Bioenergy and Value-Added Chemicals Derived Through Electrocatalytic Upgradation of Biomass: a Critical Review

IF 3.1 3区 工程技术 Q3 ENERGY & FUELS BioEnergy Research Pub Date : 2024-08-16 DOI:10.1007/s12155-024-10797-6
Mudasir Akbar Shah, Wasif Farooq, Tasrin Shahnaz, Muthumariappan Akilarasan
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Abstract

Electrocatalytic upgradation of biomass for chemicals and energy production is an emerging approach to address the environmental issues related to chemicals and energy production. If coupled with renewable energy, this approach will further enhance the sustainability goals for the future energy and chemical sector. This work critically reviews the progress on oxidative and reductive electrocatalytic upgrading of biomass-derived chemicals such as glycerol, sorbitol, levulinic acid, 5-hydroxymethylfurfural, furfural, and bio-oil to value-added products, including 2.5-dimethyl tetrahydrofuran, 2.5-dihydroxy methyl tetrahydro furan, 2-hydroxymethyl-5-(methyl amino methyl) furan, and 2,5-furan dicarboxylic acid with simulations production of hydrogen (H2) energy. The role of the mediator in electrocatalytic upgradation serves as a high-efficiency catalytic platform for oxidation and reduction reactions. Pd and Ru exhibit promising attributes such as durability and superior electrocatalytic hydrogenation performance. Additionally, this review discusses various methods for enhancing biofuel through a multitude of approaches, such as hydrocracking, hydrotreatment, supercritical fluid processing, steam reforming, catalytic cracking, esterification, emulsification, hydrodeoxygenation, and electrocatalytic hydrogenation. Techno-economic assessment of electrocatalytic conversion of biomass to chemicals and energy are explored to identify the key contributing factors toward the economic viability of electrocatalytic upgradation of biomass for chemical and energy. Finally, research gaps are identified for further work along with economic assessment of electrocatalytic upgradation of biomass technology with and without integration of renewable energy.

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生物质电催化升级产生的生物能源和增值化学品:重要综述
生物质电催化升级用于化学品和能源生产是解决化学品和能源生产相关环境问题的一种新兴方法。如果与可再生能源相结合,这种方法将进一步提高未来能源和化工行业的可持续发展目标。本研究对生物质衍生化学品(如甘油、山梨醇、乙酰丙酸、5-羟甲基糠醛、糠醛和生物油)氧化和还原电催化升级为高附加值产品(包括 2.5-二甲基四氢呋喃、2.5-二羟甲基四氢呋喃、2-羟甲基-5-(甲基氨基甲基)呋喃和 2,5-呋喃二羧酸,并模拟产生氢(H2)能。介质在电催化升级中的作用是作为氧化和还原反应的高效催化平台。Pd 和 Ru 具有耐久性和优异的电催化加氢性能等良好特性。此外,本综述还讨论了通过加氢裂化、加氢处理、超临界流体处理、蒸汽重整、催化裂化、酯化、乳化、加氢脱氧和电催化加氢等多种方法提高生物燃料的各种方法。探讨了生物质电催化转化为化学品和能源的技术经济评估,以确定生物质电催化升级用于化学品和能源的经济可行性的关键因素。最后,确定了进一步工作的研究差距,并对整合和不整合可再生能源的生物质电催化升级技术进行了经济评估。
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来源期刊
BioEnergy Research
BioEnergy Research ENERGY & FUELS-ENVIRONMENTAL SCIENCES
CiteScore
6.70
自引率
8.30%
发文量
174
审稿时长
3 months
期刊介绍: BioEnergy Research fills a void in the rapidly growing area of feedstock biology research related to biomass, biofuels, and bioenergy. The journal publishes a wide range of articles, including peer-reviewed scientific research, reviews, perspectives and commentary, industry news, and government policy updates. Its coverage brings together a uniquely broad combination of disciplines with a common focus on feedstock biology and science, related to biomass, biofeedstock, and bioenergy production.
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