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Numerical investigation of chemical reactive MHD fluid dynamics over a porous surface with Cattaneo–Christov heat flux 具有Cattaneo-Christov热流密度的多孔表面化学反应MHD流体动力学数值研究
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-12-13 DOI: 10.1007/s10973-024-13815-z
Saleem Nasir, Abdallah S. Berrouk

A theoretical framework to investigate three-dimensional Williamson fluid flow over a bidirectional extended flat horizontal surface is proposed in this dissertation. Artificial intelligence and machine learning fields have seen tremendous growth in prominence along with the rapid advancement of related technology. This work trains a machine learning model based on artificial neural networks to handle the mathematical formulation incorporating heat source and Hall effects using the Levenberg–Marquardt approach. Additionally, the impact of activation energy on fluid concentration is incorporated into the analysis. Cattaneo-Christov double diffusion models are used to model heat transfer combined with the effects of thermal radiation. The solutions, serving as reference datasets for various scenarios, have been generated numerically using the BVP4C approach. Artificial neural networks are utilized for training, testing, and validating these numerical computations using a 70:15:15 ratio. The predictive model accuracy is evaluated using various statistical metrics, including linear regression, histograms, fitting analysis, and mean squared error evaluations, with the least error ranging between 103 and 104, based on individual error analysis of four parameters. The findings show that temperature rises with the M parameter, whereas velocity declines by increasing the M parameter. Concentration rises with increasing activation energy parameter and falls with decreasing Sc. The results show that artificial neural networks can provide a successful replacement for forecasts for the future, and the fluid flow structure simulated here may result in better industrial designs.

本文提出了一个研究双向扩展平面水平面上三维威廉姆森流体流动的理论框架。随着相关技术的快速发展,人工智能和机器学习领域得到了长足的发展。本工作训练了一个基于人工神经网络的机器学习模型,使用Levenberg-Marquardt方法处理包含热源和霍尔效应的数学公式。此外,活化能对流体浓度的影响也被纳入分析。采用Cattaneo-Christov双扩散模型模拟热辐射作用下的传热过程。这些解决方案作为各种场景的参考数据集,已经使用BVP4C方法在数值上生成。人工神经网络使用70:15:15的比例用于训练、测试和验证这些数值计算。预测模型的准确性使用各种统计指标进行评估,包括线性回归、直方图、拟合分析和均方误差评估,基于四个参数的单个误差分析,最小误差范围在10−3和10−4之间。结果表明,温度随M参数的增大而升高,而速度随M参数的增大而降低。浓度随活化能参数的增大而升高,随Sc的减小而降低。结果表明,人工神经网络可以成功地替代未来的预测,本文模拟的流体流动结构可以为更好的工业设计提供依据。
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引用次数: 0
Numerical study and optimization of a ferrofluid-filled cavity with thick vertical walls and an elliptical obstacle at the center 具有厚垂直壁、中心有椭圆障碍物的铁磁流体填充腔的数值研究与优化
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-12-13 DOI: 10.1007/s10973-024-13723-2
Muhammad Ibrahim, Ebrahem A. Algehyne, Fahad Sikander, Abdulbasid S. Banga,  Vakkar Ali, Norah A. M. Alsaif, Shahid Ali Khan

This paper investigates the ferrofluid flow within a square cavity considering the effects of viscosity. An elliptical obstacle with a high temperature is placed in the center of the cavity, and the vertical walls are cooled and covered with a conductive layer of varying thickness. Electrical current-carrying wires alongside the cooled walls generate the Kelvin force in the ferrofluid. Variables studied include the Ra and Ha, varying magnetic fields (MF), the thickness and thermal conductivity of the conductive wall, and the aspect ratio (AR). The equations are solved using the finite element method, and entropy (EnY) data and Nu are studied using the response surface method. Statistical analysis revealed that the AR significantly impacts the variations in the Ha and MNF. Results indicated that increasing the Ha decreases the generated EnY and the ({Nu}_{text{m}}) in the cavity, whereas increasing the strength of the varying MF increases both the generated EnY and the ({Nu}_{text{m}}). An increase in the AR also leads to increased EnY production and ({Nu}_{text{m}}). The maximum and minimum Nu were observed at conductive wall thicknesses of 0.05 and 0.1, respectively, with a difference of 88.6%. Increasing the wall thickness reduces thermal EnY by up to 91%, fluid EnY by 82.3%, and total EnY by 90.7% compared to their maximum values. Increasing the Ra from 1000 to 1,000,000 results in a 296, 2355, and 65.8% increase in the ({Nu}_{text{m}}), fluid EnY, and total EnY, respectively, while reducing thermal EnY by 19.6% and Be by 88.8%.

