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Ecosystem Carbon and Nutrient Balances in Short-Rotation Hybrid Aspen Coppice Under Different Thinning Methods 不同疏伐方法下短旋杂交杨树林的生态系统碳和养分平衡
IF 3.6 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-06-29 DOI: 10.1007/s12155-024-10780-1
Reimo Lutter, Heiki Hepner, Arvo Tullus, Hyungwoo Lim, Tea Tullus, Eele Õunapuu-Pikas, Reeno Sopp, Marju Kaivapalu, Kristjan Täll, Katri Ots, Hardi Tullus

Coppice plantations have gained a high interest for biofuel production and carbon uptake in short rotation cycles. There is a limited knowledge how such intensive coppice management affects soil fertility and nutrients supply to maintain carbon sink. We studied ecosystem carbon and nutrients balance and allocation during a 5-year period in hybrid aspen coppice under different thinning methods in hemiboreal Estonia. The benchmark value for the changes was defined before the coppice emerged after the clear-cut of the previously planted hybrid aspen plantation. The studied systematical thinning treatments were as follows: corridor thinning with removal of 67% of the trees (CT), cross-corridor thinning with removal of 89% of the trees (CCT), and unthinned (UT) coppice. The UT and CT treatments resulted in a positive carbon balance at the ecosystem level. In all treatments, a decrease of soil acidity, organic C, total N, K, Mg and Mn contents, and an increase of soil Cu and B contents were observed in the 0–20-cm deep layer. The concentrations of leaf N, P, and K were higher in UT than in the two thinning treatments, indicating that the aspens had not entirely recovered from the changed root to shoot ratio 2 years after thinning, whereas the leaf mass fraction of medium- and small-sized trees had already increased. Bioenergy harvest from the UT site in a 5-year rotation would cause 5–18% removal of NPK from the total ecosystem pool. Overall, hybrid aspen coppice showed positive ecosystem carbon balance after the first 5-year period; however, further monitoring of soil properties is needed as we found decrease of soil organic C and nutrients concentrations in short term.

Graphical Abstract

矮林种植在短轮作周期内生产生物燃料和碳吸收方面获得了高度关注。人们对这种密集型灌木林管理如何影响土壤肥力和养分供应以保持碳汇的了解十分有限。我们研究了爱沙尼亚半干旱地区不同疏伐方法下杂交杨树灌丛 5 年的生态系统碳和养分平衡与分配情况。变化的基准值是在以前种植的杂交杨树人工林被砍伐后出现灌木丛之前确定的。研究的系统疏伐处理如下:清除 67% 树木的走廊疏伐(CT)、清除 89% 树木的交叉走廊疏伐(CCT)和未疏伐(UT)的矮林。UT和CT处理在生态系统层面上实现了正的碳平衡。在所有处理中,0-20 厘米深层的土壤酸度、有机碳、全氮、全钾、全镁和全锰含量都有所下降,而土壤中的铜和硼含量则有所上升。UT处理的叶片N、P和K含量高于两种疏伐处理,这表明在疏伐2年后,杨树尚未完全从根芽比的变化中恢复过来,而中小型树木的叶片质量分数已经增加。在 5 年轮伐期中,从UT地点收获生物能源将导致生态系统总池中的氮磷钾减少 5-18%。总体而言,杂交杨树灌木林在第一个 5 年期后显示出积极的生态系统碳平衡;然而,由于我们发现土壤有机碳和养分浓度在短期内有所下降,因此需要进一步监测土壤特性。
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引用次数: 0
Anaerobic Co-digestion of Expired Dairy Products and Synthetic Domestic Wastewater: Effect on Methane Potential in Batch Reactors 过期乳制品和合成生活废水的厌氧协同消化:对间歇式反应器中甲烷潜力的影响
IF 3.6 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-06-22 DOI: 10.1007/s12155-024-10778-9
Danieli Fernanda Canaver Marin, Caroline Varella Rodrigues, Romário Pereira de Carvalho Júnior, Sandra Imaculada Maintinguer

