A novel S-scheme photocatalyst Fe2O3/Bi2O3/g-C3N4 with enhanced visible-light photocatalytic performance for antibiotic degradation and CO2 reduction: RSM-based optimization

Abstract

The degradation of pollutants and reduction of CO₂ to hydrocarbon fuels using photocatalysis is a potential approach to reducing CO₂ emissions and decreasing environmental contamination. This study introduces an innovative S-scheme photocatalyst (Fe₂O₃/Bi₂O₃/g-C₃N₄) synthesized through simple methods for the first time. The structural, morphological, and optical properties of the synthesized photocatalysts were comprehensively characterized using XRD, XPS, FTIR, SEM, TEM, HR-TEM, BET, UV–vis DRS, PL, ESR, and mott-Schottky analyses, respectively. The visible light photodegradation of tetracycline (TC) antibiotic and CO₂ conversion were carried out in order to evaluate the photocatalytic performance of these synthesized materials. Using the RSM-CCD approach, the influence of key variables on TC degradation were optimized. The results indicated that the optimized photocatalyst (45-FeBiC) exhibited higher photocatalytic performance (99.87 %) compared to other samples via photogenerated •O₂⁻, and •OH. Additionally, four cycle studies verified that the 45-FeBiC nanocomposite had adequate photostability. After 6 h of visible light illumination, the 45-FeBiC catalyst generated 33.84 μmol/g of CO and maintained 96.2 % of its initial photocatalytic activity after 30 h of reaction. The enhanced photocatalytic efficiency of the 45-FeBiC nanocomposite is attributed to the photosensitization effect of 3 wt%-Fe₂O₃/Bi₂O₃ on g-C₃N₄ within the S-scheme photocatalytic framework.