Effect of particle size on SiO2 nanofluid viscosity determined by a two-step method

IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Journal of Thermal Analysis and Calorimetry Pub Date : 2024-09-03 DOI:10.1007/s10973-024-13403-1
Gökberk Yalçın, Semiha Öztuna, Ahmet Selim Dalkılıç, Somchai Wongwises
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Abstract

According to review of the literature, the influence of nanoparticle diameter with irregular shapes on viscosity requires further research since there is no relation between particle size and nanofluid stability. In this study, SiO2/EG–water-based nanofluid samples were prepared, and their viscosities were experimentally determined. SiO2 nanoparticles had sizes of 7, 15, and 40 nm, and the base fluid was a 50% ethylene glycol and 50% water mixture. Nanofluid samples were prepared using a two-step technique. Viscosity change was measured every 10 °C from 20 to 60 °C. The maximum viscosity values were observed for 7, 15, and 40 nm particles over an entire concentration range. Considering all measurements, the highest viscosity increase was 60.51% for 3% SiO2 (7 nm) at 60 °C, and the lowest viscosity change was 7.72% for 1% SiO2 (40 nm) at 40 °C. The most stable sample of the current study was 1% SiO2 (15 nm), and its Zeta potential was − 35.6 mV. Finally, a new empirical equation that included temperature, particle diameter, and concentration terms is suggested to predict dynamic viscosity, with R 2adj  = 0.98. It was also compared with previous correlations.

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用两步法测定粒度对二氧化硅纳米流体粘度的影响
根据文献综述,形状不规则的纳米颗粒直径对粘度的影响需要进一步研究,因为颗粒大小与纳米流体稳定性之间没有关系。本研究制备了 SiO2/EG-水基纳米流体样品,并通过实验测定了它们的粘度。SiO2 纳米粒子的尺寸分别为 7、15 和 40 纳米,基液为 50% 乙二醇和 50% 水的混合物。纳米流体样品采用两步法制备。在 20 至 60 °C 的温度范围内,每 10 °C 测量一次粘度变化。在整个浓度范围内,7、15 和 40 纳米颗粒的粘度值最大。考虑到所有测量值,3% SiO2(7 纳米)在 60 °C时的粘度增幅最大,为 60.51%;1% SiO2(40 纳米)在 40 °C时的粘度变化最小,为 7.72%。本次研究中最稳定的样品是 1% SiO2 (15 nm),其 Zeta 电位为 - 35.6 mV。最后,提出了一个包含温度、颗粒直径和浓度项的新经验方程来预测动态粘度,其 R2adj = 0.98。该方程还与之前的相关方程进行了比较。
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来源期刊
CiteScore
8.50
自引率
9.10%
发文量
577
审稿时长
3.8 months
期刊介绍: Journal of Thermal Analysis and Calorimetry is a fully peer reviewed journal publishing high quality papers covering all aspects of thermal analysis, calorimetry, and experimental thermodynamics. The journal publishes regular and special issues in twelve issues every year. The following types of papers are published: Original Research Papers, Short Communications, Reviews, Modern Instruments, Events and Book reviews. The subjects covered are: thermogravimetry, derivative thermogravimetry, differential thermal analysis, thermodilatometry, differential scanning calorimetry of all types, non-scanning calorimetry of all types, thermometry, evolved gas analysis, thermomechanical analysis, emanation thermal analysis, thermal conductivity, multiple techniques, and miscellaneous thermal methods (including the combination of the thermal method with various instrumental techniques), theory and instrumentation for thermal analysis and calorimetry.
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