本文研究了考虑黏度影响的方形腔内铁磁流体的流动。在空腔中心放置具有高温的椭圆形障碍物,对垂直壁面进行冷却并覆盖有厚度不等的导电层。沿着冷却壁的载电流导线在铁磁流体中产生开尔文力。研究的变量包括Ra和Ha、变磁场(MF)、导电壁的厚度和导热系数以及宽高比(AR)。采用有限元法对方程进行求解,采用响应面法对熵(EnY)数据和Nu进行研究。统计分析表明,AR对Ha和MNF的变化有显著影响。结果表明,增加Ha会降低腔内产生的EnY和({Nu}_{text{m}}),而增加变化MF的强度则会增加腔内产生的EnY和({Nu}_{text{m}})。AR的增加也会导致EnY产量和({Nu}_{text{m}})的增加。在导电壁厚为0.05和0.1时,Nu值最大,最小,差值为88.6%. Increasing the wall thickness reduces thermal EnY by up to 91%, fluid EnY by 82.3%, and total EnY by 90.7% compared to their maximum values. Increasing the Ra from 1000 to 1,000,000 results in a 296, 2355, and 65.8% increase in the ({Nu}_{text{m}}), fluid EnY, and total EnY, respectively, while reducing thermal EnY by 19.6% and Be by 88.8%.
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引用次数: 0
Lithium-ion battery equivalent thermal conductivity testing method based on Bayesian optimization algorithm 基于贝叶斯优化算法的锂离子电池等效导热系数测试方法
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-12-13 DOI: 10.1007/s10973-024-13884-0
Fang Wang, Ruihao Liu, Xiaole Ma, Yuxuan Zhang, Guangli Bai, Biao Ma, Danhua Li, Zhen Wei, Shiqiang Liu, Yueying Zhu

The thermal conductivity is one of the key thermal property's parameters in the design, modeling, and simulation of lithium-ion battery thermal management systems. Accurate measurement of thermal conductivity allows for a deep understanding of the heat transfer behavior inside lithium-ion batteries, providing essential insights for optimizing battery design, enhancing energy density, and improving safety. In this study, the surface temperature variation data of lithium-ion batteries were obtained by externally heating the batteries using a constant pressure source in an accelerating rate calorimeter enhanced system (ARC). Based on the Fourier one-dimensional heat conduction model, the average specific heat capacity and vertical thermal conductivity of the lithium-ion batteries were calculated. Additionally, the Bayesian optimization algorithm was employed to significantly reduce the number of iterations and rapidly invert the in-plane thermal conductivity of the batteries. The accuracy of the thermal conductivity measurement results was verified by comparing the consistency between experimental and simulation data. The results indicate that the transient deviation between experimental and simulation data at each temperature measurement point does not exceed 0.2 °C, demonstrating the high accuracy of the proposed method. Furthermore, the thermal conductivity of the lithium-ion battery was measured using the Hot Disk method for comparative validation. The results show that the maximum transient deviation of the Hot Disk data is 0.4 °C, indicating that compared to the Hot Disk method, the proposed method exhibits higher accuracy.

导热系数是锂离子电池热管理系统设计、建模和仿真的关键热性能参数之一。准确测量导热系数有助于深入了解锂离子电池内部的传热行为,为优化电池设计、提高能量密度和提高安全性提供重要见解。本研究在加速量热计增强系统(ARC)中,采用恒压源对锂离子电池进行外部加热,获得了电池表面温度的变化数据。基于傅里叶一维热传导模型,计算了锂离子电池的平均比热容和垂直导热系数。此外,采用贝叶斯优化算法显著减少迭代次数,快速反演电池的面内导热系数。通过对比实验数据与仿真数据的一致性,验证了导热系数测量结果的准确性。结果表明,各温度测量点的实验数据与仿真数据的瞬态偏差不超过0.2℃,表明该方法具有较高的精度。此外,采用热盘法测量了锂离子电池的导热系数,以进行对比验证。结果表明,热盘数据的最大瞬态偏差为0.4℃,表明与热盘法相比,该方法具有更高的精度。
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引用次数: 0
Performance evaluation and mathematical modeling of reverse osmosis membrane desalination unit 反渗透膜淡化装置性能评价及数学建模
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-12-13 DOI: 10.1007/s10973-024-13730-3
Ahmed Alzahmi, Mohammed Alswat, W. A. El-Askary, Khaled Ramzy

