Photo-induced Intercalation of Cobalt(II) Tellurium Oxide as an Oxygen Evolution (Photo)electrocatalyst

IF 3.5 4区 化学 Q2 ELECTROCHEMISTRY ChemElectroChem Pub Date : 2024-09-17 DOI:10.1002/celc.202481802
Prof. Roelof J. Kriek, Dr. Oluwaseun A. Oyetade, Dr. Nyengerai H. Zingwe, Prof. Emanuela Carleschi, Prof. Bryan P. Doyle, Dr. Jaco Koch
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Abstract

The inside cover picture highlights the ability of cobalt(II) tellurium oxide (CTO) to intercalate electrolytic potassium ions upon photo-induced charge separation, thereby stabilising the excited electron, whilst also driving the oxygen evolution reaction by oxidising hydroxide ions. It is shown that the photo-electrocatalytic (PEC) current is about double that of the electrocatalytic (EC) current while the EC current, subsequent to the termination of illumination, is almost as high as the PEC current. This exhibits the ability of CTO to deintercalate and release charge after the termination of illumination. More details can be found in the Research Article by Roelof Jacobus Kriek and co-workers (DOI: 10.1002/celc.202400047).

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光诱导碲钴(II)氧化物互嵌作为氧进化(光)电催化剂
封面内页图片突出显示了钴(II)氧化碲(CTO)在光诱导电荷分离时夹杂电解钾离子的能力,从而稳定了激发电子,同时还通过氧化氢氧根离子推动了氧进化反应。研究表明,光催化(PEC)电流大约是电催化(EC)电流的两倍,而在照明终止后,电催化电流几乎与光催化电流一样高。这显示了 CTO 在光照终止后去交联和释放电荷的能力。更多详细信息,请参阅 Roelof Jacobus Kriek 及其合作者的研究文章(DOI: 10.1002/celc.202400047)。
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来源期刊
ChemElectroChem
ChemElectroChem ELECTROCHEMISTRY-
CiteScore
7.90
自引率
2.50%
发文量
515
审稿时长
1.2 months
期刊介绍: ChemElectroChem is aimed to become a top-ranking electrochemistry journal for primary research papers and critical secondary information from authors across the world. The journal covers the entire scope of pure and applied electrochemistry, the latter encompassing (among others) energy applications, electrochemistry at interfaces (including surfaces), photoelectrochemistry and bioelectrochemistry.
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