Pub Date : 2024-09-17DOI: 10.1016/j.jmst.2024.08.050
Liangliang Zhang, Peng Li, Honggang Dong
Ni/TiAl composite brazed joints could significantly reduce the aircraft's weight. However, low interfacial adhesion, coarse and brittle-hard intermetallic compounds (IMCs) seriously limited the application of Ni/TiAl composite joints in the next generation of aerospace applications. So enhanced K4169/TiAl composite joints were investigated by vacuum brazed with (Ni53.33Cr20B16.67Si10/Zr25Ti18.75Ta12.5Ni25Cu18.75) composite filler metal (CFM) designed based on cluster-plus-glue-atom model. The shear strength of the joint reached 485 MPa, comparable to the 491 MPa of TiAl substrate. The flat and brittle-hard diffusion reaction layer between Zones I and II was eliminated, simultaneously generating CrB4 dispersion strengthening due to the CFM developed with the interfacial solid-liquid space-time hysteresis effect. In Zones II and III, IMCs all transformed into Niss(Cr,Fe)[0-88], Niss(Ti, Al)[004], and Niss(Zr,Si)[11-2] of circular and oval shapes through isothermal solidification. Meanwhile, the residual stresses and hardness were distributed in reticulated cladding characteristics. Thereby, lattice distortion led to solid solution strengthening and increased plastic toughness through crack termination and bridging mechanisms, which inhibited dislocations from plugging and crack propagation. Various interfaces in Zone Ⅳ were regulated into semi- and coherent interfaces. Ni3(Ti,Al)/(Ni,Ti,Al) and (Ni,Ti,Al)/AlNi2Ti were composed of higher interfacial bonding energy (2.771 J/m2, 2.547 J/m2) and Ni-Ni covalent bonds. Interfacial covalent bonding and large interfacial bonding energy coupling strengthened Zone IV. Consequently, cracks initiated at the (Ni,Ti,Al)[013]/Ti3Al[010] and expanded rapidly into TiAl substrate. Therefore, applying this method to design CFMs and regulate the phase, grain morphology, and interface's fine structure could provide new pathways for dissimilar hard-to-join metals.
镍/钛铝复合材料钎焊接头可显著减轻飞机重量。然而,低界面附着力、粗糙且脆硬的金属间化合物(IMC)严重限制了 Ni/TiAl 复合材料接头在下一代航空航天领域的应用。因此,通过真空钎焊与基于簇加胶原子模型设计的(Ni53.33Cr20B16.67Si10/Zr25Ti18.75Ta12.5Ni25Cu18.75)复合填充金属(CFM),研究了增强型 K4169/TiAl 复合材料接头。接头的剪切强度达到 485 兆帕,与钛铝基体的 491 兆帕相当。在 I 区和 II 区之间消除了扁平和脆硬的扩散反应层,同时由于利用界面固液时滞效应开发的 CFM 而产生了 CrB4 分散强化。在 II 区和 III 区,IMC 通过等温凝固全部转化为圆形和椭圆形的 Niss(Cr,Fe)[0-88]、Niss(Ti,Al)[004]和 Niss(Zr,Si)[11-2]。同时,残余应力和硬度分布在网状包层特征中。因此,晶格畸变导致固溶强化,并通过裂纹终止和桥接机制提高塑性韧性,从而抑制位错堵塞和裂纹扩展。Ⅳ区的各种界面被调节为半相干和相干界面。Ni3(Ti,Al)/(Ni,Ti,Al)和(Ni,Ti,Al)/AlNi2Ti由较高的界面键能(2.771 J/m2,2.547 J/m2)和 Ni-Ni 共价键组成。界面共价键和较大的界面键能耦合强化了 IV 区。因此,裂纹从(Ni,Ti,Al)[013]/Ti3Al[010]处开始,并迅速扩展到 TiAl 基底。因此,应用这种方法设计 CFM 并调节相、晶粒形态和界面的精细结构,可为异种难接合金属提供新的途径。
{"title":"Dispersion, solid solution, and covalent bond coupled to strengthen K4169/TiAl composite brazed joints: first-principles and experimental perspective","authors":"Liangliang Zhang, Peng Li, Honggang Dong","doi":"10.1016/j.jmst.2024.08.050","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.08.050","url":null,"abstract":"<p>Ni/TiAl composite brazed joints could significantly reduce the aircraft's weight. However, low interfacial adhesion, coarse and brittle-hard intermetallic compounds (IMCs) seriously limited the application of Ni/TiAl composite joints in the next generation of aerospace applications. So enhanced K4169/TiAl composite joints were investigated by vacuum brazed with (Ni<sub>53.33</sub>Cr<sub>20</sub>B<sub>16.67</sub>Si<sub>10</sub>/Zr<sub>25</sub>Ti<sub>18.75</sub>Ta<sub>12.5</sub>Ni<sub>25</sub>Cu<sub>18.75</sub>) composite filler metal (CFM) designed based on cluster-plus-glue-atom model. The shear strength of the joint reached 485 MPa, comparable to the 491 MPa of TiAl substrate. The flat and brittle-hard diffusion reaction layer between Zones I and II was eliminated, simultaneously generating CrB<sub>4</sub> dispersion strengthening due to the CFM developed with the interfacial solid-liquid space-time hysteresis effect. In Zones II and III, IMCs all transformed into Ni<sub>ss</sub>(Cr,Fe)<sub>[0-88]</sub>, Ni<sub>ss</sub>(Ti, Al)<sub>[004]</sub>, and Ni<sub>ss</sub>(Zr,Si)<sub>[11-2]</sub> of circular and oval shapes through isothermal solidification. Meanwhile, the residual stresses and hardness were distributed in reticulated cladding characteristics. Thereby, lattice distortion led to solid solution strengthening and increased plastic toughness through crack termination and bridging mechanisms, which inhibited dislocations from plugging and crack propagation. Various interfaces in Zone Ⅳ were regulated into semi- and coherent interfaces. Ni<sub>3</sub>(Ti,Al)/(Ni,Ti,Al) and (Ni,Ti,Al)/AlNi<sub>2</sub>Ti were composed of higher interfacial bonding energy (2.771 J/m<sup>2</sup>, 2.547 J/m<sup>2</sup>) and Ni-Ni covalent bonds. Interfacial covalent bonding and large interfacial bonding energy coupling strengthened Zone IV. Consequently, cracks initiated at the (Ni,Ti,Al)<sub>[013]</sub>/Ti<sub>3</sub>Al<sub>[010]</sub> and expanded rapidly into TiAl substrate. Therefore, applying this method to design CFMs and regulate the phase, grain morphology, and interface's fine structure could provide new pathways for dissimilar hard-to-join metals.</p>","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-09-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142235376","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-15DOI: 10.1016/j.jmst.2024.09.002
Yong Zhang, Lantian Zhang, Lingxin Li, Le Zong, Lequn Kan, Hao Li, Lu Jiang, Wenwen Sun
The strength of non-heat-treatable 5xxx Al alloys is derived from solid solution strengthening and strain hardening, the absence of a precipitation strengthening response results in their lower strength. In this study, significant improvements in strength can be achieved by subjecting three different Mg concentrations 5xxx Al alloys to cyclic plasticity. A quantitative analysis of the respective contributions to the yield strength has been conducted by combining transmission electron microscopy and atom probe tomography. Additionally, the fatigue performance and fatigue mechanism of the cyclic strengthened 5xxx Al alloys have been thoroughly studied due to its transformation from non-heat-treatable to precipitation strengthening. We demonstrate that the high-cycle fatigue (HCF) strength of the cyclically strengthened state only experiences a minor improvement compared to the as-received state, which is significantly disproportionate to the enhancement in tensile strength. This disparity is primarily attributed to the changes in microstructure and fatigue mechanisms, resulting in a reduction in fatigue ratio. This study provides important insights for expanding research on cyclic plasticity methods in fatigue performance, and can aid in the development of improved processes for optimal fatigue resistance.
