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Internal heating of lithium-ion batteries at low temperatures based on electro-thermal modeling 基于电热模型的低温锂离子电池内部加热
IF 2.4 4区 化学 Q4 ELECTROCHEMISTRY Pub Date : 2026-02-02 DOI: 10.1016/j.ijoes.2026.101316
Yankong Song , Kehao Yin , Chao Lyu , Xiao Liang , Wei Li
Lithium-ion batteries (LIBs) are highly sensitive to operating temperature and experience particularly severe performance degradation at low temperature (here define as temperature below 0 °C). Preheating of LIBs represents an effective strategy to mitigate these adverse effects prior to operation under such conditions. Among various preheating techniques, the internal heating method has garnered increasing attention due to its advantages in temperature uniformity and operational simplicity. However, the application of excessively high current amplitudes during heating will induce capacity rapidly fade. To address this issue, this paper proposes a constrained pulse heating method that limits the current amplitude. Based on a thermal coupling simplified electrochemical model (TC-SEM), the criterion for preventing lithium plating is translated into current amplitude constraints across varying temperature and states of charge (SOC). Moreover, this study developed an experimental platform capable of delivering adjustable pulsed currents is constructed, incorporating these predefined current constraints to dynamically regulate the heating process and minimize degradation. Validation experiments demonstrate that no significant capacity degradation is observed following 100 heating cycles. In contrast, a control group subjected to heating with current amplitudes exceeding the prescribed heating current limits exhibited a capacity loss of approximately 2.1 % after only 30 cycles.
锂离子电池(lib)对工作温度高度敏感,在低温(这里定义为低于0°C)下性能下降特别严重。在这种条件下操作之前,对lib进行预热是一种有效的策略,可以减轻这些不利影响。在各种预热技术中,内加热法因其温度均匀、操作简单等优点而受到越来越多的关注。然而,在加热过程中使用过大的电流幅值会导致容量迅速衰减。为了解决这个问题,本文提出了一种限制电流幅度的约束脉冲加热方法。基于热耦合简化电化学模型(TC-SEM),将防止镀锂的准则转化为不同温度和荷电状态(SOC)下的电流振幅约束。此外,本研究开发了一个能够提供可调脉冲电流的实验平台,并结合这些预定义的电流约束来动态调节加热过程并最大限度地减少退化。验证实验表明,在100次加热循环后,没有观察到明显的容量下降。相比之下,在超过规定的加热电流限制的电流振幅下加热的对照组,仅在30次循环后,其容量损失约为2.1 %。
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引用次数: 0
Expired omeprazole as an effective corrosion inhibitor for copper in nitric acid 过期奥美拉唑对硝酸中铜的有效缓蚀剂
IF 2.4 4区 化学 Q4 ELECTROCHEMISTRY Pub Date : 2026-01-23 DOI: 10.1016/j.ijoes.2026.101303
Azhar Farooq , Enas H. Ali , Zainab W. Ahmed , Anees A. Khadom , Khalida F. Al-azawi
Researchers have investigated the effectiveness of an expired pharmaceutical drug, omeprazole, as a corrosion inhibitor for copper in 0.5 M nitric acid using mass-loss measurements conducted at different temperatures. The results demonstrated that the tested drug significantly reduced the corrosion rate of the copper alloy in the acidic medium. An inhibition efficiency of 97.7 % was achieved when 900 ppm of expired omeprazole was applied to the copper surface. Thermodynamic analyses were performed to determine the activation and adsorption parameters. The findings indicate that temperature and inhibitor concentration are the key factors influencing the corrosion behavior. The calculated Gibbs free energy of adsorption suggests that the inhibitor molecules adhere to the copper surface predominantly through physical adsorption. Furthermore, the adsorption process was found to follow the Langmuir isotherm, confirming that the pharmaceutical molecules naturally and spontaneously adsorb onto the copper surface. The research novelty lies in the application of an expired drug as a highly effective corrosion inhibitor under aggressive nitric acid environments. This offered cost-effective, ecofriendly, and alternative to conventional corrosion inhibitors.
