The Effect of Solute Suppressed Nucleation Effect and Latent Heat on the Grain Refinement of Cast Aluminum Alloy

Li Jun, Jiang Haitao, Wu Xiaoyan, Liu Wenqiang, Lu Hongzhou
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Abstract

Grain refinement is the key to developing high-quality cast aluminum alloys. Based on the solute conservation theory and dendritic growth kinetics model, this paper developed a cellular automaton (CA) numerical model and fully considered the complex evolutionary processes, such as nucleation particle characteristics, nucleation-growth process, dynamic solute diffusion, and latent heat release during the solidification process of aluminum alloys. The CA model was used to quantify the role of solidification latent heat and solute diffusion in the grain nucleation process. The influence of solute suppressed nucleation (SSN) and solidification latent heat on the grain refinement effect of aluminum alloys are systematically studied. The results showed that when only considering the SSN effect, with the increase of nucleation density, the refinement efficiency decreases from 81.2 to 45.98 pct, and the decrease gradually decreases. This was mainly due to the increase of number of particles in the solute diffusion layer. The grain separation distance (GSD) became smaller than the size of the invisible nucleus region, reducing in the nucleation efficiency of the particles there. When the model further considered the effect of latent heat, the refinement efficiency was sharply dropped to 7 pct. The re-glow phenomenon caused by latent heat release limited the possibility of nucleation of small-sized particles and particles located in the SSN zone. Therefore, latent heat was fond to be the main factor restricting grain refinement.

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溶质抑制成核效应和潜热对铸铝合金晶粒细化的影响
晶粒细化是开发高质量铸造铝合金的关键。本文基于溶质守恒理论和树枝状生长动力学模型,建立了细胞自动机(CA)数值模型,充分考虑了铝合金凝固过程中晶核颗粒特征、晶核生长过程、溶质动态扩散和潜热释放等复杂的演化过程。CA 模型用于量化凝固潜热和溶质扩散在晶粒成核过程中的作用。系统研究了溶质抑制成核(SSN)和凝固潜热对铝合金晶粒细化效应的影响。结果表明,当仅考虑 SSN 的影响时,随着成核密度的增加,细化效率从 81.2 pct 下降到 45.98 pct,且下降幅度逐渐减小。这主要是由于溶质扩散层中颗粒数量的增加。晶粒分离距离(GSD)变得小于隐形晶核区域的尺寸,从而降低了该区域颗粒的成核效率。当模型进一步考虑潜热的影响时,细化效率急剧下降到 7%。潜热释放引起的再辉光现象限制了小尺寸颗粒和位于 SSN 区域的颗粒成核的可能性。因此,潜热被认为是限制晶粒细化的主要因素。
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