Synthesis and characterization of ZnO–NiO composites for efficient U(VI) scavenger

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-08-29 DOI:10.1007/s10967-024-09717-x
Amandeep Kaur, Khalid Mujasam Batoo, Muhammad Farziq Ijaz, Sangeeta Sharma
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Abstract

(1-x)ZnO–xNiO nanocomposites (where x = 0.05, 0.10, 0.15 and 0.20) have been successfully synthesized using a mechanical mixing approach. Structural phase, morphological, and elemental composition analysis have been carried out using X-ray diffraction, scanning electron microscope, EDX, and XPS analysis. The systematic batch mode adsorption studies were carried out to evaluate the optimized adsorption behavior of synthesized nanocomposites (pH = 6; contact time = 90 min and adsorption dose = 0.5 g/L). Kinetic studies revealed that the prepared nanocomposite (0.80ZnO0.20NiO) successfully adsorbs U(VI) through a chemisorption nature with the maximum Langmuir capacity (~ 151.20 mg/g). The results demonstrated that the prepared 0.80ZnO0.20NiO can be used as a packaging material for column units in water purifiers.

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ZnO-NiO 复合材料的合成与表征:高效的六(U)元素清除剂
(采用机械混合方法成功合成了 (1-x)ZnO-xNiO 纳米复合材料(其中 x = 0.05、0.10、0.15 和 0.20)。利用 X 射线衍射、扫描电子显微镜、EDX 和 XPS 分析进行了结构相、形态和元素组成分析。为了评估合成纳米复合材料的优化吸附行为(pH = 6;接触时间 = 90 分钟;吸附剂量 = 0.5 克/升),进行了系统的批次模式吸附研究。动力学研究表明,制备的纳米复合材料(0.80ZnO0.20NiO)通过化学吸附成功地吸附了 U(VI),其朗姆吸附容量最大(~ 151.20 mg/g)。结果表明,制备的 0.80ZnO0.20NiO 可用作净水器中柱单元的包装材料。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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