研究人员利用在不同温度下进行的质量损失测量,研究了一种过期药物奥美拉唑作为0.5 M硝酸中铜的缓蚀剂的有效性。结果表明,所测药物能显著降低铜合金在酸性介质中的腐蚀速率。用900 ppm的过期奥美拉唑对铜表面进行缓蚀,缓蚀率为97.7 %。热力学分析确定了活化和吸附参数。结果表明,温度和缓蚀剂浓度是影响腐蚀行为的关键因素。计算的吸附吉布斯自由能表明,抑制剂分子主要通过物理吸附在铜表面。此外,发现吸附过程遵循Langmuir等温线,证实了药物分子自然自发地吸附在铜表面。该研究的新颖之处在于将一种过期药物应用于腐蚀性硝酸环境下的高效缓蚀剂。这为传统的缓蚀剂提供了经济、环保的替代方案。
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引用次数: 0
Laser-cladded hBN/Ni-based composite coatings for enhanced wear and corrosion resistance of HT250 cast iron 激光熔覆hBN/ ni基复合涂层增强HT250铸铁的耐磨损和耐腐蚀性能
IF 2.4 4区 化学 Q4 ELECTROCHEMISTRY Pub Date : 2026-01-20 DOI: 10.1016/j.ijoes.2026.101302
Lunxiang Li , Xiaojun Xue , Haitao Qu , Feng Liu , Liqian Liu , Xiaoyong Chen , Ruize Xu
HT250 cast iron is widely used for its excellent castability and cost-effectiveness, but its corrosion and wear resistance are insufficient. This study fabricated Ni-based composite coatings (Ni625 +Ni50 +hBN) on HT250 via laser cladding and systematically investigated the effects of laser power (1100 W, 1300 W, 1500 W) on the coating's microstructure, wear resistance, and corrosion resistance. XRD analysis showed the coating matrix is γ-Ni, with borides (Ni₂B), carbides (Cr₂₃C₆), and undecomposed hBN. SEM and EDS revealed that at 1300 W, hBN decomposes appropriately, forming a dispersion-strengthened structure with moderately sized hard phases. Mechanically, the 1300 W sample exhibited the highest microhardness (552.16 HV), lowest friction coefficient, and minimal wear loss. Electrochemical tests confirmed the 1300 W coating has optimal pitting corrosion resistance, with the highest breakdown potential, most noble repassivation potential, and significantly higher charge transfer resistance than other samples. Thus, 1300 W is the optimal laser power, achieving synergistic optimization of hard phase size, distribution, and corrosion resistance.
HT250铸铁因其优良的浇注性和成本效益而被广泛使用,但其耐腐蚀和耐磨性不足。采用激光熔覆的方法在HT250上制备了Ni625 +Ni50 +hBN复合镀层,系统研究了激光功率(1100 W、1300 W、1500 W)对镀层显微组织、耐磨性和耐腐蚀性的影响。XRD分析表明,涂层基体为γ-Ni,含硼化物(Ni₂B)、碳化物(Cr₂₃C₆)和未分解的hBN。SEM和EDS分析表明,在1300 W时,hBN适当分解,形成具有中等大小硬相的分散强化结构。机械性能方面,1300 W样品具有最高的显微硬度(552.16 HV)、最低的摩擦系数和最小的磨损损失。电化学试验证实,1300 W涂层具有最佳的抗点蚀性能,击穿电位最高,再钝化电位最高,电荷转移电阻明显高于其他样品。因此,1300 W为最优激光功率,实现了硬相尺寸、分布和耐腐蚀性的协同优化。
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引用次数: 0
Theoretical analysis of sulfur dioxide–imidazolium ionic liquid interaction and its application in electrochemical sensing 二氧化硫-咪唑离子液体相互作用的理论分析及其在电化学传感中的应用
IF 2.4 4区 化学 Q4 ELECTROCHEMISTRY Pub Date : 2026-01-19 DOI: 10.1016/j.ijoes.2026.101301
Chunping Gao , Zhaoxia Wang , Chao Wang , Tao Wang , Wenying Chen , Lirong Chang , Yanni Sun , Xudong Zhang , Gongkai Chen , Xueliang Wang
