A simple approach to produce 34 mM hydrogen peroxide utilizing carbon nitride photocatalysts

IF 1.4 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Chemistry Letters Pub Date : 2024-08-30 DOI:10.1093/chemle/upae175
Hiroshi Kominami, Ryuki Yamashita, Xiangru Liu, Atsuhiro Tanaka
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Abstract

The production of hydrogen peroxide (H2O2) by photocatalytic reduction of oxygen (O2) has attracted considerable attention as a more efficient and cleaner method than traditional methods for synthesizing H2O2. Carbon nitride (C3N4) is a suitable photocatalyst for H2O2 production under solar light due to its band gap. The objective of this study was to achieve rapid production and high concentration of H2O2 over a C3N4 photocatalyst through the strategy of increasing the H2O2 production rate and decreasing the H2O2 decomposition rate. The results showed that 34 mM H2O2 was produced by photocatalytic reactions in an alcohol at slightly elevated temperatures under visible light irradiation. To gain a deeper understanding of the rapid production and high concentration of H2O2, various parameters were investigated.
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利用氮化碳光催化剂生产 34 mM 过氧化氢的简单方法
通过光催化还原氧气(O2)来生产过氧化氢(H2O2),是一种比传统合成 H2O2 方法更高效、更清洁的方法,因此备受关注。氮化碳(C3N4)因其带隙而成为在太阳光下生产 H2O2 的合适光催化剂。本研究的目的是通过提高 H2O2 生成率和降低 H2O2 分解率的策略,在 C3N4 光催化剂上实现快速生成高浓度 H2O2。结果表明,在可见光照射下,酒精在稍高温度下通过光催化反应产生了 34 mM H2O2。为了更深入地了解 H2O2 的快速产生和高浓度,对各种参数进行了研究。
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来源期刊
Chemistry Letters
Chemistry Letters 化学-化学综合
CiteScore
3.00
自引率
6.20%
发文量
260
审稿时长
1.2 months
期刊介绍: Chemistry Letters covers the following topics: -Organic Chemistry- Physical Chemistry- Inorganic Chemistry- Analytical Chemistry- Materials Chemistry- Polymer Chemistry- Supramolecular Chemistry- Organometallic Chemistry- Coordination Chemistry- Biomolecular Chemistry- Natural Products and Medicinal Chemistry- Electrochemistry
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