Substantial amounts of expired dairy products (EDP) are generated due to their high perishability. These wastes are rich in organic matter, and their landfill disposal negatively impacts the environment. An alternative to reducing and recovering this waste would be to use it as a substrate in anaerobic digestion (AD) to produce biogas. This study investigated methane (CH4) production using different concentrations of EDP co-digested with synthetic domestic wastewater (SDW). Five anaerobic batch reactors (1000 mL) were assembled with different concentrations of EDP in SDW (500 mL working volume), namely (1) 0%, (2) 5.0%, (3) 7.5%, (4) 10.0%, and (5) 15.0% (v/v). COD removals were 81%, 84%, 80%, 89%, and 14% for assays 1 to 5, respectively. The cumulative CH4 productions were (mL/L) 717, 3354, 5327, 6584, and 1156 for assays 1 to 5, respectively. Assay 5 (15% EDP) was inhibited by volatile fatty acid (VFA) accumulation. However, assays 2, 3, and 4 (with 5.0–10.0% EDP) showed high CH4 yields (mLCH4/gVSadd) of 319, 333, and 317, respectively, demonstrating the feasibility of anaerobic co-digestion of EDP with SDW. In assays 3 and 4, a similar archaeal community structure was observed, dominated by the genera Methanosaeta, Methanolinea, Methanoregula, and Methanobacterium. In assay 2, the archaeal community demonstrated lower dominance due to insufficient substrate adaptation. This study confirms the viability of using EDP in AD systems to generate CH4, suggesting future sustainable applications for this residue.

Graphical Abstract

由于过期乳制品极易变质,因此会产生大量过期乳制品(EDP)。这些废物富含有机物,填埋处理会对环境造成负面影响。减少和回收这些废物的另一种方法是将其用作厌氧消化(AD)的基质,以产生沼气。本研究调查了使用不同浓度的 EDP 与合成生活废水(SDW)共同消化产生甲烷(CH4)的情况。在 SDW(500 mL 工作容积)中加入不同浓度的 EDP 后,组装了五个厌氧间歇反应器(1000 mL),分别为 (1) 0%、(2) 5.0%、(3) 7.5%、(4) 10.0% 和 (5) 15.0%(v/v)。检测 1 至 5 的 COD 去除率分别为 81%、84%、80%、89% 和 14%。化验 1 至 5 的累积 CH4 产量分别为(毫升/升)717、3354、5327、6584 和 1156。试验 5(15% EDP)受到挥发性脂肪酸(VFA)积累的抑制。然而,试验 2、3 和 4(EDP 含量为 5.0-10.0%)的 CH4 产率(mLCH4/gVSadd)分别高达 319、333 和 317,证明了厌氧协同消化 EDP 和 SDW 的可行性。在试验 3 和试验 4 中,观察到了类似的古菌群落结构,主要是 Methanosaeta、Methanolinea、Methanoregula 和 Methanobacterium 属。在试验 2 中,由于对底物的适应性不足,古菌群落的优势度较低。这项研究证实了在厌氧消化(AD)系统中使用 EDP 生成 CH4 的可行性,为这种残留物未来的可持续应用提供了建议。
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引用次数: 0
Advancements in Valorization of Food Waste Resources by Microalgae for Sustainable Biorefinery Production 利用微藻对厨余资源进行价值评估以促进可持续生物精炼生产的研究进展
IF 3.6 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-06-20 DOI: 10.1007/s12155-024-10777-w
Nang Yee Mon Htoo, Chayakorn Pumas, Sirasit Srinuanpan, Phei Er Kee, John Chi-Wei Lan, Jun Wei Lim, Sudhir K. Upadhyay, Kuan Shiong Khoo

The increasing global population has led to a significant accumulation of food waste. It is important to focus on reducing food waste instead of disposal methods like landfilling and incineration, which have severe environmental impacts. Upcycling food waste has emerged as an effective strategy for repurposing discarded food into higher-value products. However, concerns about food safety and public acceptance of products directly produced from food waste persist. Consequently, there is growing interest in utilizing food waste rich in moisture and biodegradable organic compounds as a potential medium for cultivating microalgae. This review article examines the utilization of food waste as a culture medium for microalgae cultivation and the methods for treating food waste to enhance its nutrient content. Additionally, it discusses the influence of nutrients such as carbon, nitrogen, and phosphorus on microalgae growth and external factors such as pH and light intensity. The article also addresses the innovation of the food supply chain from environmental, social, and economic perspective, along with food safety and public acceptability concerns. Furthermore, it explores the legislative issues surrounding products derived from food waste and the end use of microalgae biomass produced from food waste. Overall, this review provides insight into the potential of microalgae cultivation using food waste, serving as a platform towards the realization of a circular bioeconomy.

