Synthesis of optically transparent copolyimides based on alicyclic and fluorine-containing diamine

IF 1.7 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Russian Chemical Bulletin Pub Date : 2024-08-31 DOI:10.1007/s11172-024-4322-7
I. A. Novakov, D. V. Zavyalov, E. N. Savelyev, E. A. Alykova, A. M. Pichugin, M. A. Nakhod, E. M. Sukhareva, A. D. Dubinina, E. I. Farkhutdinova
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Abstract

It was shown that copolyimides based on adamantane-containing diamine and dianhydrides of 2,3,3′,4′-biphenyltetracarboxylic acid (a-BPDA) and 5,5′-(1,1,1,3,3,3-hexafluoropropane-2,2-diyl)bis(2-benzofuran-1,3-dione) (6FDA) are characterized by good thermal-oxidative properties (T5% = 465–485 °C) and a high optical transparency (T400 = 60–80%) in comparison with copolyimides based on the same dianhydrides and 2,2′-bis(trifluoromethyl)biphenyl-4,4′-diamine (TFBA), containing bulky trifluoromethyl fragments (T400 = 38–67%).

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基于脂环族和含氟二胺的光学透明共聚多亚胺的合成
研究表明,基于含金刚烷的二胺和 2,3,3′,4′-联苯四羧酸二酐(a-BPDA)和 5,5′-(1,1,1,3,3,3-六氟丙烷-2,2-二基)双(2-苯并呋喃-1、3-二酮)(6FDA)具有良好的热氧化性能(T5% = 465-485 °C)和较高的光学透明度(T400 = 60-80%),而基于相同二酐和 2,2′-双(三氟甲基)联苯-4,4′-二胺(TFBA)的共聚亚胺则含有笨重的三氟甲基片段(T400 = 38-67%)。
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来源期刊
Russian Chemical Bulletin
Russian Chemical Bulletin 化学-化学综合
CiteScore
2.70
自引率
47.10%
发文量
257
审稿时长
3-8 weeks
期刊介绍: Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.
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