The use of reverse osmosis (RO) membranes for desalination has gained popularity in generating drinking water from seawater sources. This study assesses the performance of a single-module feed-forward reverse osmosis (RO) system, representing the membrane module as a tubular module with feed flow on the tube side. A superstructure for the single-module feed-forward RO system forms the basis for a comprehensive mathematical model of the RO system. Mass, materials, and energy balances are meticulously applied to all system components. The study also explores external factors’ influence, such as feed parameters, utility costs, and product costs, on RO system performance and optimal design. It delves into parameters affecting unit performance, including feed characteristics and operational conditions. Additionally, the impact of feed specifications and operating conditions on concentration polarization within each module is investigated. The obtained results showed that the total permeate from the unit decreases with higher salt concentration on the membrane wall as the feed concentration increases, while the unit cost remains constant. In addition, the rise in feed flow rate and feed temperature led to a decrease in wall concentration. Finally, a substantial 20% reduction in wall concentration was generated with approaching the upper limits endorsed by module manufacturers for feed temperature.

利用反渗透(RO)膜进行海水淡化已经在从海水来源生产饮用水方面得到了普及。本研究评估了单模块前馈反渗透(RO)系统的性能,将膜模块表示为管状模块,进料流在管侧。单模块前馈反渗透系统的上层结构构成了反渗透系统综合数学模型的基础。质量、材料和能量平衡被细致地应用于所有系统组件。研究还探讨了外部因素对RO系统性能和优化设计的影响,如进料参数、效用成本和产品成本。它深入研究了影响机组性能的参数,包括进料特性和操作条件。此外,还研究了进料规格和操作条件对各模块内浓度极化的影响。结果表明,随着进料浓度的增加,膜壁盐浓度越高,装置总渗透率越低,而单位成本保持不变。此外,进料流量和进料温度的升高导致壁面浓度降低。最后,在接近组件制造商认可的进料温度上限的情况下,壁浓度大幅降低了20%。
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引用次数: 0
Experimental and model study on flame radiation characteristics of ethanol spill fires in tunnel environment 隧道环境下乙醇溢出火灾火焰辐射特性的实验与模型研究
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-12-13 DOI: 10.1007/s10973-024-13764-7
Peihong Zhang, Chenghao Ye, Meiqing Xia, Jiaxing Li, Xuejing Hu

Accidental leakage of liquid fuel frequently results in spill fire accidents, with radiation playing a pivotal role in flame propagation and environmental hazard. Conducted in a scale tunnel, ethanol spill fire experiment utilized five stainless steel rectangular channels, with length of 1 m, widths ranging from 0.1 to 0.3 m, and height of 0.03 m. The study focused on aspects such as flame area, bifurcation and fusion behaviors, flame height, and the distribution of flame heat radiation. Notably, as the channel width increased, the flame area and bifurcation phenomenon decreased, leading to taller flames. Drawing comparisons with the trapezoid flame thermal radiation model, we introduced a weighted multi-point source flame thermal radiation model that takes into account flame shape. In terms of predicting thermal radiation, weighted multi-point source model demonstrates a slightly higher degree of accuracy compared to trapezoid model, providing results closer to experimental values. It not only accurately predicted near-distance radiation from the spill fire but also distant radiation, with an error margin of less than 20%. This work offers crucial insights into the spatial distribution of flame heat radiation in spill fire accidents.