全球人口的不断增长导致了食物垃圾的大量积累。重要的是要重视减少食物垃圾,而不是采用填埋和焚烧等对环境有严重影响的处理方法。对食物垃圾进行升级再造已成为一种有效的策略,可将废弃食物重新加工成价值更高的产品。然而,人们对食品安全和公众对直接利用厨余生产的产品的接受程度仍然存在担忧。因此,人们对利用富含水分和可生物降解有机化合物的厨余作为培养微藻的潜在媒介越来越感兴趣。这篇综述文章探讨了利用厨余作为培养微藻的培养基,以及处理厨余以提高其营养成分的方法。此外,文章还讨论了碳、氮、磷等营养物质对微藻类生长的影响,以及 pH 值和光照强度等外部因素。文章还从环境、社会和经济角度探讨了食品供应链的创新,以及食品安全和公众接受度问题。此外,文章还探讨了与厨余产品相关的立法问题,以及从厨余生产的微藻生物质的最终用途。总之,本综述深入探讨了利用厨余培养微藻的潜力,为实现循环生物经济提供了一个平台。
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引用次数: 0
Economical and Facile Synthesis of Monolignols 经济简便地合成单木质素
IF 3.6 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-06-19 DOI: 10.1007/s12155-024-10779-8
Alexis Dell, Mallorie Keith, Emily Y. Zhu, James Pence, Qizheng Duan, Sabiha Sultana, Yimin Zhu

Monolignols are efficiently synthesized from the corresponding cheap and readily available cinnamic acids through a borohydride reduction of the derived mixed carbonic anhydrides. Judicious choices of the reaction conditions allow for removal of the byproducts by aqueous workup and give the products cleanly in high yields.

通过对衍生的混合碳酸酐进行硼氢化还原,可以从相应的廉价且容易获得的肉桂酸中高效合成单木质素。通过对反应条件的明智选择,可以通过水处理去除副产物,并以高产率获得清洁的产品。
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引用次数: 0
Production of Ethanol from Green Coconut Fiber by Integrating Cloud Point Extraction and Simultaneous Saccharification and Fermentation 利用云点萃取和同步糖化发酵技术从绿椰子纤维中生产乙醇
IF 3.6 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-06-17 DOI: 10.1007/s12155-024-10776-x
Carlos Eduardo de Araújo Padilha, Habila Yusuf Thomas, Mariza Gabryella Brito dos Santos, José Dário Silva Fidelis, Lucas Felipe Simões Silva, Jadna Lúcia de Freitas Silva, Gleyson Batista de Oliveira, Karina Soares do Bonfim, Everaldo Silvino dos Santos, Domingos Fabiano de Santana Souza

The fermentation of whole slurry favors the increase in ethanol titers and minimizes water consumption. However, inhibitors accumulate in the liquid fraction pretreatment, reducing fermentation performance. In order to find a way out, the present study proposed an integration between cloud point extraction (CPE) and ethanol production using fiber of green coconut (GCF) as substrate. Triton X-114 was used to detoxify the liquid fraction from acid pretreatment, and optimal operating conditions were obtained by mathematical modeling. The effects of the residual surfactant from the dilute phase of CPE were analyzed in cellulase adsorption tests, enzymatic hydrolysis, and fermentation of acid-pretreated GCF. CPE promoted high removal of furans (86.23–100%) and phenolic compounds (22.79–75.15%), while the sugars migrated to the dilute phase. A neural network model coupled with a genetic algorithm obtained an optimal condition of 2.38% Triton X-114, temperature of 42 °C, pH of 4.3, and 0.55% sodium chloride. The incubation with the CPE dilute phase increased the residual activity from 25.1 to 50.1% and increased the cellulosic conversion from 32.28 to 41.15%. CPE-saccharification and simultaneous fermentation integration boosted the ethanol production to 12.40 g/L, while the untreated whole slurry reached only 6.29 g/L. Because of these results, the CPE emerges as a promising alternative to favor the full use of sugars from lignocellulosic biomass.