Sulfur dioxide (SO2) is a common atmospheric pollutant. Its testing is mandatory, especially in the areas of occupational health and safety. In this work, the interaction of SO2 and [Emim]BF4 was studied firstly by quantum chemical calculations. The results showed that the adsorption of SO2 by ionic liquids (ILs) was primarily governed by physical interactions dominated with electrostatic forces. The strength of weak interactions between [Emim]+ and [BF4]- exceeded that of X-H˙˙˙O type weak hydrogen bonds, indicating no substitutional adsorption of SO2 at the [BF4] site. Electron flow towards SO2 was confirmed through density difference mapping during all three adsorption processes. Finally, the electrochemical behaviors of SO2 on the [Emim]BF4 modified screen-printed electrodes (SPEs) were studied by Differential Pulse Voltammetry (DPV), Electrochemical Impedance Spectroscopy (EIS) and Amperometric i-t curve (I-t), respectively, and an electrochemical sensor for SO2 was set up. This work is necessary for understanding the mechanism of SO2 capture by ILs, rationally designing the functional ILs, and promoting their application in sensing pollutant gases.
二氧化硫(SO2)是常见的大气污染物。它的检测是强制性的,特别是在职业健康和安全领域。本文首次通过量子化学计算研究了SO2与[Emim]BF4的相互作用。结果表明,离子液体对SO2的吸附主要受以静电力为主的物理相互作用支配。[Emim]+与[BF4]-之间的弱相互作用强度超过了X-H˙˙O型弱氢键,表明[BF4]位点没有对SO2进行取代吸附。在三个吸附过程中,通过密度差图确定了电子流向SO2。最后,采用差分脉冲伏安法(DPV)、电化学阻抗谱法(EIS)和安培i-t曲线(i-t)分别研究了SO2在[Emim]BF4改性丝网印刷电极(spe)上的电化学行为,并建立了SO2电化学传感器。这项工作对于理解离子阱捕获SO2的机理,合理设计功能性离子阱,促进其在污染物气体检测中的应用具有重要意义。
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引用次数: 0
Dual-site doping enhances the performance of NiMnFe-LDH catalysts for alkaline oxygen evolution 双位点掺杂提高了NiMnFe-LDH催化剂的碱性析氧性能
IF 2.4 4区 化学 Q4 ELECTROCHEMISTRY Pub Date : 2026-01-15 DOI: 10.1016/j.ijoes.2026.101282
Xinxuan Duan , Daoming Zhang , Jiacuo Xirao , Zhenyu Zhou , Yanbin Wang , Xi Xiao
Nickel-iron layered double hydroxides (NiFe-LDHs) are among the most promising non-precious metal catalysts for alkaline oxygen evolution reaction (OER), yet their performance still requires further improvement for practical applications. While introducing a third metal is a common strategy, most dopants occupy only a single valence site, limiting their ability to simultaneously optimize both Ni2 + and Fe3+ centers in the LDH lattice. This work exploits the unique dual-valent character of manganese (Mn2+/Mn3+) to achieve simultaneous substitution at both Ni2+ and Fe3+ sites, a novel approach confirmed by XPS analysis. The resulting NiMnFe-LDHs catalyst exhibits exceptional OER activity (278 mV @10 mA·cm−2) and 200-hour stability at industrial current densities (400 mA·cm−2). In-situ Raman spectroscopy reveals that Mn doping facilitates the LDH-to-NiFeOOH transformation during OER, while XPS demonstrate the Mn2+/Mn3+-induced electron redistribution enhances both charge transfer and intermediate adsorption. This valence-mediated dual-site doping strategy establishes a new paradigm for designing high-performance LDH catalysts.