液体燃料的意外泄漏经常导致泄漏火灾事故,其中辐射在火焰传播和环境危害中起着关键作用。乙醇溢出火灾实验在规模隧道中进行,采用5条不锈钢矩形通道,长1 m,宽0.1 ~ 0.3 m,高0.03 m。研究重点包括火焰面积、分岔与融合行为、火焰高度、火焰热辐射分布等方面。值得注意的是,随着通道宽度的增加,火焰面积和分岔现象减少,导致火焰高度升高。通过与梯形火焰热辐射模型的比较,提出了一种考虑火焰形状的加权多点源火焰热辐射模型。在热辐射预测方面,加权多点源模型比梯形模型精度略高,预测结果更接近实验值。它不仅能准确预测泄漏火灾的近距离辐射,还能准确预测远距离辐射,误差范围小于20%。这项工作为泄漏火灾事故中火焰热辐射的空间分布提供了重要的见解。
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引用次数: 0
Novel design of artificial intelligence-based neural networks for the dynamics of magnetized chemically reactive Darcy–Forchheimer nanofluid flow 基于人工智能的Darcy-Forchheimer纳米流体磁化化学反应动力学神经网络新设计
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-12-12 DOI: 10.1007/s10973-024-13782-5
Zohaib Arshad, Zahoor Shah, Muhammad Asif Zahoor Raja, Waqar Azeem Khan, Taseer Muhammad, Mehboob Ali
<div><p>This study explores the intricate interaction of thermal radiation, chemical reactions, Brownian motion, and thermophoresis on heat and mass transfer within a magnetic nanofluid, flowing over a porous stretching surface. Current models in the literature are limited in their ability to account for the complex dynamics governing this process, particularly with respect to nonlinear variations in fluid momentum, temperature, and mass diffusion. To overcome these limitations, we propose an enhanced approach utilizing the Darcy–Forchheimer fluidic model (DFM), which integrates these nonlinear effects and addresses both momentum and mass diffusion. Our model is distinct in its application of artificial intelligence neural networks (AI-NN) alongside the Levenberg–Marquardt method (LMM), offering a more sophisticated computational solution than traditional numerical methods. The fluidic motion is governed by partial differential equations (PDEs) and these mathematical equations are then reproduced by converting them into dimensionless ordinary differential equations (ODEs) along with support parameters to control the motion and diffusion of mass if fluid. Computational solutions are derived utilizing artificial intelligence neural network (AI-NN) with Levenberg–Marquardt method (LMM), enabling an analysis of the effects of thermophysical factors such as source of heat<span>((lambda ))</span>, magnetic effect parameter<span>((M))</span>, Schmidt number<span>((Sc))</span>, chemical reaction effect<span>(({c}_{text{r}}))</span>, Brownian motion parameter<span>(({N}_{text{b}}))</span>, thermophoresis effect<span>({(N}_{text{t}}))</span>, radiation number <span>((Rd))</span>, and thermal buoyancy number<span>((alpha ))</span>. The dataset generated for the governing system of Darcy–Forchheimer fluidic model (DFM) is applied to extract the approximate solutions through Mathematica and MATLAB techniques. The findings demonstrate the significant impact of these parameters on velocity, temperature, and mass concentration, with variations observed across 14 different scenarios. The study’s computational framework, validated through regression analysis, error histograms, and fitness functions, ensures high accuracy, with mean squared error (MSE) values clearly represented. This novel approach offers a promising alternative to existing models, enhancing the understanding of heat and mass transfer in magnetized nanofluids. Performance analysis is made on the bases of variety of scenarios taken for velocity <span>(left( {f^{prime } left( eta right)} right))</span>, temperature <span>(left( {theta left( eta right)} right))</span>, and concentration of mass <span>(left(phi left(eta right)right))</span> which ranged from <span>({10}^{-14})</span> to<span>({10}^{-9})</span>. Regression analysis<span>(left(RAright))</span>, error histogram <span>(left(EHright))</span>, and fitness state of function <span>((FF))</span> stood responsible for validation and accuracy of
本研究探讨了热辐射、化学反应、布朗运动和热泳运动对磁性纳米流体内的传热和传质的复杂相互作用,这些流体流经多孔拉伸表面。目前文献中的模型在解释控制这一过程的复杂动力学方面的能力有限,特别是在流体动量、温度和质量扩散方面的非线性变化。为了克服这些限制,我们提出了一种利用Darcy-Forchheimer流体模型(DFM)的增强方法,该模型集成了这些非线性效应,并解决了动量和质量扩散问题。我们的模型在人工智能神经网络(AI-NN)和Levenberg-Marquardt方法(LMM)的应用方面是独特的,提供了比传统数值方法更复杂的计算解决方案。流体运动由偏微分方程(PDEs)控制,然后通过将这些数学方程转换为无量纲常微分方程(ode)以及支持参数来重现这些数学方程,以控制流体质量的运动和扩散。利用人工智能神经网络(AI-NN)和Levenberg-Marquardt方法(LMM)推导计算解,分析热源((lambda ))、磁效应参数((M))、施密特数((Sc))、化学反应效应(({c}_{text{r}}))、布朗运动参数(({N}_{text{b}}))、热驱效应({(N}_{text{t}}))、辐射数((Rd))等热物理因素的影响。热浮力值((alpha ))。利用Darcy-Forchheimer流体模型(DFM)控制系统生成的数据集,通过Mathematica和MATLAB技术提取近似解。研究结果表明,这些参数对速度、温度和质量浓度有显著影响,在14种不同的情况下观察到变化。该研究的计算框架通过回归分析、误差直方图和适应度函数验证,确保了较高的准确性,均方误差(MSE)值清晰地表示出来。这种新方法为现有模型提供了一个有希望的替代方案,增强了对磁化纳米流体中传热传质的理解。在速度(left( {f^{prime } left( eta right)} right))、温度(left( {theta left( eta right)} right))、质量浓度(left(phi left(eta right)right))范围为({10}^{-14}) ~ ({10}^{-9})的不同工况下进行了性能分析。回归分析(left(RAright))、误差直方图(left(EHright))和函数适应度状态((FF))负责AI-NN LMM图形化展示MSE的验证和准确性。
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引用次数: 0
Molecular dynamics simulation of the microscopic mechanism of argon-based gold nanofluids 氩基金纳米流体微观机理的分子动力学模拟
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-12-12 DOI: 10.1007/s10973-024-13858-2
Liang Zhang, Jiabai Song, Taiyan Lu, Hongfa Liu, Hairui Wang, Yuyan Jing

