Dual robust electrode-electrolyte interfaces enabled by fluorinated electrolyte for high-performance zinc metal batteries

IF 17.3 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Matter Pub Date : 2024-11-06 DOI:10.1016/j.matt.2024.08.002
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Abstract

Rechargeable zinc metal batteries (ZMBs) are promising for fabricating low-cost, safe, and high-energy-density storage systems. However, ZMBs typically undergo interfacial side reactions and cathode dissolution during cycling, resulting in the depletion of active materials and performance decay of batteries. Here, we develop a localized high-concentration fluorinated electrolyte featuring a high fluorine/oxygen atomic ratio (388.72%) with beneficial solvation chemistry, fostering the simultaneous formation of a cathode-electrolyte interphase (CEI) enriched with C–F bonds and a ZnF2-dominant solid-electrolyte interphase (SEI). The constructed robust electrode-electrolyte interfaces (EEIs) contribute to dendrite-free zinc deposition and a highly stable cathode, demonstrating soft-packed Zn||Mn-doped V2O5 batteries with an exceptional energy density (91.25 Wh kg−1cathode+anode) and capacity retention (90.5%) over 500 cycles employing a limited zinc supply. The anode-free ZMBs deliver a record power density of 153.9 Wh kg−1cathode+anode with a high capacity retention of 80.2% over 1,500 cycles. This research provides significant insights for interface construction in multivalent ion batteries.

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氟化电解质为高性能锌金属电池提供了坚固的电极-电解质双界面
可充电锌金属电池(ZMB)在制造低成本、安全和高能量密度存储系统方面前景广阔。然而,锌金属电池在循环过程中通常会发生界面副反应和阴极溶解,导致活性材料耗竭和电池性能下降。在这里,我们开发了一种局部高浓度含氟电解质,它具有高氟/氧原子比(388.72%)和有利的溶解化学性质,可同时形成富含 C-F 键的阴极-电解质相(CEI)和以 ZnF2 为主导的固态-电解质相(SEI)。所构建的坚固电极-电解质界面(EEIs)有助于实现无枝晶锌沉积和高度稳定的阴极,在使用有限锌供应的 500 次循环过程中,展示了能量密度(91.25 Wh kg-1(阴极+阳极))和容量保持率(90.5%)极高的软包装锌||锰掺杂 V2O5 电池。无阳极 ZMB 的功率密度达到创纪录的 153.9 Wh kg-1(阴极+阳极),在 1,500 次循环中的容量保持率高达 80.2%。这项研究为多价离子电池的界面构造提供了重要启示。
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来源期刊
Matter
Matter MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
26.30
自引率
2.60%
发文量
367
期刊介绍: Matter, a monthly journal affiliated with Cell, spans the broad field of materials science from nano to macro levels,covering fundamentals to applications. Embracing groundbreaking technologies,it includes full-length research articles,reviews, perspectives,previews, opinions, personnel stories, and general editorial content. Matter aims to be the primary resource for researchers in academia and industry, inspiring the next generation of materials scientists.
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