Tao Wang, Jiaxu Ma, Jie Ma, Xiaopei Cai, Yaping Cui, Ruilin Ning, Jin Li
{"title":"Understanding progressive aging of bitumen-rubber composite binder and its separate phases considering biphase interactions","authors":"Tao Wang, Jiaxu Ma, Jie Ma, Xiaopei Cai, Yaping Cui, Ruilin Ning, Jin Li","doi":"10.1617/s11527-024-02449-0","DOIUrl":null,"url":null,"abstract":"<div><p>Bitumen-rubber composite binder (BRCB) has great potential to construct durable road pavement infrastructures that can withstand the environmental aging. However, the aging behavior of BRCB has not been fully investigated so far, especially from the perspective of biphase system with the phase interactions consideration. Therefore, this study investigated the progressive aging behavior of BRCB in terms of separate bitumen phase and rubber phase as well as the biphase interactions, to further understand the mechanisms behind. The results showed that the bitumen phase gradually dominated rheological performance of BRCB with the progressive aging. On the contrast, the fatigue resistance of BRCB was constantly controlled by its rubber phase in the aging process. Secondly, the rubber phase gradually dissolved during the aging with a decrease in the crosslinking density, although the change rate slowed down with the aging duration. The breakdown pattern of rubber structure was further identified as the simultaneous scission of crosslinking bonds and main chains. Besides, biphase interactions during progressive aging primarily included the absorption of light components from bitumen phase into rubber phase and the release of long rubber molecular chains and fillers from rubber phase into bitumen phase. Overall, the progressive aging of BRCBs can be considered as the combined effect of the secondary bitumen-rubber biphase interactions after the first-stage production and thermal oxidation of the bitumen phase.</p><h3>Graphical abstract</h3>\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":691,"journal":{"name":"Materials and Structures","volume":"57 8","pages":""},"PeriodicalIF":3.4000,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials and Structures","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1617/s11527-024-02449-0","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CONSTRUCTION & BUILDING TECHNOLOGY","Score":null,"Total":0}
引用次数: 0
Abstract
Bitumen-rubber composite binder (BRCB) has great potential to construct durable road pavement infrastructures that can withstand the environmental aging. However, the aging behavior of BRCB has not been fully investigated so far, especially from the perspective of biphase system with the phase interactions consideration. Therefore, this study investigated the progressive aging behavior of BRCB in terms of separate bitumen phase and rubber phase as well as the biphase interactions, to further understand the mechanisms behind. The results showed that the bitumen phase gradually dominated rheological performance of BRCB with the progressive aging. On the contrast, the fatigue resistance of BRCB was constantly controlled by its rubber phase in the aging process. Secondly, the rubber phase gradually dissolved during the aging with a decrease in the crosslinking density, although the change rate slowed down with the aging duration. The breakdown pattern of rubber structure was further identified as the simultaneous scission of crosslinking bonds and main chains. Besides, biphase interactions during progressive aging primarily included the absorption of light components from bitumen phase into rubber phase and the release of long rubber molecular chains and fillers from rubber phase into bitumen phase. Overall, the progressive aging of BRCBs can be considered as the combined effect of the secondary bitumen-rubber biphase interactions after the first-stage production and thermal oxidation of the bitumen phase.
期刊介绍：
Materials and Structures, the flagship publication of the International Union of Laboratories and Experts in Construction Materials, Systems and Structures (RILEM), provides a unique international and interdisciplinary forum for new research findings on the performance of construction materials. A leader in cutting-edge research, the journal is dedicated to the publication of high quality papers examining the fundamental properties of building materials, their characterization and processing techniques, modeling, standardization of test methods, and the application of research results in building and civil engineering. Materials and Structures also publishes comprehensive reports prepared by the RILEM’s technical committees.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
