Model-free detection and quantitative assessment of micro short circuits in lithium-ion battery packs based on incremental capacity and unsupervised clustering

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-09-17 DOI:10.1016/j.ijoes.2024.100794
Da Lei , Meng Zhang , Qiang Guo , Yibin Gao , Zhigang Bai , Qi Yang , Ke Fu , Chao Lyu
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Abstract

Timely diagnosis of micro short circuit (MSC) faults is crucial for ensuring the safe operation of lithium-ion battery energy storage systems. Existing diagnostic methods face limitations such as high dependency on battery models, difficulty in determining accurate diagnostic thresholds, or low computational efficiency. This work presents a model-free approach for the detection and quantitative assessment of MSCs in lithium-ion battery packs, with incremental capacity (IC) and unsupervised clustering. First, the IC is extracted from charging voltage data to effectively characterize MSC faults in lithium-ion batteries. Next, principal component analysis is used to map the high-dimensional feature space onto a two-dimensional plane to facilitate fault detection and result visualization. Then, an unsupervised clustering algorithm is employed for anomaly detection to identify MSC cells within the battery pack. For the detected MSC cells, a method based on the maximum charging voltage difference between adjacent cycles is designed to estimate the MSC resistance, quantitatively assessing the severity and evolution stage of the MSC. Experimental results show that the accuracy of MSC detection is 99.17 % and the minimum relative error of short-circuit resistance estimation is 1.20 %, which demonstrates the effectiveness and feasibility of the proposed method.

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基于增量容量和无监督聚类的锂离子电池组微短路无模型检测和定量评估
及时诊断微短路(MSC)故障对于确保锂离子电池储能系统的安全运行至关重要。现有的诊断方法存在一些局限性,如高度依赖电池模型、难以确定准确的诊断阈值或计算效率低。本研究提出了一种无模型方法,利用增量容量(IC)和无监督聚类来检测和定量评估锂离子电池组中的间充质干细胞。首先,从充电电压数据中提取增量容量,以有效描述锂离子电池中的 MSC 故障。然后,利用主成分分析法将高维特征空间映射到二维平面上,以方便故障检测和结果可视化。然后,采用无监督聚类算法进行异常检测,以识别电池组中的 MSC 电池。对于检测到的间隙电池,设计了一种基于相邻循环之间最大充电电压差的方法来估算间隙电池电阻,从而定量评估间隙电池的严重程度和演变阶段。实验结果表明,MSC 检测的准确率为 99.17%,短路电阻估算的最小相对误差为 1.20%,证明了所提方法的有效性和可行性。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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