镍铁层状双氢氧化物(NiFe-LDHs)是碱析氧反应(OER)中最有前途的非贵金属催化剂之一,但其性能仍需进一步改进才能得到实际应用。虽然引入第三种金属是一种常见的策略,但大多数掺杂剂只占据一个价位,限制了它们同时优化LDH晶格中Ni2 +和Fe3+中心的能力。这项工作利用锰(Mn2+/Mn3+)独特的双价特性在Ni2+和Fe3+位点上同时实现取代,这是一种由XPS分析证实的新方法。所制得的NiMnFe-LDHs催化剂表现出优异的OER活性(278 mV @10 mA·cm−2)和在工业电流密度(400 mA·cm−2)下200小时的稳定性。原位拉曼光谱结果表明,Mn的掺杂促进了OER过程中ldh到nifeooh的转变,而XPS结果表明,Mn2+/Mn3+诱导的电子重分配促进了电荷转移和中间吸附。这种价介导的双位点掺杂策略为设计高性能LDH催化剂建立了新的范例。
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引用次数: 0
Study on the corrosion behavior of three types of steel in marine atmospheric environment 三种钢在海洋大气环境中的腐蚀行为研究
IF 2.4 4区 化学 Q4 ELECTROCHEMISTRY Pub Date : 2026-01-15 DOI: 10.1016/j.ijoes.2026.101298
Peng Zhang , Jingwang Niu , Jie Zhang , Haiyang Yang , Qifu Zhang
Q235, Q345, and 921 steels were selected as study materials for a one-year exposure test in the marine atmospheric environment of Qingdao. The corrosion behavior and mechanisms of the three steels were systematically investigated using weight-loss measurements, electrochemical tests, pitting morphology observations, and rust layer phase analyses. The results indicated that the corrosion rates followed the order Q345 > Q235 > 921. Q345 steel exhibited MnS inclusions that acted as pitting-sensitive sites, resulting in lower corrosion resistance than Q235 steel, while 921 steel, containing Ni, Cr, and Mo, showed significantly reduced corrosion rates. XRD analysis revealed that the corrosion products of all three steels mainly consisted of γ-Fe₂O₃/Fe₃O₄, α-FeOOH, and γ-FeOOH, with 921 steel exhibiting a higher proportion of α-FeOOH and greater amorphization, forming a dense protective layer that effectively slowed electrochemical corrosion. XPS results showed that the formation of NiFe₂O₄ in 921 steel conferred cation selectivity to the rust layer, enhancing its protective effect. Raman spectroscopy indicated that the rust layers of all three steels displayed an outward-to-inward stratified structure, but the inner α-FeOOH layer of 921 steel was richer and more stable, providing the basis for its superior corrosion resistance. Electrochemical tests further demonstrated that 921 steel had significantly higher polarization resistance and impedance than Q235 and Q345 steels, which increased with exposure time, indicating a dense and stable rust layer that strongly hindered charge transfer and ion diffusion.
