{"title":"Ti-catalyzed homocyclomagnesiation of (Z)-1,2,6-trienes in the stereoselective synthesis of 1Z,5Z,9Z,13Z-tetraenes","authors":"E. Kh. Makarova, A. A. Makarov","doi":"10.1007/s11172-024-4309-4","DOIUrl":null,"url":null,"abstract":"<div><p>On the basis of the Ti-catalyzed homocyclomagnesiation of terminal 1,2-dienes, an effective method for the synthesis of 1<i>Z</i>,5<i>Z</i>,9<i>Z</i>,13<i>Z</i>-tetraenes in high yields and high stereoselectivity has been developed. A new approach to the synthesis of allenes with substituents containing <i>Z</i>-double bonds has been elaborated.</p></div>","PeriodicalId":756,"journal":{"name":"Russian Chemical Bulletin","volume":"73 7","pages":"1916 - 1922"},"PeriodicalIF":1.7000,"publicationDate":"2024-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Chemical Bulletin","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11172-024-4309-4","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
On the basis of the Ti-catalyzed homocyclomagnesiation of terminal 1,2-dienes, an effective method for the synthesis of 1Z,5Z,9Z,13Z-tetraenes in high yields and high stereoselectivity has been developed. A new approach to the synthesis of allenes with substituents containing Z-double bonds has been elaborated.
期刊介绍：
Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections:
General and Inorganic Chemistry;
Physical Chemistry;
Organic Chemistry;
Organometallic Chemistry;
Chemistry of Natural Compounds and Bioorganic Chemistry.
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