Selective laser melting of 2507 duplex stainless steel: Effect of energy density on microstructure and corrosion resistance

Abstract

Duplex stainless steel (DSS) is widely used in the marine, petroleum, chemical, automotive, and other fields owing to its excellent mechanical properties and corrosion resistance. However, the research on duplex stainless steel prepared by additive manufacturing is still limited. In this paper, high-density 2507 DSS was successfully prepared by selective laser melting (SLM) additive manufacturing. The effects of energy density on the formability, phase composition, microstructure and corrosion properties of SLM 2507 DSS were investigated. The results showed that with the decrease of the energy density, the density of the specimen increases first and then decreases, and the density achieves 99.18% with the energy density of 190.5 J/mm³. The types of phases are not affected by the energy density, i.e., all 2507 DSS samples prepared by SLM showed a ferrite phase. The YOZ (parallel to the building direction) plane of the SLM 2507 DSS samples showed predominantly columnar grains attributed to the high temperature gradient and epitaxial growth characteristics. With the increase of energy density, the average grain size decreases slightly from 16.97 μm to 15.78 μm, the KAM value decreases slightly from 1.15 to 1.05, and the low angle grain boundaries (LAGBs) increase significantly from 68.4% to 74.8%. The SLM 2507 DSS sample exhibited excellent corrosion resistance. The self-corrosion potential of the sample is 136 mV and the self-corrosion current density is 2.066 × 10⁻⁸ A/cm² at the maximum density. This investigation provides a new approach for the preparation of super duplex stainless steel, which can provide a theoretical basis and guidance for industrialized application.