Biogeochemical evidence of the Oligocene and late Miocene–Pleistocene climatic variability from two deep sediment cores of the South China Sea

IF 1.3 4区 地球科学 Q3 GEOSCIENCES, MULTIDISCIPLINARY Journal of Earth System Science Pub Date : 2024-08-29 DOI:10.1007/s12040-024-02372-6
P Duraimaran, Devleena Mani, Rajeev Yadav, Dhananjay K Pandey, P B Ramamurthy, Waseem Raza, E V S S K Babu
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Abstract

Organic geochemical and stable isotope records of Oligocene and late Miocene–Pliocene sediments from IODP hole U1501C and Pliocene–Pleistocene sediments from U1499A of South China Sea (SCS) were studied to investigate clock sources of organic matter and carbonates and their spatiotemporal variations with East Asian climatic variability. Geochemical data was constrained using shipboard information. CaCO3 and total organic carbon contents (wt%) varied between 1.32 to 56.52 and 0.12 to 1.13, respectively. δ13Ccarb, δ18Ocarb and δ13Corg ranged from −4.89 to 1.98‰, −5.54 to 1.96‰, and −24.66 to −28.13‰, respectively. Contributions from mixed sources of carbon were observed in the Oligocene, while the late Miocene–Pleistocene exhibited terrestrial dominance. Early Oligocene carbonate, low and higher TOC are attributed to the opening of SCS, increased terrigenous input, and prevalence of cooler climate. Stable isotopes suggest the expansion of the marine environment and the probable dawning of the East Asian Winter Monsoon (EAWM) during the Oligocene. The late Oligocene marked a transition to a warmer climate. The strengthening of EAWM since the late Miocene is indicated by moderate organic carbon and high carbonates with enriched isotopes. Glacial low sea levels and higher terrestrial inputs increased TOC, while dissolution affected late Plio–early Pleistocene carbonates. Higher carbonates and productivity since the mid-Pleistocene were influenced by alternate weakening and strengthening of EAWM.

Research highlights

  • Organic matter, carbonates, C and O isotopes from Oligocene and late Miocene–Pleistocene sediments, northern SCS.

  • Productivity in the South China Sea fluctuated, being low during the Oligocene, with a subsequent increase since the late Miocene.

  • δ13Corg and δ13Ccarb indicate cold climatic conditions and probable winter monsoon signatures since the early Oligocene, transitioning to warmer conditions during the late Oligocene.

  • During the late Miocene (~8–5.6 Ma), deep-water circulation and intensified winter monsoons led to higher productivity.

  • Pliocene sediments (since ~5.6 Ma) showed signs of climatic cooling, sea level fluctuations, and enhanced winter monsoons with carbonate dilution.

  • The Plio-Pleistocene period witnessed glacial and interglacial cycles reflecting changing monsoon intensities.

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从南中国海的两个深层沉积物岩芯看渐新世和中新世晚期-始新世气候变异的生物地球化学证据
摘要 研究了中国南海(SCS)IODP U1501C孔的渐新世和中新世晚期-更新世沉积物以及U1499A孔的更新世-始新世沉积物的有机地球化学和稳定同位素记录,以探讨有机质和碳酸盐的时钟源及其随东亚气候变异的时空变化。地球化学数据利用船上信息进行了约束。CaCO3 和总有机碳含量(重量百分比)分别在 1.32 至 56.52 和 0.12 至 1.13 之间变化。δ13Ccarb、δ18Ocarb 和 δ13Corg的变化范围分别为-4.89-1.98‰、-5.54-1.96‰和-24.66-28.13‰。渐新世出现了混合碳源,而中新世晚期-早更新世则以陆地碳源为主。渐新世早期的碳酸盐、低总有机碳和较高的总有机碳可归因于SCS的开放、陆源输入的增加以及较冷气候的盛行。稳定同位素表明,在渐新世,海洋环境扩大,东亚冬季季风(EAWM)可能开始形成。晚渐新世标志着气候向温暖过渡。中新世晚期以来东亚冬季季候风的加强体现在适度的有机碳和富含同位素的高碳酸盐上。冰川时期的低海平面和更高的陆地输入增加了总有机碳,而溶解作用则影响了晚更新世-早更新世的碳酸盐。南中国海北部渐新世和中新世晚期-更新世沉积物中的有机质、碳酸盐、C和O同位素。δ13Corg和δ13Ccarb表明,自渐新世早期以来,气候条件寒冷,可能具有冬季季风特征,在渐新世晚期过渡到较暖的气候条件。在中新世晚期(〜8-5.6Ma),深水环流和冬季季风的加强导致生产力提高。上新世沉积物(约 5.6 千兆年以来)显示出气候变冷、海平面波动以及冬季季风增强和碳酸盐稀释的迹象。
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来源期刊
Journal of Earth System Science
Journal of Earth System Science Earth and Planetary Sciences-General Earth and Planetary Sciences
CiteScore
3.20
自引率
5.30%
发文量
226
期刊介绍: The Journal of Earth System Science, an International Journal, was earlier a part of the Proceedings of the Indian Academy of Sciences – Section A begun in 1934, and later split in 1978 into theme journals. This journal was published as Proceedings – Earth and Planetary Sciences since 1978, and in 2005 was renamed ‘Journal of Earth System Science’. The journal is highly inter-disciplinary and publishes scholarly research – new data, ideas, and conceptual advances – in Earth System Science. The focus is on the evolution of the Earth as a system: manuscripts describing changes of anthropogenic origin in a limited region are not considered unless they go beyond describing the changes to include an analysis of earth-system processes. The journal''s scope includes the solid earth (geosphere), the atmosphere, the hydrosphere (including cryosphere), and the biosphere; it also addresses related aspects of planetary and space sciences. Contributions pertaining to the Indian sub- continent and the surrounding Indian-Ocean region are particularly welcome. Given that a large number of manuscripts report either observations or model results for a limited domain, manuscripts intended for publication in JESS are expected to fulfill at least one of the following three criteria. The data should be of relevance and should be of statistically significant size and from a region from where such data are sparse. If the data are from a well-sampled region, the data size should be considerable and advance our knowledge of the region. A model study is carried out to explain observations reported either in the same manuscript or in the literature. The analysis, whether of data or with models, is novel and the inferences advance the current knowledge.
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