非热处理 5xxx Al 合金的强度来自固溶强化和应变硬化,缺乏沉淀强化反应导致其强度较低。在本研究中,通过对三种不同镁浓度的 5xxx Al 合金进行循环塑性处理,可显著提高其强度。通过结合透射电子显微镜和原子探针断层扫描技术,对各自对屈服强度的贡献进行了定量分析。此外,由于 5xxx Al 合金从不可热处理到沉淀强化的转变,我们还对循环强化 5xxx Al 合金的疲劳性能和疲劳机理进行了深入研究。我们证明,循环强化状态下的高循环疲劳强度(HCF)与接收状态相比仅有轻微提高,与拉伸强度的提高明显不成比例。造成这种差异的主要原因是微观结构和疲劳机制发生了变化,导致疲劳比降低。这项研究为扩大疲劳性能中循环塑性方法的研究提供了重要启示,并有助于开发改进工艺,以获得最佳抗疲劳性能。
{"title":"Elucidating the effect of cyclic plasticity on strengthening mechanisms and fatigue property of 5xxx Al alloys","authors":"Yong Zhang, Lantian Zhang, Lingxin Li, Le Zong, Lequn Kan, Hao Li, Lu Jiang, Wenwen Sun","doi":"10.1016/j.jmst.2024.09.002","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.09.002","url":null,"abstract":"<p>The strength of non-heat-treatable 5xxx Al alloys is derived from solid solution strengthening and strain hardening, the absence of a precipitation strengthening response results in their lower strength. In this study, significant improvements in strength can be achieved by subjecting three different Mg concentrations 5xxx Al alloys to cyclic plasticity. A quantitative analysis of the respective contributions to the yield strength has been conducted by combining transmission electron microscopy and atom probe tomography. Additionally, the fatigue performance and fatigue mechanism of the cyclic strengthened 5xxx Al alloys have been thoroughly studied due to its transformation from non-heat-treatable to precipitation strengthening. We demonstrate that the high-cycle fatigue (HCF) strength of the cyclically strengthened state only experiences a minor improvement compared to the as-received state, which is significantly disproportionate to the enhancement in tensile strength. This disparity is primarily attributed to the changes in microstructure and fatigue mechanisms, resulting in a reduction in fatigue ratio. This study provides important insights for expanding research on cyclic plasticity methods in fatigue performance, and can aid in the development of improved processes for optimal fatigue resistance.</p>","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142233527","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-15DOI: 10.1016/j.jmst.2024.09.001
Hao Xu, Shuai Liu, Zhiang Li, Fan Ding, Ting Wang, Ting Liu, Weimin Wang, Kaikai Song, Jie Liu, Lina Hu
Succinonitrile has shown significant promise for application in polymer electrolytes for solid-state lithium metal batteries due to its high ionic conductivity at low-temperature. However, the use of Succinonitrile is limited due to its corrosion of Li metal. Herein, we report a solid polymer electrolyte with high ionic conductivity (2.17 × 10−3 S cm−1, 35 °C) enhanced by Ti3C2Tx. Corrosion of the Li anode is prevented due to the Succinonitrile molecules being efficiently anchored by Ti3C2Tx. Meanwhile, the coordination environment of Li+ is weakened due to the introduction of competitive coordination induction effects into the polymer electrolyte, resulting in efficient Li+ conduction. Furthermore, the mechanical properties of the electrolyte are enhanced by modulating the ratio of Ti3C2Tx to suppress the growth of Li dendrites. Therefore, Li||Li symmetric batteries deliver stable cycling up to 8000 h at 28 °C. LiFePO4||Li full batteries exhibit excellent cycling stability of 151.7 mAh g−1 with a capacity retention of 99.3% after 300 cycles. This work not only presents a new idea to suppress the corrosion of the Li anode by Succinonitrile but also provides a simple, feasible, and scalable strategy for high-performance Li metal batteries.