Nanofluid (NF) as a new type of high thermal conductivity fluid, macroscopic research methods can only observe the macroscopic change of thermal conductivity of NF, but cannot further reveal the microscopic mechanism of nanoparticles. In this paper, the microscopic mechanism of thermal conductivity enhancement of NF was simulated based on non-equilibrium molecular dynamics method (NEMD), and the thermal conductivities of argon-based gold (Au–Ar) NF with different volume fractions and Au nanoparticle sizes are simulated separately, and the radial distribution functions, system densities, and tracking atom trajectories are computed to explore the mechanism of the action of the change in thermal conductivity of the nanofluids induced by nanoparticles at the microscopic level. It was found that the thermal conductivity of Au–Ar–NF system is positively correlated with the volume fraction of nanoparticles and negatively correlated with the particle size. When the NP particle size was 0.8 nm and the volume fraction was 6.0%, the NF thermal conductivity increased by 65.7% compared to the base solution. The key finding of the study was that the underlying liquid atoms on the surface of the nanoparticles form a non-fugitive adsorption layer, and that their arrangement resembles the ordered arrangement of a solid. In the model with r (NP) = 0.8 nm, the highest thermal conductivity was 1.21 times that of the base solution, and the thickness of the adsorption layer on the particle surface was about 0.35 nm. Generally speaking, the addition of nanoparticles alters the atomic configuration of NF, resulting in NF displaying a solid-like microstructure, which significantly increases the thermal conductivity of NF.

纳米流体作为一种新型的高导热流体,宏观研究方法只能观察到纳米流体导热系数的宏观变化,而不能进一步揭示纳米颗粒的微观机理。本文基于非平衡分子动力学方法(NEMD)模拟了纳米材料增强导热性的微观机理,分别模拟了不同体积分数和不同金纳米颗粒尺寸的氩基金(Au - ar)纳米材料的导热性,并对其径向分布函数、体系密度、通过计算原子轨迹,从微观层面探讨纳米颗粒诱导纳米流体热导率变化的作用机制。研究发现,Au-Ar-NF体系的导热系数与纳米颗粒体积分数呈正相关,与粒径呈负相关。当NP粒径为0.8 nm,体积分数为6.0%时,其导热系数较碱溶液提高了65.7%。这项研究的关键发现是,纳米颗粒表面的液体原子形成了一个非逃逸的吸附层,它们的排列类似于固体的有序排列。在r (NP) = 0.8 nm的模型中,热导率最高为碱溶液的1.21倍,颗粒表面的吸附层厚度约为0.35 nm。一般来说,纳米颗粒的加入改变了NF的原子构型,使NF呈现出类似固体的微观结构,从而显著提高了NF的导热性。
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引用次数: 0
A review of the research progress of cooling technology in deep mining 深部采矿冷却技术研究进展综述
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-12-11 DOI: 10.1007/s10973-024-13719-y
Min Qu, Yongliang Zhang, Xilong Zhang, Hongwei Mu, Shili Yin, Yunfei Liu, Lijing Meng

