CCS Chemistry最新文献

{"title":"Red-Light-Driven CO2 Reduction in Aqueous Solution Using CdSe Quantum Dots and Cobalt Molecular Catalysts","authors":"Kai Guo, Zuting Wei, Bixian Chen, Shuang Yang, Jingxiang Lei, Huiqing Yuan & Zhiji Han1MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, IGCME, Sun Yat-sen University, Guangzhou 5102752School of Chemistry and Environment, Jiaying University, Meizhou, Guangdong 5140153College of Light Chemical Industry and Materials Engineering, Shunde Polytechnic, Foshan 528333","doi":"10.31635/ccschem.024.202405179","DOIUrl":"https://doi.org/10.31635/ccschem.024.202405179","url":null,"abstract":"CCS Chemistry, Ahead of Print.<br/>The development of inexpensive artificial photosynthetic (AP) systems, utilizing low-energy sunlight for CO2reduction remains a significant challenge. Here, we report a red-light-driven CO2reduction system with pyridinethiolate-capped CdSe quantum dots (...","PeriodicalId":9810,"journal":{"name":"CCS Chemistry","volume":"11 1","pages":""},"PeriodicalIF":11.2,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143084187","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Direct α-Cross-Coupling of Benzylamines with Bulky Alkyl Iodides Enabled by Radical Carbonyl Catalysis","authors":"Chengkang Hou, Longjie Huang, Lei Wang, Siqi Liu, Guoqing Zhao, Kuiling Ding & Baoguo Zhao1The Education Ministry Key Lab of Resource Chemistry, Shanghai Frontiers Science Center of Biomimetic Catalysis, College of Chemistry and Materials Science, Shanghai Normal University, Shanghai 2002342The Frontiers Science Center for Transformative Molecules and the School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240","doi":"10.31635/ccschem.025.202405131","DOIUrl":"https://doi.org/10.31635/ccschem.025.202405131","url":null,"abstract":"CCS Chemistry, Ahead of Print.<br/>α-Amino radicals are highly reactive and synthetically valuable species. However, their instability and short lifetime limit their applications in organic synthesis. This work has demonstrated a catalytic strategy for in situ generation of persistent α-...","PeriodicalId":9810,"journal":{"name":"CCS Chemistry","volume":"11 1","pages":""},"PeriodicalIF":11.2,"publicationDate":"2025-02-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143084071","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Modulating Static and Dynamic Magnetizations of Ytterbium(III) Coordination Polymers by Light-Induced Radicals","authors":"Xiaoshuang Gou, Yuewei Wu, Hanqi Wen, Liang Li, Wenlong Lan, Ning Liu, Shiqi Zhang, Liviu Ungur, Peng Cheng & Wei Shi1Frontiers Science Center for New Organic Matter, Key Laboratory of Advanced Energy Materials Chemistry (MOE) and State Key Laboratory of Advanced Chemical Power Sources, College of Chemistry, Nankai University, Tianjin 3000712Department of Chemistry, National University of Singapore, Singapore 117543","doi":"10.31635/ccschem.024.202404999","DOIUrl":"https://doi.org/10.31635/ccschem.024.202404999","url":null,"abstract":"CCS Chemistry, Ahead of Print.<br/>Light-induced transformation from diamagnetic ligand to paramagnetic radical offers a unique approach to modulating the magnetization dynamics of magnetic compounds. In this study, we present a two-dimensional Yb(III) coordination polymer1and its Y(III)-...","PeriodicalId":9810,"journal":{"name":"CCS Chemistry","volume":"7 1","pages":""},"PeriodicalIF":11.2,"publicationDate":"2025-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142934859","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Selective Dearomatic Deuteration of (Het)arenes via Electrophotocatalysis","authors":"Ya-Jing Chen, Dong Wei, Cheng Wang, Shu-Lin Meng, Bin Chen, Chen-Ho Tung & Li-Zhu Wu1Key Laboratory of Photochemical Conversion and Optoelectronic Materials, New Cornerstone Science Laboratory, Technical Institute of Physics and Chemistry, The Chinese Academy of Sciences, Beijing 1001902School of Future Technology, University of Chinese Academy of Sciences, Beijing 100049","doi":"10.31635/ccschem.024.202405016","DOIUrl":"https://doi.org/10.31635/ccschem.024.202405016","url":null,"abstract":"CCS Chemistry, Ahead of Print.