选取Q235、Q345和921钢材作为研究材料,在青岛海洋大气环境中进行为期一年的暴露试验。通过失重测量、电化学测试、点蚀形貌观察和锈层相分析,系统地研究了这三种钢的腐蚀行为和机理。结果表明:腐蚀速率为Q345 >; Q235 >; 921。Q345钢中含有作为点蚀敏感部位的MnS夹杂物,其耐蚀性低于Q235钢,而921钢中含有Ni、Cr和Mo,腐蚀速率明显降低。XRD分析表明,3种钢的腐蚀产物主要由γ-Fe₂O₃/Fe₃O₄、α-FeOOH和γ-FeOOH组成,其中921钢的α-FeOOH比例更高,非晶化程度更大,形成致密的保护层,有效减缓了电化学腐蚀。XPS结果表明,921钢中NiFe₂O₄的形成赋予了锈层阳离子选择性,增强了其保护作用。拉曼光谱分析结果表明,三种钢的锈层均呈现由外向内分层结构,但921钢内部α-FeOOH更丰富、更稳定,这为其优异的耐蚀性提供了基础。电化学测试进一步表明,921钢的极化电阻和阻抗显著高于Q235和Q345钢,且随着暴露时间的延长而增大,表明其致密而稳定的锈层严重阻碍了电荷转移和离子扩散。
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引用次数: 0
ZrB2-reinforced electroless Ni-W-P composite coating with enhanced corrosion and wear resistance in 3.5 wt% NaCl solution zrb2增强化学镀Ni-W-P复合涂层在3.5 wt% NaCl溶液中的耐蚀耐磨性能增强
IF 2.4 4区 化学 Q4 ELECTROCHEMISTRY Pub Date : 2026-01-13 DOI: 10.1016/j.ijoes.2026.101293
Hongjie Li , Hongfa Huang , Deqiang Cai , Jie Xiao , Xi Yuan , Wenxu Zhu , Liangchen Lv
In this paper, various concentrations ZrB2 nanoparticles were applied in the Ni-W-P bath system, and a series of Ni-W-P composite coatings were fabricated via composite chemical deposition. The phase composition, microstructure, elemental distribution, and chemical states of the different coatings were systematically characterized using XRD, SEM, EDS, and XPS, and the results of the tests indicated that Ni-W-P/ZrB2 composite coatings were prepared successfully. The corrosion resistance, wear resistance and hardness of the coatings were investigated through electrochemical corrosion tests, friction tests and hardness tests. Electrochemical tests revealed that the incorporation of ZrB2 particles significantly refines the coating’s microstructure. This structural optimization directly contributes to a remarkable enhancement in corrosion resistance and mechanical properties, as evidenced by detailed analysis of the electrochemical parameters. When ZrB2 content reaches 1.25 g/L, Ni-W-P/ZrB2 composite coatings exhibited the most excellent corrosion resistance (the lowest corrosion rate of 0.00499 mm/a). To further compare the mechanical properties between the pure alloy deposit and ZrB2 strengthened composite deposit, the results of friction tests and hardness tests demonstrated that Ni-W-P/ZrB2 composite deposit has better wear resistance.
本文将不同浓度的ZrB2纳米粒子应用于Ni-W-P镀液体系中,通过复合化学沉积法制备了一系列Ni-W-P复合镀层。采用XRD、SEM、EDS和XPS对不同涂层的相组成、微观结构、元素分布和化学状态进行了系统表征,测试结果表明成功制备了Ni-W-P/ZrB2复合涂层。通过电化学腐蚀试验、摩擦试验和硬度试验对镀层的耐蚀性、耐磨性和硬度进行了研究。电化学测试表明,ZrB2颗粒的加入显著改善了涂层的微观结构。详细的电化学参数分析证明,这种结构优化直接有助于显著提高耐腐蚀性和力学性能。当ZrB2含量达到1.25 g/L时,Ni-W-P/ZrB2复合镀层的耐蚀性能最优,腐蚀速率最低,为0.00499 mm/a。为了进一步比较纯合金镀层与ZrB2强化复合镀层的力学性能,摩擦试验和硬度试验结果表明,Ni-W-P/ZrB2复合镀层具有更好的耐磨性。
{"title":"ZrB2-reinforced electroless Ni-W-P composite coating with enhanced corrosion and wear resistance in 3.5 wt% NaCl solution","authors":"Hongjie Li ,&nbsp;Hongfa Huang ,&nbsp;Deqiang Cai ,&nbsp;Jie Xiao ,&nbsp;Xi Yuan ,&nbsp;Wenxu Zhu ,&nbsp;Liangchen Lv","doi":"10.1016/j.ijoes.2026.101293","DOIUrl":"10.1016/j.ijoes.2026.101293","url":null,"abstract":"<div><div>In this paper, various concentrations ZrB<sub>2</sub> nanoparticles were applied in the Ni-W-P bath system, and a series of Ni-W-P composite coatings were fabricated via composite chemical