High-temperature heat damage is a common phenomenon in the field of mine mining, and as the mining depth increases, the degree of underground heat damage is also increasing, which seriously restricts the productivity of the mine and affects the physical and mental health of workers. Based on the mining situation of mineral resources, this paper summarized the formation mechanism and heat dissipation characteristics of different heat sources of mine high-temperature heat damage and analyzed the influence of heat damage on the mine production process and human physiological and biochemical indicators. Then, we summarized the existing cooling technologies, mainly divided into non-artificial and artificial cooling technology. The cooling mechanism and application status of cooling technology were introduced and analyzed and compared the characteristics and application scope of each cooling technology, which have specific guiding and reference significance for the selection of cooling technology for different degrees of heat damage mines. Finally, building upon the low-temperature rock formation pre-cooling technology, a novel concept for quantifying the mine inlet airflow volume was advanced, along with the formulation of a relationship model that correlates the geometry of the roadway with the temperature alteration of the airflow. This development laid a theoretical foundation for harnessing the ground temperature effect in shallow roadways to regulate the temperature of the mine’s inlet airflow, thereby enhancing the working environment at the mine’s working face.

高温热损伤是矿山开采领域普遍存在的现象,而且随着开采深度的增加,井下热损伤程度也在不断加大,严重制约了矿山的生产效率,影响了工人的身心健康。本文结合矿产资源的开采情况,总结了矿山高温热损伤不同热源的形成机理和散热特点,分析了热损伤对矿山生产过程和人体生理生化指标的影响。然后对现有的冷却技术进行了总结,主要分为非人工冷却技术和人工冷却技术。介绍了冷却技术的冷却机理和应用现状,分析比较了各种冷却技术的特点和适用范围,对不同程度热损矿山冷却技术的选择具有具体的指导和参考意义。最后,在低温岩层预冷技术的基础上,提出了矿井进风量量化的新概念,并建立了巷道几何形状与气流温度变化的关系模型。这为利用浅埋巷道地温效应调节矿井进风温度,从而改善矿井工作面工作环境奠定了理论基础。
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引用次数: 0
Impact of the botanic origin of starch on the physicochemical properties and thermal kinetic behavior of high-density energy starch nitrate biopolymer 淀粉的植物来源对高密度能量淀粉硝酸盐生物聚合物理化性质和热动力学行为的影响
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-12-11 DOI: 10.1007/s10973-024-13650-2
Nassima Sahnoun, Amir Abdelaziz, Djalal Trache, Ahmed Fouzi Tarchoun, Wissam Bessa, Hani Boukeciat, Amel Meslem, Sourbh Thakur, Thomas M. Klapötke

This study delved into the influence of starch botanic origin on the ultimate physicochemical properties and energetic attributes of modified starches. To accomplish this, starches extracted from potato (PS), corn (CS), and wheat (WS) underwent chemical modification via nitration, resulting in the creation of high-energy polysaccharides (NPS), (NCS), and (NWS), respectively, which were then subjected to comprehensive characterization. The principal finding of this investigation underscored the substantial impact of starch botanical origin on the properties of the resultant starch nitrate. Notably, the synthesized starch nitrate exhibited promising characteristics, including heightened density and elevated nitrogen content. Moreover, it is observed that both the short and long-term thermal stability of starch nitrate are influenced by the botanical origin of the starch, alongside their mechanical sensitivities, which diminish with higher nitrogen content. Through kinetic degradation analysis of all prepared nitro-starches, it was observed that the Arrhenius parameters decreased as nitrogen content increased. Specifically, starch nitrate derived from corn (NCS), with lower nitrogen content, displayed a higher energy of activation (Ea), while potato-derived starch nitrate (NPS), with the highest nitrogen concentration, exhibited the lowest activation energy value, indicative of its heightened reactivity.

