Synthesis of Highly Ordered Mesoporous Silica (SBA-16) to Support Titania (TiO2) Nanoparticles for Enhancing the Degradation of Diuron Herbicide

IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Silicon Pub Date : 2024-08-31 DOI:10.1007/s12633-024-03124-3
Chutima Vanichvattanadecha, Angkhana Jaroenworaluck, Pimpun Henpraserttae, Panida Wimuktiwan
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Abstract

In this study, highly ordered mesoporous silica (SBA-16) were synthesized by a one-step sol–gel method, relating to the interaction with the self-assembly of the non-ionic surfactant, pluronic F127 under an acidic condition without the hydrothermal process. SBA-16 was further incorporated with titanium dioxide (TiO2) with varied Si/Ti ratios (11.2, 2.8 and 0.7) to optimize a suitable condition for producing SBA-16/TiO2 composites. After calcination, the composites were characterized by using various techniques to evaluate pore characteristics, morphologies and phase present. Typically, the highly ordered porous structure of the synthesized SBA-16 was confirmed by low angle X-ray analysis (LAXRD) and N2 adsorption isotherms. TiO2 nanoparticles were found at the surfaces of SBA-16 of each composite based on the HR-TEM images. Diuron herbicide in aqueous solutions (50 ppm of the initial concentration) was used as a polluted model for studying on the photocatalytic activity of the composites under an artificial UV illumination for 24 h. Experimental results revealed that SBA-16 could assist on diuron reduction in the dark condition by the adsorption process. Diuron in the solutions were fully degraded by the synthesized TiO2 and the SBA-16/TiO2 composite (0.7 Si/Ti ratio) within 24 h of the UV illumination. In addition, it revealed that SBA-16 could assist on diuron reduction in the dark condition by the adsorption process. The degradation was calculated and followed to the first order kinetic model. Finally, a mechanism of the degradation was discussed and proposed.

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合成高有序介孔二氧化硅(SBA-16)以支持钛(TiO2)纳米粒子,从而增强迪古隆除草剂的降解能力
本研究采用一步溶胶-凝胶法合成了高有序介孔二氧化硅(SBA-16),该方法与非离子表面活性剂 pluronic F127 在酸性条件下的自组装相互作用有关,无需水热过程。为了优化生产 SBA-16/TiO2 复合材料的合适条件,进一步将 SBA-16 与不同硅/钛比率(11.2、2.8 和 0.7)的二氧化钛(TiO2)结合在一起。煅烧后,使用各种技术对复合材料进行表征,以评估孔隙特征、形态和相的存在。低角 X 射线分析(LAXRD)和 N2 吸附等温线证实了合成的 SBA-16 具有高度有序的多孔结构。根据 HR-TEM 图像,在每种复合材料的 SBA-16 表面都发现了 TiO2 纳米颗粒。实验结果表明,在黑暗条件下,SBA-16 可通过吸附过程帮助降解敌草隆。合成的二氧化钛和 SBA-16/TiO2 复合材料(硅/二氧化钛比为 0.7)可在紫外线照射 24 小时内完全降解溶液中的利谷隆。此外,研究还发现 SBA-16 可以在黑暗条件下通过吸附过程帮助降解利谷隆。根据一阶动力学模型对降解过程进行了计算和跟踪。最后,讨论并提出了降解机理。
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来源期刊
Silicon
Silicon CHEMISTRY, PHYSICAL-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
5.90
自引率
20.60%
发文量
685
审稿时长
>12 weeks
期刊介绍: The journal Silicon is intended to serve all those involved in studying the role of silicon as an enabling element in materials science. There are no restrictions on disciplinary boundaries provided the focus is on silicon-based materials or adds significantly to the understanding of such materials. Accordingly, such contributions are welcome in the areas of inorganic and organic chemistry, physics, biology, engineering, nanoscience, environmental science, electronics and optoelectronics, and modeling and theory. Relevant silicon-based materials include, but are not limited to, semiconductors, polymers, composites, ceramics, glasses, coatings, resins, composites, small molecules, and thin films.
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