Boris A. Voronin, Jonathan Tennyson, Tatyana Yu. Chesnokova, Aleksei V. Chentsov, Aleksandr D. Bykov
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引用次数: 0
Abstract
The absorption spectrum of H219O, a radioactive isotopologue of the water molecule, is predicted using variational nuclear motion calculated based on a high precision potential energy function and ab initio dipole moment surface. Vibrational - rotational energy levels and wave functions, line centers and Einstein coefficients for dipole transitions are calculated. Predicted transition wavenumbers are improved by extrapolating known empirical energy levels of the stable H216O, H217O and H218O isotopologues to H219O. A line list for possible atmospheric application is presented which includes air line broadening coefficients. The calculations span a wide spectral range covering infrared and visible wavelengths, and are appropriate for temperatures up to 1000 K. Windows suitable for observing absorption by H219O are identified and comparisons made with the infrared spectra of water vapor in natural abundance, H215O and H214O.
利用基于高精度势能函数和 ab initio 偶极矩表面计算的变异核运动预测了水分子的放射性同位素 H219O 的吸收光谱。计算了偶极转换的振动-旋转能级和波函数、线中心和爱因斯坦系数。通过将稳定的 H216O、H217O 和 H218O 同素异形体的已知经验能级外推至 H219O,改进了预测的转换波数。还提供了一份可能应用于大气的谱线表,其中包括空气谱线展宽系数。计算结果的光谱范围很广,涵盖了红外线和可见光波长,适用于高达 1000 K 的温度。
期刊介绍:
An international periodical publishing original papers, letters, review papers and short communications on nuclear chemistry. The subjects covered include: Nuclear chemistry, Radiochemistry, Radiation chemistry, Radiobiological chemistry, Environmental radiochemistry, Production and control of radioisotopes and labelled compounds, Nuclear power plant chemistry, Nuclear fuel chemistry, Radioanalytical chemistry, Radiation detection and measurement, Nuclear instrumentation and automation, etc.