<br/>Developing green and practicald-labeling techniques is valuable and in high demand for medical chemistry, mechanistic studies, and materials science. Although dearomatic deuteration of simple aromatic systems represents an attractive protocol to accessd-...","PeriodicalId":9810,"journal":{"name":"CCS Chemistry","volume":"5 1","pages":""},"PeriodicalIF":11.2,"publicationDate":"2025-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142934858","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Supramolecularly Activatable Photosensitizer: Controllable Cyanine J-Aggregation for Efficient Photodynamic Therapy","authors":"He Ma, Weiquan Xu, Xingchen Tang, Yushen Kang, Jiang-Fei Xu & Xi ZhangKey Lab of Organic Optoelectronics & Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084","doi":"10.31635/ccschem.024.202405042","DOIUrl":"https://doi.org/10.31635/ccschem.024.202405042","url":null,"abstract":"CCS Chemistry, Ahead of Print.<br/>An activatable photosensitizer that could induce phototoxicity only in target sites is highly demanded to overcome the potential off-target toxicity in photodynamic therapy. It is of great significance to design tailored photosensitizers with a new caging ...","PeriodicalId":9810,"journal":{"name":"CCS Chemistry","volume":"22 1","pages":""},"PeriodicalIF":11.2,"publicationDate":"2025-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142934857","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enantioselective Synthesis of Chiral Isoindolines via Palladium-Catalyzed Asymmetric Allylic C–H Amination","authors":"","doi":"10.31635/ccschem.024.202404613","DOIUrl":"https://doi.org/10.31635/ccschem.024.202404613","url":null,"abstract":"CCS Chemistry, Ahead of Print.<br/>","PeriodicalId":9810,"journal":{"name":"CCS Chemistry","volume":"19 1","pages":""},"PeriodicalIF":11.2,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142563197","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Divide and Conquer: Desymmetrization Separates Charge and Mass Transport in Porphyrinic Covalent Organic Frameworks for Artificial Photosynthesis","authors":"","doi":"10.31635/ccschem.024.202404867","DOIUrl":"https://doi.org/10.31635/ccschem.024.202404867","url":null,"abstract":"CCS Chemistry, Ahead of Print.<br/>","PeriodicalId":9810,"journal":{"name":"CCS Chemistry","volume":"63 1","pages":""},"PeriodicalIF":11.2,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142563254","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Author Spotlight","authors":"","doi":"10.31635/ccschem.024.202401017ed2","DOIUrl":"https://doi.org/10.31635/ccschem.024.202401017ed2","url":null,"abstract":"CCS Chemistry, Volume 6, Issue 11, Page 2623-2626, November 2024.<br/>","PeriodicalId":9810,"journal":{"name":"CCS Chemistry","volume":"45 1","pages":""},"PeriodicalIF":11.2,"publicationDate":"2024-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142580387","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Toward the Synthesis of Pentaheptite Substructure: The Cyclopenta[ef]heptalene to Phenanthrene Rearrangement","authors":"Chang Wang, Chenyu Hu, Weize Wang, Jun Yang, Junzhi Liu","doi":"10.31635/ccschem.024.202404765","DOIUrl":"https://doi.org/10.31635/ccschem.024.202404765","url":null,"abstract":"<p>Novel carbon allotropes have long been pursued in synthetic chemistry and materials science, and graphene has been the most well-investigated carbon nanostructure in the past decade. However, an analogous carbon pentaheptite with equal numbers of pentagons and heptagons has not yet been synthesized because designing and synthesizing nonhexagon motifs along two dimensions is challenging. During the synthesis of a pentaheptite substructure (or named nanopentaheptite, <b