Front Cover Picture: Exploring Ferrocenyl Imine-Phosphane Complexes in Gold(I) Redox Switchable Catalysis and the Role of the “Magic Blue” Oxidant (Adv. Synth. Catal. 18/2024)

IF 4.4 2区 化学 Q2 CHEMISTRY, APPLIED Advanced Synthesis & Catalysis Pub Date : 2024-09-18 DOI:10.1002/adsc.202400921
Juan Carlos Pérez-Sánchez, Raquel P. Herrera, M. Concepción Gimeno
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Abstract

The front cover illustrates the dual role of the “Magic Blue” molecule. Set in an enchanting forest, a whimsical wizard conjures two gold complexes in a magical cauldron full of “Magic Blue”. The compounds react via chloride abstraction for the [AuCl(JohnPhos)] catalyst and one-electron oxidation for the ferrocenyl imine-phosphane catalyst. Fairies are depicted pulling a chloride atom and an electron, respectively, showcasing the dynamic nature that “Magic Blue” oxidant can adopt depending on the molecule it reacts with. Details can be found in Research Article by Pérez-Sánchez, Herrera, and Gimeno (J. C. Pérez-Sánchez, R. P. Herrera, M. C. Gimeno, Adv. Synth. Catal. 2024, 366, 3697–3924; DOI: 10.1002/adsc.202400593)

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探索二茂铁酰亚胺-膦烷配合物在金(I)氧化还原可转换催化作用中的作用以及 "魔蓝 "氧化剂的作用。
封面展示了 "魔法蓝 "分子的双重作用。在一片迷人的森林中,一位奇思妙想的魔法师在一个装满 "魔法蓝 "的神奇大锅中变幻出两种金络合物。在[AuCl(JohnPhos)]催化剂中,化合物通过氯化物抽取反应,在二茂铁酰亚胺-膦催化剂中,化合物通过单电子氧化反应。图中的仙女分别拉动一个氯原子和一个电子,展示了 "魔蓝 "氧化剂可根据与之反应的分子的不同而具有的动态性质。详情请见佩雷斯-桑切斯、埃雷拉和吉梅诺的研究文章(J. C. Pérez-Sánchez, Herrera, and Gimeno)。Pérez-Sánchez, R. P.Herrera, M. C.Gimeno, Adv.Catal.2024, 366, 3697-3924; DOI: 10.1002/adsc.202400593)
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Advanced Synthesis & Catalysis
Advanced Synthesis & Catalysis 化学-应用化学
CiteScore
9.40
自引率
7.40%
发文量
447
审稿时长
1.8 months
期刊介绍: Advanced Synthesis & Catalysis (ASC) is the leading primary journal in organic, organometallic, and applied chemistry. The high impact of ASC can be attributed to the unique focus of the journal, which publishes exciting new results from academic and industrial labs on efficient, practical, and environmentally friendly organic synthesis. While homogeneous, heterogeneous, organic, and enzyme catalysis are key technologies to achieve green synthesis, significant contributions to the same goal by synthesis design, reaction techniques, flow chemistry, and continuous processing, multiphase catalysis, green solvents, catalyst immobilization, and recycling, separation science, and process development are also featured in ASC. The Aims and Scope can be found in the Notice to Authors or on the first page of the table of contents in every issue.
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