琥珀腈在低温下具有高离子导电性,因此在固态锂金属电池聚合物电解质中的应用前景十分广阔。然而,由于琥珀腈对锂金属的腐蚀,其使用受到了限制。在此,我们报告了一种由 Ti3C2Tx 增强的高离子电导率(2.17 × 10-3 S cm-1,35 °C)固体聚合物电解质。由于琥珀腈分子被 Ti3C2Tx 有效锚定,锂阳极的腐蚀得以防止。同时,由于在聚合物电解质中引入了竞争性配位诱导效应,Li+的配位环境被削弱,从而实现了 Li+ 的高效传导。此外,通过调节 Ti3C2Tx 的比例来抑制锂枝晶的生长,从而增强了电解质的机械性能。因此,锂||锂对称电池可在 28 °C 下稳定循环长达 8000 小时。磷酸铁锂||锂全电池表现出卓越的循环稳定性,300 次循环后的容量保持率为 99.3%,达到 151.7 mAh g-1。这项工作不仅提出了用琥珀腈抑制锂阳极腐蚀的新思路,还为高性能锂金属电池提供了一种简单、可行和可扩展的策略。
{"title":"Ti3C2Tx MXene enhanced PEO/SN-based solid electrolyte for high-performance Li metal battery","authors":"Hao Xu, Shuai Liu, Zhiang Li, Fan Ding, Ting Wang, Ting Liu, Weimin Wang, Kaikai Song, Jie Liu, Lina Hu","doi":"10.1016/j.jmst.2024.09.001","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.09.001","url":null,"abstract":"<p>Succinonitrile has shown significant promise for application in polymer electrolytes for solid-state lithium metal batteries due to its high ionic conductivity at low-temperature. However, the use of Succinonitrile is limited due to its corrosion of Li metal. Herein, we report a solid polymer electrolyte with high ionic conductivity (2.17 × 10<sup>−3</sup> S cm<sup>−1</sup>, 35 °C) enhanced by Ti<sub>3</sub>C<sub>2</sub>T<em><sub>x</sub></em>. Corrosion of the Li anode is prevented due to the Succinonitrile molecules being efficiently anchored by Ti<sub>3</sub>C<sub>2</sub>T<em><sub>x</sub></em>. Meanwhile, the coordination environment of Li<sup>+</sup> is weakened due to the introduction of competitive coordination induction effects into the polymer electrolyte, resulting in efficient Li<sup>+</sup> conduction. Furthermore, the mechanical properties of the electrolyte are enhanced by modulating the ratio of Ti<sub>3</sub>C<sub>2</sub>T<em><sub>x</sub></em> to suppress the growth of Li dendrites. Therefore, Li||Li symmetric batteries deliver stable cycling up to 8000 h at 28 °C. LiFePO<sub>4</sub>||Li full batteries exhibit excellent cycling stability of 151.7 mAh g<sup>−1</sup> with a capacity retention of 99.3% after 300 cycles. This work not only presents a new idea to suppress the corrosion of the Li anode by Succinonitrile but also provides a simple, feasible, and scalable strategy for high-performance Li metal batteries.</p>","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142233529","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-14DOI: 10.1016/j.jmst.2024.08.048
Yujie Xing, Dingxuan Zhao, Jinwen Lei, Youchuan Mao, Zehua Zheng, Wei Chen, Jinyu Zhang, Xianghong Liu, Jun Sun
Titanium alloys can achieve ultrahigh strength through precipitation hardening of secondary α-phase (αs) from β-matrix but often compromise ductility due to the conventional strength-ductility trade-off. In this study, a new strategy based on β-subgrains-mediated hierarchical α-precipitation is devised to balance the conflict in Ti-6Al-2Mo-4Cr-2Fe (wt.%) alloy through a unique combination of hot rolling, short-term solid solution, and aging treatment, i.e., RSST+A. Tensile testing reveals that the RSST+A samples exhibit ultrahigh strength of ∼1581 MPa and decent ductility of ∼8.4%, surpassing ∼1060 MPa and ∼2.7% of the corresponding RSST counterparts without final aging treatment. This remarkable strengthening and counterintuitive ductilizing is attributed to the architecting of β-subgrains-mediated hierarchical α-precipitates as a result of our specific processing approach. The designed short-term solution introduces abundant β subgrains that are transformed from the retained intensive dislocations during hot rolling. The β subgrain boundaries subsequently promote a dramatic precipitation of α allotriomorphs (αGB) and Widmanstätten side-plates (αWGB), which effectively subdivides β grains into numerous tiny independent deformation units. Consequently, plastic strain is uniformly partitioned into a large number of small aged β subgrains during tension, which strongly impedes strain localization that would typically occur across multiple β subgrains in the fashion of long straight slip bands in the case of the RSST samples. Furthermore, the hierarchical α structure also postpones uncontrollable cracking even when structural damage occurs at the last stage of straining. These findings demonstrate that appropriately manipulating microstructure through elaborately designing processing routes enables unexpectedly ductilizing high-strength titanium alloys in the precipitation-hardening state.
