Optimizing the Conversion of Bio-Oil from Haematococcus pluvialis to Fatty Acid Methyl Esters

IF 3.1 3区 工程技术 Q3 ENERGY & FUELS BioEnergy Research Pub Date : 2024-08-17 DOI:10.1007/s12155-024-10794-9
C. Sanjurjo, E. Rodríguez, M. Bartolomé, R. González, A. Hernández Battez
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Abstract

Haematococcus pluvialis microalgae have emerged as a prevalent source of antioxidants in cosmetics and nutritional products. Additionally, numerous researchers have posited the potential of this microalgae to produce fatty acid methyl esters (FAME). Nevertheless, the optimization of the production of FAME from H. pluvialis oil has not been investigated. In this study, the transesterification reaction of H. pluvialis bio-oil was optimized using the response surface methodology, resulting in optimal experimental conditions for an oil to methanol ratio of 1:4.17, at a temperature of 80 °C, with a reaction time of 47 min. The resulting FAME was found to not comply with the biodiesel standard in terms of the content of polyunsaturated fatty acids (6.02%), as well as kinematic viscosity (7.02 mm2/s). Further study is required to reduce these parameters in order to ensure biodiesel quality and compliance with the standard. Nevertheless, its high flash point value of 150 °C and its high thermal stability within the temperature range of 211–290 °C suggest the potential for utilization as a biolubricant.

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优化将血球藻生物油转化为脂肪酸甲酯的过程
血球藻微藻已成为化妆品和营养品中抗氧化剂的主要来源。此外,许多研究人员都认为这种微藻具有生产脂肪酸甲酯(FAME)的潜力。然而,关于如何优化利用 H. pluvialis 油生产 FAME 的问题还没有进行过研究。在本研究中,利用响应面方法优化了 H. pluvialis 生物油的酯交换反应,得出了最佳实验条件:油与甲醇的比例为 1:4.17,温度为 80 °C,反应时间为 47 分钟。结果发现,FAME 的多不饱和脂肪酸含量(6.02%)和运动粘度(7.02 mm2/s)不符合生物柴油标准。需要进一步研究如何降低这些参数,以确保生物柴油的质量和符合标准。不过,生物柴油 150 °C 的高闪点值和 211-290 °C 温度范围内的高热稳定性表明,生物柴油具有用作生物润滑剂的潜力。
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来源期刊
BioEnergy Research
BioEnergy Research ENERGY & FUELS-ENVIRONMENTAL SCIENCES
CiteScore
6.70
自引率
8.30%
发文量
174
审稿时长
3 months
期刊介绍: BioEnergy Research fills a void in the rapidly growing area of feedstock biology research related to biomass, biofuels, and bioenergy. The journal publishes a wide range of articles, including peer-reviewed scientific research, reviews, perspectives and commentary, industry news, and government policy updates. Its coverage brings together a uniquely broad combination of disciplines with a common focus on feedstock biology and science, related to biomass, biofeedstock, and bioenergy production.
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