Advancements in on-site heavy metal detection: Characterizing and sensitive Hg2+ sensing of silver spheroid nanoparticles obtained by laser ablation synthesis in solution

Abstract

Heavy metal detection in water bodies is crucial to prevent potential harm to the environment, animals and humans. While powerful techniques such as atomic absorption spectrometry exist, they often require extensive sample preparation and are typically confined to laboratory settings. As a result, alternative detection methods such as optical sensors, are under development to provide a simpler, faster, and on-site detection solution. In the present work spheroidal silver nanoparticles (AgNPs) with a mean size of 14.7 ± 0.6 nm were synthesized by laser ablation in a sodium citrate solution. These nanoparticles exhibit a localized surface plasmon resonance (LSPR), which is profoundly dependent on the size, morphology and composition of the nanoparticles and the refractive index of the surrounding media. The detection capabilities of these nanoparticles were assessed by exposing them to various metal ions, revealing a distinctive sensitivity to Hg ions. Notably, this particular ion had a significant impact on the extinction curve of the AgNPs. The impact of synthesis parameters, including sodium citrate and NaCl concentration, as well as pH, on the efficacy of Hg detection was systematically studied. Characterization techniques such as Dynamic Light Scattering (DLS), Transmission Electron Microscopy (TEM), High-Resolution TEM (HRTEM), and Scanning Transmission Electron Microscopy (STEM) were employed to determine the size, morphology, distribution, crystalline structure, and elemental composition of the AgNPs. The results indicated that AgNPs synthesized through laser ablation in a sodium citrate solution exhibited sensitive detection capabilities for Hg ions, reaching an LOD and LOQ of 0.9355 μM and 2.8350 μM respectively.