Effect of moisture diffusion on the properties of rubber-modified asphalt and aggregate interface considering multiple influencing factors

IF 8 1区工程技术 Q1 CONSTRUCTION & BUILDING TECHNOLOGY Construction and Building Materials Pub Date : 2024-09-18 DOI:10.1016/j.conbuildmat.2024.138358

Siting Chen , Lei Lu , Ya Gao , Chaoen Yin , Md Sumon Prodhan , Xinxing Zhou , Xiaorui Zhang

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引用次数: 0

Abstract

Moisture-induced degradation is an inherent phenomenon at the interface between rubber-modified asphalt and aggregate, moisture ingress through diffusion impairs the integrity of this interface. This study employed molecular simulation to assess the performance of the rubber-modified asphalt and aggregate interface, considering multiple influencing factors such as temperature and loading. Infrared spectroscopy served to validate the alterations in functional groups after moisture exposure. Quantitative metrics, including mean square displacement, interfacial adhesion energy, adsorption energy, radius of gyration, solubility parameter, and molecular orientation, were computed to pinpoint the moisture-induced degradation zones. The findings demonstrated that the maximum moisture diffusion rate subject to various influencing parameters occurred at 298 K and 3 atm, as well as 333 K and 3 atm. Temperature exerted a more profound influence on the rubber-modified asphalt-aggregate interface compared to loading. The strength of hydrogen bonding between moisture and rubber molecules surpassed Van der Waals forces and induction force. Infrared spectroscopy showed that the diffused moisture persisted within the interface.

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考虑多种影响因素后水分扩散对橡胶改性沥青和集料界面性能的影响

湿气引起的降解是橡胶改性沥青和集料界面的固有现象，湿气通过扩散侵入会损害该界面的完整性。本研究采用分子模拟来评估橡胶改性沥青和集料界面的性能，并考虑了温度和荷载等多种影响因素。红外光谱分析验证了功能基团在受潮后发生的变化。计算了包括均方位移、界面粘附能、吸附能、回转半径、溶解度参数和分子取向在内的定量指标，以确定由湿气引起的降解区。研究结果表明，在 298 K 和 3 atm 以及 333 K 和 3 atm 条件下，受各种影响参数的影响，湿气扩散速率最大。与负载相比，温度对橡胶改性沥青集料界面的影响更大。水分和橡胶分子之间的氢键强度超过了范德华力和感应力。红外光谱显示，扩散的水分在界面内持续存在。

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来源期刊

Construction and Building Materials 工程技术-材料科学：综合

CiteScore

13.80

自引率

21.60%

发文量

3632

审稿时长

82 days

期刊介绍： Construction and Building Materials offers an international platform for sharing innovative and original research and development in the realm of construction and building materials, along with their practical applications in new projects and repair practices. The journal publishes a diverse array of pioneering research and application papers, detailing laboratory investigations and, to a limited extent, numerical analyses or reports on full-scale projects. Multi-part papers are discouraged. Additionally, Construction and Building Materials features comprehensive case studies and insightful review articles that contribute to new insights in the field. Our focus is on papers related to construction materials, excluding those on structural engineering, geotechnics, and unbound highway layers. Covered materials and technologies encompass cement, concrete reinforcement, bricks and mortars, additives, corrosion technology, ceramics, timber, steel, polymers, glass fibers, recycled materials, bamboo, rammed earth, non-conventional building materials, bituminous materials, and applications in railway materials.