Study on the performance of ground melon vine straw fiber modified asphalt

IF 4.1 2区 化学 Q2 POLYMER SCIENCE Polymer Pub Date : 2024-09-11 DOI:10.1016/j.polymer.2024.127599
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Abstract

In order to reduce the waste of resources and the pollution of ecological environment caused by the large amount of waste crop straw accumulation or incineration, and to realize the high-value utilization of waste straw resources, this paper adopts the mechanical crushing method, acid and alkali solution treatment method to prepare the groundnut seedling straw fibers, and compares and analyzes the micro-morphology and chemical composition and thermal stability of the groundnut seedling straw fibers prepared by the physical method, the NaOH solution method, and the HCL solution method, through the scanning electron microscope, infrared spectroscope and the thermogravimetric analysis test; secondly, the optimal blending range of the groundnut seedling straw fibers is preferred. Secondly, the optimal dosage range of ground melon vine straw fiber was selected, the preparation process of ground melon vine straw fiber modified asphalt was proposed, five different dosages of ground melon vine straw fiber modified asphalt were prepared, and the basic properties, viscosity and temperature characteristics, and storage stability of ground melon vine straw fiber modified asphalt were analyzed; and then, a dynamic shear rheometer was used. Dynamic Shear Rheometer and Bending Beam Rheometer tests were used to study the high and low temperature rheological properties and resistance to permanent deformation of ground melon vine straw fiber modified asphalt, and the optimal dosage of groundnut seedling straw fibers was determined; finally, through Fourier Transform Infrared Spectroscopy and Scanning Electron Microscopy tests, the chemical components of ground melon vine straw fiber modified asphalt were clarified, and the chemical components of ground melon vine straw fiber modified asphalt were revealed to be the most important. The toughening mechanism of ground melon vine straw fiber modified asphalt was revealed. The results showed that the chemical alkali treatment method was the best preparation process for groundnut straw fiber, and the process flow was to use NaOH solution with a mass fraction of 3 % to treat the ground melon vine straw fiber for 50 min at a temperature of 60 °C; compared with the matrix asphalt, the needle penetration and elongation of the ground melon vine straw fiber modified asphalt decreased with the increase of the blending amount, and the softening point, the equivalent softening point, and the temperature sensitivity of the asphalt increased. Sensitivity enhancement, softening point difference in line with the specification requirements, but the ductility in the low dosage improved; with the increase in the dosage of ground melon vine straw fiber, ground melon vine straw fiber modified asphalt rutting factor, creep modulus, 0.4 %–1 % dosage of the creep rate and creep recovery rate increased, while 1.3 %–1.6 % dosage of the creep rate and the amount of unrecoverable creep flexibility decreased The results show that 0.4 %–1.6 % dosage of melaleuca alternifolia straw fiber modified asphalt high temperature performance and resistance to permanent deformation performance, and 0.4 %–1 % dosage of melaleuca alternifolia straw fiber low temperature performance has also been improved, the overall consideration, to determine the optimal dosage of melaleuca alternifolia straw fiber 1 %; melaleuca alternifolia straw fibers (NaOH) and the asphalt combined with the production of new functional groups, and melaleuca alternifolia straw fibers with each other. Lap cross to form a fiber skeleton grid structure, can play a role in the entire material to transfer stress and crack resistance, asphalt to play the role of enhanced toughening effect.

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地瓜藤秸秆纤维改性沥青性能研究
为了减少大量废弃农作物秸秆堆积或焚烧造成的资源浪费和生态环境污染,实现废弃秸秆资源的高值化利用,本文采用机械粉碎法、酸碱溶液处理法制备地肤苗秸秆纤维、并通过扫描电镜、红外光谱和热重分析测试,对比分析了物理法、NaOH 溶液法和 HCL 溶液法制备的地肤苗秸秆纤维的微观形态、化学成分和热稳定性;其次,优选地瓜秧秸秆纤维的最佳混合范围。其次,优选地瓜秧秸秆纤维的最佳掺量范围,提出地瓜秧秸秆纤维改性沥青的制备工艺,制备了五种不同掺量的地瓜秧秸秆纤维改性沥青,分析了地瓜秧秸秆纤维改性沥青的基本性能、粘度和温度特性以及储存稳定性;然后,使用动态剪切流变仪。动态剪切流变仪和弯梁流变仪试验,研究了地瓜秧秸秆纤维改性沥青的高低温流变性能和抗永久变形性能,确定了地瓜秧秸秆纤维的最佳添加量;最后,通过傅里叶变换红外光谱和扫描电子显微镜试验,明确了地瓜秧秸秆纤维改性沥青的化学成分,揭示了地瓜秧秸秆纤维改性沥青的化学成分的最揭示了地瓜藤纤维改性沥青的增韧机理。结果表明,化学碱处理法是地瓜秸秆纤维的最佳制备工艺,其工艺流程是用质量分数为3%的NaOH溶液在60 ℃的温度下处理地瓜秸秆纤维50 min;与基质沥青相比,地瓜秸秆纤维改性沥青的针入度和伸长率随掺量的增加而降低,沥青的软化点、等效软化点和温度敏感性增加。敏感性增强,软化点差异符合规范要求,但延度在低掺量时有所改善;随着地瓜藤秸秆纤维掺量的增加,地瓜藤秸秆纤维改性沥青的车辙系数、蠕变模量、0.4 %-1 %掺量时的蠕变率和蠕变恢复率增加,而1.3 %-1.6 %掺量时的蠕变率和不可恢复蠕变弹性量减少 结果表明,0.4 %-1.6 %用量的白千层秸秆纤维改性沥青的耐高温性能和抗永久变形性能较好,而 0.4 %-1.6 %用量的白千层秸秆纤维的耐低温性能也有所改善,综合考虑,确定白千层秸秆纤维的最佳用量为 1 %;白千层秸秆纤维(NaOH)与沥青结合产生新的官能团,与白千层秸秆纤维相互配合。搭接交叉形成纤维骨架网格结构,可在整个材料中起到传递应力和抗裂的作用,沥青则起到增强增韧效果的作用。
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来源期刊
Polymer
Polymer 化学-高分子科学
CiteScore
7.90
自引率
8.70%
发文量
959
审稿时长
32 days
期刊介绍: Polymer is an interdisciplinary journal dedicated to publishing innovative and significant advances in Polymer Physics, Chemistry and Technology. We welcome submissions on polymer hybrids, nanocomposites, characterisation and self-assembly. Polymer also publishes work on the technological application of polymers in energy and optoelectronics. The main scope is covered but not limited to the following core areas: Polymer Materials Nanocomposites and hybrid nanomaterials Polymer blends, films, fibres, networks and porous materials Physical Characterization Characterisation, modelling and simulation* of molecular and materials properties in bulk, solution, and thin films Polymer Engineering Advanced multiscale processing methods Polymer Synthesis, Modification and Self-assembly Including designer polymer architectures, mechanisms and kinetics, and supramolecular polymerization Technological Applications Polymers for energy generation and storage Polymer membranes for separation technology Polymers for opto- and microelectronics.
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