全浆发酵有利于提高乙醇滴度,并最大限度地减少耗水量。然而,抑制剂会在液体部分预处理中积累,降低发酵性能。为了寻找出路,本研究提出了一种以青椰子纤维(GCF)为基质的浊点萃取(CPE)与乙醇生产相结合的方法。采用 Triton X-114 对酸预处理后的液体馏分进行解毒,并通过数学建模获得最佳操作条件。在纤维素酶吸附试验、酶水解和酸预处理 GCF 发酵过程中,分析了 CPE 稀释相中残留表面活性剂的影响。CPE 对呋喃(86.23%-100%)和酚类化合物(22.79%-75.15%)的去除率较高,而糖类则迁移到稀释相中。神经网络模型与遗传算法相结合,得出了 2.38% 的 Triton X-114、42 °C 的温度、4.3 的 pH 值和 0.55% 的氯化钠的最佳条件。使用 CPE 稀释相进行培养后,剩余活性从 25.1% 提高到 50.1%,纤维素转化率从 32.28% 提高到 41.15%。CPE 糖化与同步发酵的结合使乙醇产量提高到 12.40 克/升,而未经处理的全浆仅为 6.29 克/升。由于这些结果,CPE 成为了有利于充分利用木质纤维素生物质中糖的一种有前途的替代方法。
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引用次数: 0
Single-Pass, Single-Stream Harvest of Corn Grain and Stover: a Comparison of Two Harvest Methods 玉米粒和秸秆的单程单流收割:两种收割方法的比较
IF 3.6 3区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-06-13 DOI: 10.1007/s12155-024-10775-y
A. Hemmelgarn, K. Shinners, A. J. Timm, M. Digman
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引用次数: 0
Evaluation of the Energy Potential of Agro-industrial Waste from Mangifera indica L. in Zamora, Mexico: Perspectives for the Management of Solid and Liquid Biofuels 墨西哥萨莫拉州芒果树农工业废弃物的能源潜力评估:固体和液体生物燃料的管理前景
IF 3.6 3区 工程技术 Q1 Agricultural and Biological Sciences Pub Date : 2024-05-24 DOI: 10.1007/s12155-024-10774-z
Luis Bernardo López-Sosa, Gustavo Alberto Santibáñez-Rocha, Mario Morales-Máximo, Ricardo González-Carabes, José Guadalupe Rutiaga-Quiñones, Carlos Alberto García Bustamante, Luis Fernando Pintor-Ibarra, Ismael Santos Ramos, Cecilia Irene Villaseñor Reyes, María del Carmen Rodríguez Magallón, Saúl Leonardo Hernández Trujillo

A study of the energy potential from agro-industrial waste of Mangifera indica L. in the city of Zamora, Michoacán is presented, considering its use through solid biofuels. This research is composed of three stages: (a) the qualitative and quantitative diagnosis of the waste disposal of M. indica, spatiotemporally (b) the physicochemical characterization of the waste collected from 14 processing companies using characterization techniques, as well as proximal analysis of the moisture content, ash, volatiles, fixed carbon, and calorific value, and (c) estimation of the energy potential to spatially and temporally define the final energy disposition and possible use of the analyzed waste. The results show the ash content of mango residues below 3.5%, while the volatile material was 82.9%, the fixed carbon content was below 17%, and the polymeric compounds showed 27.24% cellulose, 10.46% for hemicellulose, and for lignin 5.78%. The presence of carbon was also identified in the order of 44.61%, hydrogen in 6.53%, oxygen in 48.11%, nitrogen of 0.74%, and the sulfur recorded was below the range of 0.01%. The calorific value was estimated from 17.5 to 19.28 MJ/kg; the available energy potential on the order of 0.5 TJ/day for 4 months. This proposal not only shows a case study of the bioenergy potential available, but it can also encourage addressing future research related to the use and valuation of agro-industrial waste, which, like in the Zamora region, there are many more in Mexico, and they are so diverse and productive that the energy potential is relevant.

本研究介绍了米却肯州萨莫拉市芒果树农用工业废弃物的能源潜力,并考虑通过固体生物燃料加以利用。这项研究包括三个阶段:(a)对芒果废弃物处理进行定性和定量的时空诊断;(b)使用表征技术对从 14 家加工企业收集的废弃物进行物理化学表征,以及对含水量、灰分、挥发物、固定碳和热值进行近似分析;以及(c)估算能源潜力,以便从空间和时间上确定最终的能源处置以及分析废弃物的可能用途。结果显示,芒果残渣的灰分含量低于 3.5%,挥发性物质含量为 82.9%,固定碳含量低于 17%,高分子化合物中纤维素含量为 27.24%,半纤维素含量为 10.46%,木质素含量为 5.78%。碳含量为 44.61%,氢含量为 6.53%,氧含量为 48.11%,氮含量为 0.74%,硫含量低于 0.01%。热值估计为 17.5 至 19.28 兆焦/千克;4 个月的可用能源潜力约为 0.5 太焦耳/天。这项建议不仅展示了生物能源潜力的案例研究,而且还可以鼓励今后开展与农业工业废弃物的利用和评估有关的研究。
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引用次数: 0
Machine Learning Approach for Predicting Hydrothermal Liquefaction of Lignocellulosic Biomass 预测木质纤维素生物质热液液化的机器学习方法
IF 3.6 3区 工程技术 Q1 Agricultural and Biological Sciences Pub Date : 2024-05-24 DOI: 10.1007/s12155-024-10773-0
Tossapon Katongtung, Sanphawat Phromphithak, Thossaporn Onsree, Nakorn Tippayawong
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引用次数: 0
Fermentation of Rice Straw and Its Hydrolysate with Sludge for Ethanol Production 用污泥发酵稻草及其水解物以生产乙醇
IF 3.6 3区 工程技术 Q1 Agricultural and Biological Sciences Pub Date : 2024-05-18 DOI: 10.1007/s12155-024-10771-2
Ji-Liang Lü, Zhen Wang, Min Tao, Han Zheng, Chao-Gang Lou, Shanshan Yang, Xianli Liu

