Effect of intermittent non-isothermal aging on the microstructure and properties of Al–Zn–Mg–Cu alloy

IF 4.3 3区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Materials Chemistry and Physics Pub Date : 2024-09-11 DOI:10.1016/j.matchemphys.2024.129946
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Abstract

The proposition of an intermittent non-isothermal aging (IM-NIA) is an innovative approach to address the challenge of balancing the mechanical properties and corrosion resistance of Al–Zn–Mg–Cu alloys. The effects of IM-NIA on the hardness, corrosion resistance and microstructure morphology of Al–Zn–Mg–Cu alloys were investigated by hardness test, intergranular corrosion test (IGC), exfoliation corrosion test (EXCO), electrochemical corrosion test and combined with transmission electron microscopy (TEM) observation. The results showed that the hardness of the alloy was the highest at 186HV after intermittent post-tempering to 180 °C (IM-H180). The intergranular corrosion depth is the smallest, the corrosion rate is the slowest, and the exfoliation corrosion rating is EA. In addition, the alloy matrix precipitated phase has the smallest average diameter, the highest volume fraction, the strongest ability to repair the passivation film, and the strongest resistance to Cl erosion; At the same time, the grain boundary precipitation phase is intermittent and multilinear parallel distribution, PFZ is the widest, hindering the anodic corrosion channel, slow corrosion progress and improve corrosion resistance.

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间歇性非等温时效对铝锌镁铜合金微观结构和性能的影响
间歇性非等温老化(IM-NIA)是解决铝锌镁铜合金机械性能和耐腐蚀性平衡难题的一种创新方法。通过硬度测试、晶间腐蚀测试(IGC)、剥落腐蚀测试(EXCO)、电化学腐蚀测试并结合透射电子显微镜(TEM)观察,研究了 IM-NIA 对铝锌镁铜合金硬度、耐腐蚀性和微观结构形态的影响。结果表明,在间歇性后回火至 180 °C(IM-H180)后,合金的硬度在 186HV 时最高。晶间腐蚀深度最小,腐蚀速率最慢,剥离腐蚀等级为 EA。此外,合金基体析出相平均直径最小,体积分数最高,修复钝化膜能力最强,抗Cl-侵蚀能力最强;同时,晶界析出相呈间歇多线性平行分布,PFZ最宽,阻碍了阳极腐蚀通道,减缓了腐蚀进程,提高了耐蚀性。
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来源期刊
Materials Chemistry and Physics
Materials Chemistry and Physics 工程技术-材料科学:综合
CiteScore
8.70
自引率
4.30%
发文量
1515
审稿时长
69 days
期刊介绍: Materials Chemistry and Physics is devoted to short communications, full-length research papers and feature articles on interrelationships among structure, properties, processing and performance of materials. The Editors welcome manuscripts on thin films, surface and interface science, materials degradation and reliability, metallurgy, semiconductors and optoelectronic materials, fine ceramics, magnetics, superconductors, specialty polymers, nano-materials and composite materials.
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