Effect of iron‐containing fillers on heat release kinetics and strength properties of polyester resin

Abstract

The influence of filling by iron‐containing fillers on the heat release kinetics and mechanical properties of industrial unsaturated polyester resin PN‐1 is investigated experimentally. The iron ore concentrate, electrostatic precipitator dust, high alumina cement grade HAC‐1, shavings made of cast iron, fine grade sand are used as fillers. To improve the strength characteristics of polyester resin composites the small amount (0.2–1.0 wt%) of organosilicon additives such as synthetic silicone rubber, tris(trimethylsiloxy) phenylsilane, octamethyl cyclotetrasiloxane are used. The heat release kinetics is studied for different ratios between accelerator (cobalt naphthenate) and initiator (cyclohexanone peroxide). The time to reach the maximum temperature of the heat release is significantly reduced when a large amount of iron ore concentrate is used as filler. The temperature of maximum heat release decreases and the time to reach it increases when adding electrostatic precipitator dust in small amount of 5 wt% to the high filled by iron ore concentrate (295 wt%) composite system. The optimum in strength indicators associated with the ratio of different fractions in systems consisting of two fillers of different properties and granulometric composition is found. The highest values of compressive strength in the cement–iron ore concentrate and sand–iron ore concentrate systems are observed. An increase in the strength characteristics of composites by 15%–20% with organosilicon additive introduction is observed. The addition of the silicone rubber increases the strength properties of samples the most among all additives considered.Highlights Effect of filling by iron‐containing fillers on the heat release kinetics and mechanical properties of polyester resin is found. The time to reach the maximum temperature of the heat release is significantly reduced when the resin is filled by a large amount of iron ore concentrate. The temperature of maximum heat release decreases when the electrostatic precipitator dust in small amount is added to the high filled by iron ore concentrate. An increase in the strength characteristics of composites by 15–20% with introduction of organosilicon additives is observed.