{"title":"Enhancing strength-ductility synergy in metastable β-Ti alloys through β-subgrains-mediated hierarchical α-precipitation","authors":"Yujie Xing, Dingxuan Zhao, Jinwen Lei, Youchuan Mao, Zehua Zheng, Wei Chen, Jinyu Zhang, Xianghong Liu, Jun Sun","doi":"10.1016/j.jmst.2024.08.048","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.08.048","url":null,"abstract":"<p>Titanium alloys can achieve ultrahigh strength through precipitation hardening of secondary α-phase (α<sub>s</sub>) from β-matrix but often compromise ductility due to the conventional strength-ductility trade-off. In this study, a new strategy based on β-subgrains-mediated hierarchical α-precipitation is devised to balance the conflict in Ti-6Al-2Mo-4Cr-2Fe (wt.%) alloy through a unique combination of hot rolling, short-term solid solution, and aging treatment, i.e., RSST+A. Tensile testing reveals that the RSST+A samples exhibit ultrahigh strength of ∼1581 MPa and decent ductility of ∼8.4%, surpassing ∼1060 MPa and ∼2.7% of the corresponding RSST counterparts without final aging treatment. This remarkable strengthening and counterintuitive ductilizing is attributed to the architecting of β-subgrains-mediated hierarchical α-precipitates as a result of our specific processing approach. The designed short-term solution introduces abundant β subgrains that are transformed from the retained intensive dislocations during hot rolling. The β subgrain boundaries subsequently promote a dramatic precipitation of α allotriomorphs (α<sub>GB</sub>) and Widmanstätten side-plates (α<sub>WGB</sub>), which effectively subdivides β grains into numerous tiny independent deformation units. Consequently, plastic strain is uniformly partitioned into a large number of small aged β subgrains during tension, which strongly impedes strain localization that would typically occur across multiple β subgrains in the fashion of long straight slip bands in the case of the RSST samples. Furthermore, the hierarchical α structure also postpones uncontrollable cracking even when structural damage occurs at the last stage of straining. These findings demonstrate that appropriately manipulating microstructure through elaborately designing processing routes enables unexpectedly ductilizing high-strength titanium alloys in the precipitation-hardening state.</p>","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142231862","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-14DOI: 10.1016/j.jmst.2024.08.045
Zhifan Song, Ruyi Bi, Jianhao Li, Yilei He, Fu Rao, Xiaoyu Chen, Jiangyan Wang, Zumin Wang, Ranbo Yu, Dan Wang
NiS2 with high theoretical capacitance shows great potential for supercapacitors (SCs). However, the poor cycling stability and sluggish redox kinetics have limited the development of high-rate NiS2-based SCs. Integrating materials with high conductivity potentially reinforces its structure and improves its rate capability. 1T-MoS2 featuring extended interlayer spacing and superior electronic conductivity emerges as an ideal candidate. Therefore, we designed a hybrid material with an alternating interconnected structure of NiS2 and MoS2 with adjustable content of 1T-MoS2. Owing to the improved ion/electron transmittability and the mutual shielding effect, an obvious positive correlation between rate capability and stability with 1T-MoS2 content was established. The optimized 1T-MoS2/NiS2 nanosheets (NMS-2) with 1T phase purity of up to 67.6% in MoS2 demonstrated exceptional specific capacity (579.4 C g−1 at 1 A g−1) and impressive rate capability (345.0 C g−1 at 30 A g−1), which suggests much faster kinetics compared to pure NiS2. Notably, the hybrid supercapacitor (HSC) assembled with NMS-2 as the cathode and activated carbon as the anode (NMS-2//AC HSC) exhibited a maximum specific capacitance of 137.4 F g−1 at 1 A g−1. Furthermore, this HSC can deliver a high energy density of 45.9 Wh kg−1 at 774.9 W kg−1, and could retain 17.7 Wh kg−1 even at a high power density of 7731.7 W kg−1. After 5000 cycles at a high current density of 5 A g−1, the HSC still remained 93.23% of its initial capacitance with an extremely low fading rate of 0.0014% per cycle.
