V. Vlasova, Yu. N. Toikka, V. V. Suslonov, A. S. Smirnov, N. A. Bokach
{"title":"Synthesis and Structure of Copper(I) Halide Complexes with Halogen-Functionalized Isocyanide Ligands","authors":"V. Vlasova, Yu. N. Toikka, V. V. Suslonov, A. S. Smirnov, N. A. Bokach","doi":"10.1134/S1070363224070107","DOIUrl":null,"url":null,"abstract":"<p>Eleven copper(I) halide complexes [CuX(CNR)<sub>3</sub>] (X = Cl, Br; R = C<sub>6</sub>H<sub>3</sub>-2,6-Cl<sub>2</sub>, C<sub>6</sub>H<sub>3</sub>-2-Cl-6-Me, C<sub>6</sub>H<sub>3</sub>-2,6-Br<sub>2</sub>, C<sub>6</sub>H<sub>3</sub>-2-Br-6-Me; X = I, R = C<sub>6</sub>H<sub>3</sub>-2,6-Cl<sub>2</sub>, C<sub>6</sub>H<sub>3</sub>-2-Cl-6-Me, C<sub>6</sub>H<sub>3</sub>-2-Br-6-Me) bearing halogen-functionalized aromatic isocyanide ligands were synthesized. The compounds were characterized by atomic emission spectroscopy (Cu), IR, <sup>1</sup>H NMR spectroscopy and high-resolution mass spectrometry. The structure of nine compounds was determined by X-ray diffraction. Structural studies allow to reveal that the supramolecular structure of the complexes is based on weak C–H···X (X = Cl, Br, I) interactions and π-stacking of the aromatic rings of isocyanide ligands.</p>","PeriodicalId":761,"journal":{"name":"Russian Journal of General Chemistry","volume":"94 7","pages":"1682 - 1688"},"PeriodicalIF":0.9000,"publicationDate":"2024-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1134/S1070363224070107.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of General Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S1070363224070107","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Eleven copper(I) halide complexes [CuX(CNR)3] (X = Cl, Br; R = C6H3-2,6-Cl2, C6H3-2-Cl-6-Me, C6H3-2,6-Br2, C6H3-2-Br-6-Me; X = I, R = C6H3-2,6-Cl2, C6H3-2-Cl-6-Me, C6H3-2-Br-6-Me) bearing halogen-functionalized aromatic isocyanide ligands were synthesized. The compounds were characterized by atomic emission spectroscopy (Cu), IR, 1H NMR spectroscopy and high-resolution mass spectrometry. The structure of nine compounds was determined by X-ray diffraction. Structural studies allow to reveal that the supramolecular structure of the complexes is based on weak C–H···X (X = Cl, Br, I) interactions and π-stacking of the aromatic rings of isocyanide ligands.
期刊介绍：
Russian Journal of General Chemistry is a journal that covers many problems that are of general interest to the whole community of chemists. The journal is the successor to Russia’s first chemical journal, Zhurnal Russkogo Khimicheskogo Obshchestva (Journal of the Russian Chemical Society ) founded in 1869 to cover all aspects of chemistry. Now the journal is focused on the interdisciplinary areas of chemistry (organometallics, organometalloids, organoinorganic complexes, mechanochemistry, nanochemistry, etc.), new achievements and long-term results in the field. The journal publishes reviews, current scientific papers, letters to the editor, and discussion papers.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