Rice straw hydrolysate produced in rice straw pretreatment, comprising a lot of fermentable sugars, is generally released into the environment. This not only causes environment pollution but also wastes fermentable sugars from rice straw. To alleviate environment impact, maximize ethanol production from rice straw, and reduce the cost of ethanol production, rice straw hydrolysate and NaOH-pretreated rice straw were converted to ethanol using ethanol-type fermentation and simultaneous saccharification and fermentation (SSF) by sludge. Meanwhile, microbial community in sludge was analyzed to find the relationship between ethanol production and microbial community succession during ethanol-type fermentation and SSF. Under the optimal condition of the COD, pH and oxidation–reduction potential (ORP) value of rice straw hydrolysate with 6280.56 mg/L, 6.7, and − 42 mV, ethanol-type fermentation with the sludge of 15 g obtained the highest ethanol concentration (8.34 g/L) and the highest COD removal rate (54.83%). For SSF, the maximum ethanol concentration (3.75 g/L) produced by pretreated rice straw and sludge from ethanol-type fermentation with the sludge of 15 g was higher than that (2.61 g/L) generated by pretreated rice straw and sludge from ethanol-type fermentation with the sludge of 22.5 g. This indicated that sludge from ethanol-type fermentation with the sludge of 15 g more efficiently converted rice straw to ethanol than sludge from ethanol-type fermentation with the sludge of 22.5 g. Microbial community analysis suggested that ethanol production had a negative correlation with the relative abundance changes of Bacteroidetes, when the relative abundance of Firmicutes constantly rose in ethanol-type fermentation and SSF. This study provides a scientific basis for maximizing ethanol production from rice straw by microbial regulation in sludge, which could further reduce the cost of ethanol production.

稻草预处理过程中产生的稻草水解物含有大量可发酵糖,通常会被排放到环境中。这不仅会造成环境污染,还会浪费稻草中的可发酵糖。为了减轻对环境的影响,最大限度地利用稻草生产乙醇,并降低乙醇生产成本,利用乙醇型发酵和污泥同步糖化发酵(SSF)将稻草水解物和 NaOH 预处理过的稻草转化为乙醇。同时,对污泥中的微生物群落进行了分析,以找出乙醇型发酵和糖化发酵过程中乙醇产量与微生物群落演替之间的关系。在 COD、pH 和氧化还原电位(ORP)值分别为 6280.56 mg/L、6.7 和 - 42 mV 的最佳条件下,使用 15 克污泥进行乙醇型发酵可获得最高的乙醇浓度(8.34 g/L)和最高的 COD 去除率(54.83%)。就 SSF 而言,经预处理的稻草和 15 克污泥乙醇发酵产生的乙醇浓度最高(3.75 克/升),高于经预处理的稻草和 22.5 克污泥乙醇发酵产生的乙醇浓度最高(2.61 克/升)。微生物群落分析表明,乙醇生产与类杆菌相对丰度的变化呈负相关,而在乙醇发酵和 SSF 中,固着菌的相对丰度持续上升。这项研究为通过污泥中的微生物调控最大限度地利用稻草生产乙醇提供了科学依据,从而可进一步降低乙醇生产成本。
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引用次数: 0
Production of Fermented Solid Containing Lipases from Penicillium polonicum and Its Direct Use as Biocatalyst in the Synthesis of Ethyl Oleate 从多孔青霉中生产含脂肪酶的发酵固体并将其直接用作合成油酸乙酯的生物催化剂
IF 3.6 3区 工程技术 Q1 Agricultural and Biological Sciences Pub Date : 2024-05-16 DOI: 10.1007/s12155-024-10772-1
Jéssyca Ketterine Carvalho, Ricardo Antonio Zanella, P. A. Piana, Adriana Fiorini Rosado, Mairim Dahm da Silva, Rosemeire Aparecida da Silva de Lucca, M. R. Fagundes‐Klen, Edson Antônio da Silva, Karine Zanella, Cleide Viviane Buzanello, Álvaro Barcellos Onofrio, Maria Luiza Fernandes Rodrigues
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引用次数: 0
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