具有高理论电容的 NiS2 在超级电容器(SC)方面具有巨大潜力。然而,较差的循环稳定性和缓慢的氧化还原动力学限制了基于 NiS2 的高速率 SC 的发展。整合具有高导电性的材料有可能强化其结构并提高其速率能力。1T-MoS2 具有扩展的层间间距和优异的电子导电性,是一种理想的候选材料。因此,我们设计了一种具有 NiS2 和 MoS2 交替互连结构、1T-MoS2 含量可调的混合材料。由于离子/电子传输性和相互屏蔽效应的改善,速率能力和稳定性与 1T-MoS2 含量之间建立了明显的正相关。优化后的 1T-MoS2/NiS2 纳米片(NMS-2)在 MoS2 中的 1T 相纯度高达 67.6%,表现出卓越的比容量(1 A g-1 时为 579.4 C g-1)和令人印象深刻的速率能力(30 A g-1 时为 345.0 C g-1),这表明其动力学速度比纯 NiS2 快得多。值得注意的是,以 NMS-2 为阴极、活性炭为阳极组装而成的混合超级电容器(HSC)(NMS-2//AC HSC)在 1 A g-1 时的最大比电容为 137.4 F g-1。此外,这种 HSC 还能在 774.9 W kg-1 的功率密度下提供 45.9 Wh kg-1 的高能量密度,即使在 7731.7 W kg-1 的高功率密度下也能保持 17.7 Wh kg-1。在 5 A g-1 的高电流密度下循环 5000 次后,该 HSC 仍能保持其初始电容的 93.23%,且衰减率极低,仅为 0.0014%/次。
{"title":"Metallic 1T-MoS2 boosts the kinetics for NiS2-based hybrid supercapacitors with superb rate performance","authors":"Zhifan Song, Ruyi Bi, Jianhao Li, Yilei He, Fu Rao, Xiaoyu Chen, Jiangyan Wang, Zumin Wang, Ranbo Yu, Dan Wang","doi":"10.1016/j.jmst.2024.08.045","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.08.045","url":null,"abstract":"<p>NiS<sub>2</sub> with high theoretical capacitance shows great potential for supercapacitors (SCs). However, the poor cycling stability and sluggish redox kinetics have limited the development of high-rate NiS<sub>2</sub>-based SCs. Integrating materials with high conductivity potentially reinforces its structure and improves its rate capability. 1T-MoS<sub>2</sub> featuring extended interlayer spacing and superior electronic conductivity emerges as an ideal candidate. Therefore, we designed a hybrid material with an alternating interconnected structure of NiS<sub>2</sub> and MoS<sub>2</sub> with adjustable content of 1T-MoS<sub>2</sub>. Owing to the improved ion/electron transmittability and the mutual shielding effect, an obvious positive correlation between rate capability and stability with 1T-MoS<sub>2</sub> content was established. The optimized 1T-MoS<sub>2</sub>/NiS<sub>2</sub> nanosheets (NMS-2) with 1T phase purity of up to 67.6% in MoS<sub>2</sub> demonstrated exceptional specific capacity (579.4 C g<sup>−1</sup> at 1 A g<sup>−1</sup>) and impressive rate capability (345.0 C g<sup>−1</sup> at 30 A g<sup>−1</sup>), which suggests much faster kinetics compared to pure NiS<sub>2</sub>. Notably, the hybrid supercapacitor (HSC) assembled with NMS-2 as the cathode and activated carbon as the anode (NMS-2//AC HSC) exhibited a maximum specific capacitance of 137.4 F g<sup>−1</sup> at 1 A g<sup>−1</sup>. Furthermore, this HSC can deliver a high energy density of 45.9 Wh kg<sup>−1</sup> at 774.9 W kg<sup>−1</sup>, and could retain 17.7 Wh kg<sup>−1</sup> even at a high power density of 7731.7 W kg<sup>−1</sup>. After 5000 cycles at a high current density of 5 A g<sup>−1</sup>, the HSC still remained 93.23% of its initial capacitance with an extremely low fading rate of 0.0014% per cycle.</p>","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142231819","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-14DOI: 10.1016/j.jmst.2024.08.049
Junliang Chen, Dongdong Jin, Qianqian Wang, Xing Ma