本研究探讨了淀粉的植物来源对变性淀粉的最终理化性质和能量特性的影响。为了实现这一目标,从马铃薯(PS)、玉米(CS)和小麦(WS)中提取的淀粉通过硝化进行化学改性,分别产生高能量多糖(NPS)、高能量多糖(NCS)和高能量多糖(NWS),然后对其进行全面表征。本研究的主要发现强调了淀粉植物来源对所得硝酸盐淀粉性质的重大影响。值得注意的是,合成的硝酸淀粉具有较高的密度和氮含量。此外,我们还观察到,淀粉的短期和长期热稳定性都受到淀粉的植物来源的影响,以及它们的机械敏感性,这些敏感性随着氮含量的增加而降低。通过对制备的亚硝基淀粉的动力学降解分析发现,随着氮含量的增加,Arrhenius参数降低。其中,氮含量较低的玉米衍生的硝酸淀粉(NCS)具有较高的活化能(Ea),而氮含量最高的马铃薯衍生的硝酸淀粉(NPS)具有最低的活化能,表明其反应活性较高。
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引用次数: 0
Thermal performance of MWCNTs-Al2O3 hybrid nanofluid flow in heated tubes, entropy production, and environmental assessment MWCNTs-Al2O3混合纳米流体在加热管中的热性能、熵产和环境评价
IF 3 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-12-11 DOI: 10.1007/s10973-024-13797-y
Ammar Laichi, Aicha Bouhezza, Omar Kholai, Aissa Atia, Mohamed Teggar, Hasan Köten

The surge in electricity generation demand has led to heightened CO2 emissions and climate change; thus, the emphasis on transitioning to renewable energy (solar energy) and enhancing energy efficiency (hybrid nanofluids) is emerged as the most significant solutions. The investigation examines MWCNTs-Al2O3-water hybrid nanofluid laminar forced convection in a circular duct subject to a uniform heat flux. The effect of MWCNTs nanoparticles percentage ratio (0 to 100%), total nanoparticles volume fraction (1 to 4%), and Reynolds number (100 to 2100) on thermal and hydraulic performance, entropy generation, and CO2 emissions, embodied energy, and water saving is investigated numerically. ANSYS Fluent was employed to solve this issue using the finite volume method; validation of the current work demonstrates strong concordance with experimental, numerical, and theoretical investigations. Outcomes show that increasing Reynolds number, total nanoparticles volume fraction, and percentage ratio of MWCNT in hybrid nanofluid significantly affects the hydrodynamic and thermal entry region in terms of average velocity, outlet temperature, and the temperature gap in the system. The heat transfer coefficient enhances by up to 50.96%. However, the maximum pressure drop, Nusselt number, and thermal efficiency increased by 769.97%, 24.75%, and 24.75%, respectively. Moreover, the entropy production due to the thermal irreversibility was reduced by 32.65% compared with water showed for 4% of (100%:0) MWCNTs-Al2O3–water at Reynolds number about 2100. Furthermore, the embodied energy and water consumption, tube mass, and CO2 emissions are reduced by 1.81041 MJ, 9.00691 m3, 0.00831 kg, and 1.09892 kg, respectively.

发电需求的激增导致二氧化碳排放增加和气候变化;因此,强调向可再生能源(太阳能)过渡和提高能源效率(混合纳米流体)成为最重要的解决方案。研究了mwcnts - al2o3 -水混合纳米流体层流强迫对流在圆形管道受到均匀的热流。研究了MWCNTs纳米颗粒百分比比(0 ~ 100%)、总纳米颗粒体积分数(1 ~ 4%)和雷诺数(100 ~ 2100)对热工性能、水力性能、熵产、CO2排放、体现能和节水的影响。采用ANSYS Fluent有限体积法求解该问题;当前工作的验证显示了与实验、数值和理论研究的强烈一致性。结果表明,增加混合纳米流体中雷诺数、总纳米颗粒体积分数和MWCNT的百分比,对系统的平均速度、出口温度和温度间隙都有显著影响。换热系数提高了50.96%。最大压降、努塞尔数和热效率分别提高了769.97%、24.75%和24.75%。此外,在雷诺数为2100左右时,与4% (100%:0)MWCNTs-Al2O3-water相比,由于热不可逆性而产生的熵减少了32.65%。减少了1.81041 MJ、9.00691 m3、0.00831 kg和1.09892 kg的隐含能量和水耗、管质量和二氧化碳排放量。
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Journal of Thermal Analysis and Calorimetry
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