Ultrastable Ruthenium-Based Electrocatalysts for Hydrogen Oxidation Reaction in High-Temperature Polymer Electrolyte Membrane Fuel Cells

IF 9.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY CCS Chemistry Pub Date : 2024-08-13 DOI:10.31635/ccschem.024.202404436
Miaoyu Li, Pupu Yang, Wenjie Lv, Qie Liu, Yujie Wu, Shiqian Du, Gen Huang, Zuyao Jiang, Jingjing Wang, Yabin Xu, Yangyang Zhou, Shanfu Lu, Li Tao, Shuangyin Wang
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Abstract

Ruthenium (Ru) is a promising electrocatalyst for hydrogen oxidation reaction (HOR) due to the similar metal hydrogen bond energy to Pt. However, Ru is easily deactivated or dissolved under an oxidation potential, which makes it unavailable in proton exchange membrane fuel cells. In this work, ultrastable Ru-based electrocatalysts for HOR in high-temperature polymer electrolyte membrane fuel cells (HT-PEMFCs) were developed by Mo doping. Under the operation conditions of HT-PEMFCs, thermal reduction inhibited the production of amorphous Ru oxide (RuO2) in the Ru-based electrocatalysts during the HOR. Mo doping significantly improved the stability of the electrocatalyst by decreasing the reduction temperature of RuO2 and accelerating the HOR by reducing the adsorption of H*. RuMo/C exhibited excellent HOR activity at high temperatures due to thermal reduction inhibition of electrooxidation; the fabricated HT-PEMFCs exhibited long-term stability and a 1050 mW cm−2 peak power density, comparable to the commercial Pt catalyst. This work provides a novel strategy for designing electrocatalysts by combining material intrinsic properties and work conditions, which could promote the development of advanced electrocatalysts for HT-PEMFCs.

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用于高温聚合物电解质膜燃料电池中氢氧化反应的超稳定钌基电催化剂
钌(Ru)与铂(Pt)具有相似的金属氢键能量,因此是一种很有前途的氢氧化反应(HOR)电催化剂。然而,Ru 在氧化电位下很容易失活或溶解,因此无法用于质子交换膜燃料电池。在这项工作中,通过掺杂 Mo,开发出了用于高温聚合物电解质膜燃料电池(HT-PEMFC)中氢键的超稳定 Ru 基电催化剂。在高温聚合物电解质膜燃料电池的运行条件下,热还原抑制了 Ru 基电催化剂中无定形 Ru 氧化物(RuO2)在 HOR 过程中的生成。掺杂 Mo 可降低 RuO2 的还原温度,并通过减少 H* 的吸附加速 HOR,从而大大提高电催化剂的稳定性。由于热还原抑制了电氧化作用,RuMo/C 在高温下表现出优异的 HOR 活性;所制备的 HT-PEMFC 具有长期稳定性和 1050 mW cm-2 的峰值功率密度,与商用铂催化剂相当。这项工作提供了一种结合材料固有特性和工作条件设计电催化剂的新策略,可促进用于 HT-PEMFCs 的先进电催化剂的开发。
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来源期刊
CCS Chemistry
CCS Chemistry Chemistry-General Chemistry
CiteScore
13.60
自引率
13.40%
发文量
475
审稿时长
10 weeks
期刊介绍: CCS Chemistry, the flagship publication of the Chinese Chemical Society, stands as a leading international chemistry journal based in China. With a commitment to global outreach in both contributions and readership, the journal operates on a fully Open Access model, eliminating subscription fees for contributing authors. Issued monthly, all articles are published online promptly upon reaching final publishable form. Additionally, authors have the option to expedite the posting process through Immediate Online Accepted Article posting, making a PDF of their accepted article available online upon journal acceptance.
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