Due to the small size, active mobility, and intrinsic softness, miniature soft robots hold promising potentials in reaching the deep region inside living bodies otherwise inaccessible with compelling agility, adaptability and safety. Various materials and actuation strategies have been developed for creating soft robots, among which, ferromagnetic soft materials that self-actuate in response to external magnetic fields have attracted worldwide attention due to their remote controllability and excellent compatibility with biological tissues. This review presents comprehensive and systematic research advancements in the design, fabrication, and applications of ferromagnetic soft materials for miniature robots, providing insights into their potential use in biomedical fields and beyond. The programming strategies of ferromagnetic soft materials are summarized and classified, including mold-assisted programming, 3D printing-assisted programming, microassembly-assisted programming, and magnetization reprogramming. Each approach possesses unique advantages in manipulating the magnetic responsiveness of ferromagnetic soft materials to achieve outstanding actuation and deformation performances. We then discuss the biomedical applications of ferromagnetic soft material-based soft robots (e.g., minimally invasive surgery, targeted delivery, and tissue engineering), highlighting their potentials in revolutionizing biomedical technologies. This review also points out the current challenges and provides insights into future research directions, which we hope can serve as a useful reference for the development of next-generation adaptive miniature robots.
{"title":"Programming ferromagnetic soft materials for miniature soft robots: Design, fabrication, and applications","authors":"Junliang Chen, Dongdong Jin, Qianqian Wang, Xing Ma","doi":"10.1016/j.jmst.2024.08.049","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.08.049","url":null,"abstract":"<p>Due to the small size, active mobility, and intrinsic softness, miniature soft robots hold promising potentials in reaching the deep region inside living bodies otherwise inaccessible with compelling agility, adaptability and safety. Various materials and actuation strategies have been developed for creating soft robots, among which, ferromagnetic soft materials that self-actuate in response to external magnetic fields have attracted worldwide attention due to their remote controllability and excellent compatibility with biological tissues. This review presents comprehensive and systematic research advancements in the design, fabrication, and applications of ferromagnetic soft materials for miniature robots, providing insights into their potential use in biomedical fields and beyond. The programming strategies of ferromagnetic soft materials are summarized and classified, including mold-assisted programming, 3D printing-assisted programming, microassembly-assisted programming, and magnetization reprogramming. Each approach possesses unique advantages in manipulating the magnetic responsiveness of ferromagnetic soft materials to achieve outstanding actuation and deformation performances. We then discuss the biomedical applications of ferromagnetic soft material-based soft robots (e.g., minimally invasive surgery, targeted delivery, and tissue engineering), highlighting their potentials in revolutionizing biomedical technologies. This review also points out the current challenges and provides insights into future research directions, which we hope can serve as a useful reference for the development of next-generation adaptive miniature robots.</p>","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142231838","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-14DOI: 10.1016/j.jmst.2024.08.043