xmlns:bkstg=\"http://www.atypon.com/backstage-ns\" xmlns:fn=\"http://www.w3.org/2005/xpath-functions\" xmlns:pxje=\"java:com.atypon.frontend.services.impl.PassportXslJavaExtentions\" xmlns:urlutil=\"java:com.atypon.literatum.customization.UrlUtil\" xmlns:xlink=\"http://www.w3.org/1999/xlink\">\u0000<bold>NPH</bold></b>), which contain four pentagon-heptagon pairs and one heptalene unit, unexpected cyclopenta[<i>ef</i>]heptalene-into-phenanthrene rearrangements were observed for the first time, yielding two novel compounds (<b xmlns:bkstg=\"http://www.atypon.com/backstage-ns\" xmlns:fn=\"http://www.w3.org/2005/xpath-functions\" xmlns:pxje=\"java:com.atypon.frontend.services.impl.PassportXslJavaExtentions\" xmlns:urlutil=\"java:com.atypon.literatum.customization.UrlUtil\" xmlns:xlink=\"http://www.w3.org/1999/xlink\">\u0000<bold>NPH-R1</bold></b> and <b xmlns:bkstg=\"http://www.atypon.com/backstage-ns\" xmlns:fn=\"http://www.w3.org/2005/xpath-functions\" xmlns:pxje=\"java:com.atypon.frontend.services.impl.PassportXslJavaExtentions\" xmlns:urlutil=\"java:com.atypon.literatum.customization.UrlUtil\" xmlns:xlink=\"http://www.w3.org/1999/xlink\">\u0000<bold>NPH-R2</bold></b>). Experimental and theoretical results demonstrated that the <b xmlns:bkstg=\"http://www.atypon.com/backstage-ns\" xmlns:fn=\"http://www.w3.org/2005/xpath-functions\" xmlns:pxje=\"java:com.atypon.frontend.services.impl.PassportXslJavaExtentions\" xmlns:urlutil=\"java:com.atypon.literatum.customization.UrlUtil\" xmlns:xlink=\"http://www.w3.org/1999/xlink\">\u0000<bold>NPH</bold></b> series exhibits narrower energy gaps than that of their hexagonal analog with similar size (e.g., hexa-peri-hexabenzocoronene, <b xmlns:bkstg=\"http://www.atypon.com/backstage-ns\" xmlns:fn=\"http://www.w3.org/2005/xpath-functions\" xmlns:pxje=\"java:com.atypon.frontend.services.impl.PassportXslJavaExtentions\" xmlns:urlutil=\"java:com.atypon.literatum.customization.UrlUtil\" xmlns:xlink=\"http://www.w3.org/1999/xlink\">\u0000<bold>HBC</bold></b>). Our work reported herein, based on the azulene chemistry, provides new insights into the preparation of novel carbon allotrope pentaheptite nanostructures.</p>","PeriodicalId":9810,"journal":{"name":"CCS Chemistry","volume":"79 1","pages":""},"PeriodicalIF":11.2,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142556295","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Universal Visible-Light Photoiniferter Polymerization","authors":"Shuangqi Lian, Steven P. Armes, Zesheng An","doi":"10.31635/ccschem.024.202404894","DOIUrl":"https://doi.org/10.31635/ccschem.024.202404894","url":null,"abstract":"<p>Currently, there is no versatile method for the synthesis of high molecular weight (MW) polymers by controlled radical polymerization from a broad range of monomers using a single agent. Herein, we report a universal photoiniferter reversible addition-fragmentation chain transfer (RAFT) polymerization formulation using a suitable pyrazole-based chain transfer agent (CTA) combined with blue light irradiation. Well-controlled polymerization was observed for methyl methacrylate (MMA), methyl acrylate (MA), <i>N</i>,<i>N</i>-dimethylacrylamide (DMA), and <i>N</i>-vinylpyrrolidone (NVP). High polymerization rates were achieved, attributed to the high molar absorption coefficient of the pyrazole-based CTA and its rapid rate of photolysis. Poly(methyl acrylate) (PMA) and poly(<i>N</i>,<i>N</i>-dimethylacrylamide) (PDMA) syntheses yielded low-dispersity ultrahigh MW chains (&gt;10⁶ g mol⁻¹, <i>Ð</i> &lt; 1.3). High end-group fidelity enabled the preparation of well-defined high MW diblock copolymers comprising both more activated and less activated monomers, including PDMA-<i>b</i>-PNVP and PMA-<i>b</i>-PNVP. Such syntheses demonstrated that visible light-mediated photoiniferter RAFT polymerization conducted using pyrazole-based CTAs was both highly efficient and versatile.</p>","PeriodicalId":9810,"journal":{"name":"CCS Chemistry","volume":"6 1","pages":""},"PeriodicalIF":11.2,"publicationDate":"2024-10-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142556297","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}