Luminescent Solar Concentrators for Greenhouse Applications Based on Highly Luminescent Carbon Quantum Dots

Abstract

Carbon quantum dots (CQDs) are promising luminophores for luminescent solar concentrators (LSCs) in transparent photovoltaic greenhouse covers due to their high ultraviolet (UV)-light absorption coefficient, which is vital for plant growth. Herein, high quantum yield (75%) and large Stokes shift (0.706 eV) CQDs are synthesized by a simple, fast, cheap, and mass scalable method. A comprehensive study on the LSC engineering is carried out. Thin layers of CQDs with different concentrations of 1, 3, and 5 wt% and different number of layers (1–5) are coated on glass and poly(methyl methacrylate) (PMMA) waveguides, sized 5 × 5 × 0.6 and 15 × 15 × 0.6 cm³. The best performing single-layer LCS exhibits power conversion efficiency (PCE) and optical efficiency as high as 1.6% and 6.5%, respectively (LSC size 5 × 5 × 0.6 cm³), and 1.19% and 3.27% (LSC size of 15 × 15 × 0.6 cm³), respectively. Over 90 days, stability tests show a 2% PCE decrease. Tests on a small-scale greenhouse model demonstrate that transparent photovoltaic LSC roofs not only produce electricity but also control temperature inside the greenhouse. Hence, CQD-based LSCs synthesized by the scalable method can be used in commercialization of transparent greenhouses photovoltaic covers.