deposition. The phase composition, microstructure, elemental distribution, and chemical states of the different coatings were systematically characterized using XRD, SEM, EDS, and XPS, and the results of the tests indicated that Ni-W-P/ZrB<sub>2</sub> composite coatings were prepared successfully. The corrosion resistance, wear resistance and hardness of the coatings were investigated through electrochemical corrosion tests, friction tests and hardness tests. Electrochemical tests revealed that the incorporation of ZrB<sub>2</sub> particles significantly refines the coating’s microstructure. This structural optimization directly contributes to a remarkable enhancement in corrosion resistance and mechanical properties, as evidenced by detailed analysis of the electrochemical parameters. When ZrB<sub>2</sub> content reaches 1.25 g/L, Ni-W-P/ZrB<sub>2</sub> composite coatings exhibited the most excellent corrosion resistance (the lowest corrosion rate of 0.00499 mm/a). To further compare the mechanical properties between the pure alloy deposit and ZrB<sub>2</sub> strengthened composite deposit, the results of friction tests and hardness tests demonstrated that Ni-W-P/ZrB<sub>2</sub> composite deposit has better wear resistance.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"21 3","pages":"Article 101293"},"PeriodicalIF":2.4,"publicationDate":"2026-01-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145976033","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of phthalocyanine-ligand-based MOF materials for the hydrogen evolution reaction 酞菁配体基MOF材料的制备及其析氢反应
IF 2.4 4区 化学 Q4 ELECTROCHEMISTRY Pub Date : 2026-01-13 DOI: 10.1016/j.ijoes.2026.101291
Mingming Shi, Guodong Tang, Shaogui Hua, Jichen Hu
As a clean energy carrier, hydrogen energy demands efficient and cost-effective electrocatalysts for the hydrogen evolution reaction (HER). Although traditional noble metal catalysts exhibit high performance, their scarcity and high cost limit practical applications. This study proposes a novel strategy of constructing non-precious metal MOF materials using phthalocyanine ligands to address these challenges. The core innovation lies in designing and synthesizing a cobalt-phthalocyanine-derived MOF composite (CoPc@rGO-MOF) using a hot-solvent method. This method achieves the atomic dispersion of Co–N–C active sites within a hierarchical porous carbon matrix. The study optimizes the preparation process and investigates the structure–performance relationship for HER. The optimized CoPc@rGO-MOF demonstrated exceptional HER activity in 1 M KOH, with a low overpotential of only 98 mV at 10 mA cm−2 and a small Tafel slope of 56 mV dec−1. Moreover, it exhibited remarkable stability, with less than 5 % activity decay after 1000 cycles. Characterization revealed that the conjugated system of phthalocyanine ligands significantly enhanced charge transfer efficiency, while the hierarchical pore structure facilitated mass transport. This work provides a high-performance, non-precious metal HER catalyst and offers insights into the rational design of macrocyclic-ligand-based MOFs for energy conversion applications.
