Evaluation of MagneTOF detector signals for the determination of many-ion bunches

IF 1.6 3区 化学 Q3 PHYSICS, ATOMIC, MOLECULAR & CHEMICAL International Journal of Mass Spectrometry Pub Date : 2024-09-10 DOI:10.1016/j.ijms.2024.117337
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Abstract

In preparation of space-change studies a MagneTOF detector is evaluated for bunches with a wide range of ion numbers. The detector is calibrated based on the comparison between single-ion counting and ion-bunch-signal integration. This allows to determine up to several ten thousands of ions in a bunch with a FWHM of about 700ns, the integrated signal of which increases linearly with the ion number. Furthermore, this detector limit can be circumvented using transmission-limiting elements in front of the detector. Based on this, ion bunches are investigated up to several million ions, which are prepared with a linear Paul trap. Thus, in addition to the MagneTOF detector this trap is characterized with respect to its space-charge limits at low potential-well depth.

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评估用于测定多离子束的 MagneTOF 检测器信号
在准备空间变化研究时,对一个 MagneTOF 检测器进行了评估,该检测器适用于各种离子群。根据单离子计数和离子束信号积分之间的比较对探测器进行了校准。这样就能以约 700ns 的全宽均方根(FWHM)测定离子束中的数万个离子,其积分信号随离子数的增加而线性增加。此外,还可以利用探测器前的传输限制元件来规避探测器的这一限制。在此基础上,利用线性保罗阱制备的离子束可研究多达数百万个离子。因此,除了 MagneTOF 检测器之外,这种阱的特点还在于其在低电位井深度时的空间电荷限制。
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来源期刊
CiteScore
3.60
自引率
5.60%
发文量
145
审稿时长
71 days
期刊介绍: The journal invites papers that advance the field of mass spectrometry by exploring fundamental aspects of ion processes using both the experimental and theoretical approaches, developing new instrumentation and experimental strategies for chemical analysis using mass spectrometry, developing new computational strategies for data interpretation and integration, reporting new applications of mass spectrometry and hyphenated techniques in biology, chemistry, geology, and physics. Papers, in which standard mass spectrometry techniques are used for analysis will not be considered. IJMS publishes full-length articles, short communications, reviews, and feature articles including young scientist features.
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