Effect of doping of metal salts on polymers and their applications in various fields

IF 4.1 3区 化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR Reviews in Inorganic Chemistry Pub Date : 2024-08-28 DOI:10.1515/revic-2024-0034
Dyari Mustafa Mamand, Nazk Mohammed Aziz, Rebaz Anwar Omer
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Abstract

Transition metal compounds (TMCs) provide the benefits of vast reserves, affordability, non-toxicity, and environmental friendliness, making them highly sought-after in recent times. Integrating transition metal salts into polymers may result in substantial enhancements in optical and electrical characteristics, making them appealing for many applications. Transition metal ions may display a range of electronic transitions, which enables the adjustment of absorption and emission spectra. This characteristic has significant value in applications such as light-emitting devices (LEDs) and sensors. The photoluminescence of polymers may be improved by the addition of transition metal salts, which results in light emission that is both more brilliant and more efficient. On the other hand, this is advantageous for screens and optoelectronic devices. The presence of transition metal salts in polymers may help to improve their optical stability, hence lowering the probability that the polymers will degrade or change color over time. When it comes to the performance of optical devices over the long run, this is quite essential. Elevating the electrical conductivity of polymers is possible via the use of transition metal salts. This is very helpful in the process of developing conductive polymers for use in applications such as electronic fabrics, organic solar cells, and flexible electronic devices. Transition metal salts can affect the electrical band structure of polymers, which enables the band gap of the material to be tuned. This is very necessary in order to maximize the amount of light that is absorbed by photovoltaic devices. Through having all these benefits, we conducted a review to find out the effects on polymeric materials.
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金属盐掺杂对聚合物的影响及其在各领域的应用
过渡金属化合物(TMC)具有储量丰富、价格低廉、无毒和环保等优点,因此近年来备受追捧。将过渡金属盐整合到聚合物中可大幅提高光学和电学特性,使其在许多应用中具有吸引力。过渡金属离子可显示一系列电子跃迁,从而可调整吸收和发射光谱。这一特性在发光器件(LED)和传感器等应用中具有重要价值。通过添加过渡金属盐,聚合物的光致发光性能可以得到改善,从而使光发射更绚丽、更高效。另一方面,这对屏幕和光电设备也是有利的。聚合物中过渡金属盐的存在有助于提高其光学稳定性,从而降低聚合物随时间推移而降解或变色的可能性。这对光学设备的长期性能至关重要。使用过渡金属盐可以提高聚合物的导电性。这对于开发用于电子织物、有机太阳能电池和柔性电子设备等应用的导电聚合物非常有帮助。过渡金属盐可以影响聚合物的电带结构,从而调整材料的带隙。这对于最大限度地提高光伏设备的光吸收量非常必要。通过了解所有这些优点,我们对聚合物材料的影响进行了审查。
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来源期刊
Reviews in Inorganic Chemistry
Reviews in Inorganic Chemistry 化学-分析化学
CiteScore
7.30
自引率
4.90%
发文量
20
审稿时长
1 months
期刊介绍: Reviews in Inorganic Chemistry (REVIC) is a quarterly, peer-reviewed journal that focuses on developments in inorganic chemistry. Technical reviews offer detailed synthesis protocols, reviews of methodology and descriptions of apparatus. Topics are treated from a synthetic, theoretical, or analytical perspective. The editors and the publisher are committed to high quality standards and rapid handling of the review and publication process. The journal publishes all aspects of solid-state, molecular and surface chemistry. Topics may be treated from a synthetic, theoretical, or analytical perspective. The editors and the publisher are commited to high quality standards and rapid handling of the review and publication process. Topics: -Main group chemistry- Transition metal chemistry- Coordination chemistry- Organometallic chemistry- Catalysis- Bioinorganic chemistry- Supramolecular chemistry- Ionic liquids
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