistry.
Australian Journal of Chemistry is published with the endorsement of the Commonwealth Scientific and Industrial Research Organisation (CSIRO) and the Australian Academy of Science.
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