Formation mechanism of Al-O intergranular amorphous phase toughened nanoscale ZrB2-ZrC composite coating synthesized by reactive plasma spraying

IF 11.2 1区 材料科学 Q1 MATERIALS SCIENCE, MULTIDISCIPLINARY Journal of Materials Science & Technology Pub Date : 2024-09-20 DOI:10.1016/j.jmst.2024.06.059
Yu-hang Cui, Yong Yang, Dian-long Wang, Yan-wei Wang
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Abstract

A new nanostructured ZrB2-ZrC composite coating with ZrB2-ZrC nanoscale eutectic and ZrB2+Amorphous microstructure was synthesized in situ by plasma spraying Zr-B4C-Al composite powder. The thermal analysis, quenching experiments and microstructure characterization were investigated and the formation mechanism of the bimodal in-situ microstructure was revealed. Al contributed to the liquid phase separation of molten droplets, which is the key to forming ZrB2+Amorphous microstructure. The formation of coating followed reaction-melting-liquid separation-deposition and solidification mechanism. The nanostructured ZrB2-ZrC composite coating with Al-O intergranular amorphous phase has excellent mechanical properties. The uniform nano-grains improved the hardness and the toughness of the ZrB2-ZrC eutectic. The ZrB2+Al-O amorphous microstructure obtained high toughness and the toughening mechanism was the crack deflection and crack branching caused by intergranular Al-O amorphous phase.

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反应等离子喷涂合成的 Al-O 晶间非晶相增韧纳米级 ZrB2-ZrC 复合涂层的形成机理
通过等离子喷涂 Zr-B4C-Al 复合粉末,原位合成了具有 ZrB2-ZrC 纳米共晶和 ZrB2+Amorphous 显微结构的新型纳米 ZrB2-ZrC 复合涂层。通过热分析、淬火实验和显微结构表征,揭示了双峰原位显微结构的形成机理。铝促进了熔滴的液相分离,是形成 ZrB2+Amorphous 显微结构的关键。涂层的形成遵循反应-熔融-液相分离-沉积-凝固的机理。具有 Al-O 晶间非晶相的纳米结构 ZrB2-ZrC 复合涂层具有优异的机械性能。均匀的纳米晶粒提高了 ZrB2-ZrC 共晶的硬度和韧性。ZrB2+Al-O 非晶微结构获得了高韧性,其增韧机制是晶间 Al-O 非晶相引起的裂纹偏转和裂纹分支。
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来源期刊
Journal of Materials Science & Technology
Journal of Materials Science & Technology 工程技术-材料科学:综合
CiteScore
20.00
自引率
11.00%
发文量
995
审稿时长
13 days
期刊介绍: Journal of Materials Science & Technology strives to promote global collaboration in the field of materials science and technology. It primarily publishes original research papers, invited review articles, letters, research notes, and summaries of scientific achievements. The journal covers a wide range of materials science and technology topics, including metallic materials, inorganic nonmetallic materials, and composite materials.
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