{"title":"Integrating multiple interactions for the assembly of ordered organic frameworks","authors":"","doi":"10.1038/s44160-024-00641-2","DOIUrl":null,"url":null,"abstract":"A strategy is demonstrated for the hierarchical assembly of highly crystalline supramolecular nanotubes and tubular covalent organic frameworks (COFs), driven by cooperative dynamic covalent and coordination bonding. The pore size of the tubular COFs can be precisely controlled, and their reversible demetallation and remetallation could enable further tuning of the properties.","PeriodicalId":74251,"journal":{"name":"Nature synthesis","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nature synthesis","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1038/s44160-024-00641-2","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"0","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
A strategy is demonstrated for the hierarchical assembly of highly crystalline supramolecular nanotubes and tubular covalent organic frameworks (COFs), driven by cooperative dynamic covalent and coordination bonding. The pore size of the tubular COFs can be precisely controlled, and their reversible demetallation and remetallation could enable further tuning of the properties.
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