氢能作为一种清洁的能源载体,需要高效、经济的析氢反应电催化剂。传统贵金属催化剂虽然性能优异,但其稀缺性和高成本限制了其实际应用。本研究提出了一种利用酞菁配体构建非贵金属MOF材料的新策略来解决这些挑战。核心创新在于采用热溶剂法设计和合成钴-酞菁衍生的MOF复合材料(CoPc@rGO-MOF)。该方法实现了Co-N-C活性位点在分层多孔碳基体中的原子分散。本研究优化了HER的制备工艺,并考察了其结构性能关系。优化后的CoPc@rGO-MOF在1 M KOH中表现出优异的HER活性,在10 mA cm−2时过电位仅为98 mV, Tafel斜率很小,为56 mV dec−1。此外,它还表现出了显著的稳定性,经过1000次循环后活性衰减小于5 %。表征表明,酞菁配体的共轭体系显著提高了电荷转移效率,而分层孔结构促进了质量传输。这项工作提供了一种高性能的非贵金属HER催化剂,并为能量转换应用中基于大环配体的mof的合理设计提供了见解。
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引用次数: 0
Electrochemical corrosion behavior of P110 tubing steel in CO2-saturated brine containing NO2 P110油管钢在含NO2的co2饱和盐水中的电化学腐蚀行为
IF 2.4 4区 化学 Q4 ELECTROCHEMISTRY Pub Date : 2026-01-13 DOI: 10.1016/j.ijoes.2026.101292
Zhen Yang , Guoxian Zhao , Ranran Liu
During CO2 sequestration, injected gas contains various carbon source impurities. This work conducted in situ electrochemical testing on P110 tubing steel at 90°C under conditions where the carbon source impurity NO2 content was 0, 100 ppm, and 900 ppm respectively. Impedance spectroscopy and dynamic potential scanning polarisation curve testing techniques were employed to characterise the microstructural information of different post-corrosion films, product film/substrate interfaces, and product film/corrosion medium interfaces. Results indicate that under pure CO2 conditions, the capacitive arc radius is maximal, with a dense and highly protective corrosion product film. The charge transfer resistance (Rt) is 220.674 Ω·cm2, and the anodic active area is suppressed, resulting in a low and uniform corrosion rate. The introduction of NO2 significantly compromises the integrity and stability of the corrosion product film, leading to intensified localised corrosion. As NO2 concentration increased from 0 ppm to 900 ppm, the electrode surface potential distribution became more dispersed, the anodic current peak intensified, and the number of active sites increased. Consequently, Icorr rose, Ecorr shifted negatively, the capacitive arc radius decreased, and Rt dropped sharply. These changes significantly exacerbated both generalised and localised corrosion tendencies in the material.
在CO2固存过程中,注入气体中含有各种碳源杂质。本工作在90℃条件下对P110管钢进行了原位电化学测试,碳源杂质NO2含量分别为0、100 ppm和900 ppm。采用阻抗谱和动态电位扫描极化曲线测试技术表征了不同腐蚀后膜、产品膜/衬底界面和产品膜/腐蚀介质界面的微观结构信息。结果表明,在纯CO2条件下,电容弧半径最大,腐蚀产物膜致密,防护性强。电荷转移电阻(Rt)为220.674 Ω·cm2,阳极活性区受到抑制,腐蚀速率低且均匀。NO2的引入极大地损害了腐蚀产物膜的完整性和稳定性,导致局部腐蚀加剧。随着NO2浓度从0 ppm增加到900 ppm,电极表面电位分布更加分散,阳极电流峰值增强,活性位点数量增加。因此,Icorr升高,Ecorr负移,电容弧半径减小,Rt急剧下降。这些变化显著地加剧了材料的普遍和局部腐蚀趋势。
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引用次数: 0
Preparation and electrochemical properties of mesoporous Carbon@ MoS2 anode materials for lithium-ion batteries 锂离子电池介孔碳@ MoS2负极材料的制备及其电化学性能
IF 2.4 4区 化学 Q4 ELECTROCHEMISTRY Pub Date : 2026-01-13 DOI: 10.1016/j.ijoes.2026.101294
Jiazhe Sun , Zhao Xu , Wenyu Wang , Shuqi Sheng , Shengyi Zhao , Yifei Chen , Huhao Kong , Yuqi Liu , Xiaoping Jiang , Yongchao Yao , He Chen , Jia Wei Chew , Zhengping Zhao
Addressing the escalating demand for high-performance lithium-ion batteries (LIBs) in light of the energy crisis and environmental concerns, this study aimed to develop an advanced anode material. To overcome the limitations of conventional graphite anodes, a novel NG@MoS2@LS-C composite was synthesized via a hydrothermal method combined with lignin–carbon coating and carbonization. Specifically, MoS2 nanoparticles were uniformly deposited on the surface of natural graphite, followed by lignin–carbon coating and carbonization, resulting in a unique structure with enhanced electrochemical properties. The experimental results show that the incorporation of MoS2 nanoparticles significantly improved cycling performance, while the lignin–carbon coating mitigated volume expansion, enhancing cycle stability. The composite exhibited an initial capacity of 588.2 mAh·g⁻¹ and retained a reversible capacity of 326.2 mAh·g⁻¹ after 30 cycles, outperforming pristine graphite. In addition, the lamellar structure of MoS2 nanoparticles, combined with the buffering and electrolyte blocking effects of a lignin-derived carbon shell, endows the composite with low charge transfer resistance and a high lithium-ion diffusion rate, resulting in excellent electron-ion cooperative transmission characteristics. This study presents a promising anode material for next-generation LIBs, which can contribute towards green and sustainable energy storage solutions.
针对能源危机和环境问题对高性能锂离子电池(LIBs)不断增长的需求,本研究旨在开发一种先进的负极材料。为克服传统石墨阳极的局限性,采用木质素-碳包覆和炭化相结合的水热法制备了新型NG@MoS2@LS-C复合材料。其中,二硫化钼纳米粒子均匀沉积在天然石墨表面,然后进行木质素-碳包覆和碳化,得到了独特的结构和增强的电化学性能。实验结果表明,二硫化钼纳米颗粒的掺入显著提高了循环性能,而木质素-碳涂层则减轻了体积膨胀,增强了循环稳定性。这种复合材料的初始容量为588.2 mAh·g⁻¹ ,经过30次循环后,其可逆容量为326.2 mAh·g⁻¹ ,优于原始石墨。此外,二硫化钼纳米颗粒的层状结构,结合木质素衍生碳壳的缓冲和电解质阻断作用,使复合材料具有低电荷转移电阻和高锂离子扩散速率,从而具有优异的电子-离子协同传输特性。该研究为下一代锂离子电池提供了一种有前途的阳极材料,可以为绿色和可持续的储能解决方案做出贡献。
{"title":"Preparation and electrochemical properties of mesoporous Carbon@ MoS2 anode materials for lithium-ion batteries","authors":"Jiazhe Sun ,&nbsp;Zhao Xu ,&nbsp;Wenyu Wang ,&nbsp;Shuqi Sheng ,&nbsp;Shengyi Zhao ,&nbsp;Yifei Chen ,&nbsp;Huhao Kong ,&nbsp;Yuqi Liu ,&nbsp;Xiaoping Jiang ,&nbsp;Yongchao Yao ,&nbsp;He Chen ,&nbsp;Jia Wei Chew ,&nbsp;Zhengping Zhao","doi":"10.1016/j.ijoes.2026.101294","DOIUrl":"10.1016/j.ijoes.2026.101294","url":null,"abstract":"<div><div>Addressing the escalating demand for high-performance lithium-ion batteries (LIBs) in light of the energy crisis and environmental concerns, this study aimed to develop an advanced anode material. To overcome the limitations of conventional graphite anodes, a novel NG@MoS<sub>2</sub>@LS-C composite was synthesized via a hydrothermal method combined with lignin–carbon coating and carbonization. Specifically, MoS<sub>2</sub> nanoparticles were uniformly deposited on the surface of natural graphite, followed by lignin–carbon coating and carbonization, resulting in a unique structure with enhanced electrochemical properties. The experimental results show that the incorporation of MoS<sub>2</sub> nanoparticles significantly improved cycling performance, while the lignin–carbon coating mitigated volume expansion, enhancing cycle stability. The composite exhibited an initial capacity of 588.2 mAh·g⁻¹ and retained a reversible capacity of 326.2 mAh·g⁻¹ after 30 cycles, outperforming pristine graphite. In addition, the lamellar structure of MoS<sub>2</sub> nanoparticles, combined with the buffering and electrolyte blocking effects of a lignin-derived carbon shell, endows the composite with low charge transfer resistance and a high lithium-ion diffusion rate, resulting in excellent electron-ion cooperative transmission characteristics. This study presents a promising anode material for next-generation LIBs, which can contribute towards green and sustainable energy storage solutions.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"21 3","pages":"Article 101294"},"PeriodicalIF":2.4,"publicationDate":"2026-01-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146035668","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
International Journal of Electrochemical Science
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