Xin Ye, He Ma, Shaoyang Wu, Fan Wu, Xiangqun Zhuge, Jiangchuan Liu, Yurong Ren, Peng Wei
Due to its high electrical conductivity and platinum-like electronic structure, molybdenum phosphide (MoP) has attracted extensive attention as a potential catalyst for the hydrogen evolution reaction (HER) by water splitting. Nevertheless, in the oxygen evolution reaction (OER), the electrocatalytic performance of MoP did not achieve satisfactory results. Therefore, novel nitrogen-doped carbon-encapsulated La-doped MoP nanoparticles (La-MoP@N/C) are synthesized, which show outstanding durability and electrocatalytic activity in both HER and OER. Detailed structural characterization and calculations confirm that La doping not only effectively adjusts the electron density around Mo and P atoms, accelerates the adsorption and desorption processes, but also increases the number of active sites. Low overpotentials of 113 and 388 mV for HER and OER at 10 mA cm-2 are achieved with the optimized La0.025-Mo0.975P@N/C. Furthermore, the two-electrode electrolyzer assembled with La0.025-Mo0.975P@N/C also presents impressive water splitting performance. This study indicates that rare earth doping can be used as an efficient strategy to control the local electronic structure of phosphides precisely, which can also be extended to other electrocatalysts.
由于具有高导电性和类铂电子结构,磷化钼(MoP)作为水分裂氢进化反应(HER)的潜在催化剂受到广泛关注。然而,在氧进化反应(OER)中,MoP 的电催化性能并未达到令人满意的效果。因此,我们合成了新型的掺氮碳包封 La 掺杂 MoP 纳米粒子(La-MoP@N/C),它在 HER 和 OER 反应中都表现出卓越的耐久性和电催化活性。详细的结构表征和计算证实,掺杂 La 不仅能有效调整 Mo 原子和 P 原子周围的电子密度,加速吸附和解吸过程,还能增加活性位点的数量。优化后的 La0.025-Mo0.975P@N/C 在 10 mA cm-2 的条件下,HER 和 OER 的过电位分别为 113 和 388 mV。此外,用 La0.025-Mo0.975P@N/C 组装的双电极电解槽也具有令人印象深刻的水分离性能。这项研究表明,稀土掺杂可作为精确控制磷化物局部电子结构的一种有效策略,这种策略也可扩展到其他电催化剂。
{"title":"Electron structure customization of molybdenum phosphide via lanthanum doping toward highly efficient overall water splitting","authors":"Xin Ye, He Ma, Shaoyang Wu, Fan Wu, Xiangqun Zhuge, Jiangchuan Liu, Yurong Ren, Peng Wei","doi":"10.1016/j.jmst.2024.08.043","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.08.043","url":null,"abstract":"<p>Due to its high electrical conductivity and platinum-like electronic structure, molybdenum phosphide (MoP) has attracted extensive attention as a potential catalyst for the hydrogen evolution reaction (HER) by water splitting. Nevertheless, in the oxygen evolution reaction (OER), the electrocatalytic performance of MoP did not achieve satisfactory results. Therefore, novel nitrogen-doped carbon-encapsulated La-doped MoP nanoparticles (La-MoP@N/C) are synthesized, which show outstanding durability and electrocatalytic activity in both HER and OER. Detailed structural characterization and calculations confirm that La doping not only effectively adjusts the electron density around Mo and P atoms, accelerates the adsorption and desorption processes, but also increases the number of active sites. Low overpotentials of 113 and 388 mV for HER and OER at 10 mA cm<sup>-2</sup> are achieved with the optimized La<sub>0.025</sub>-Mo<sub>0.975</sub>P@N/C. Furthermore, the two-electrode electrolyzer assembled with La<sub>0.025</sub>-Mo<sub>0.975</sub>P@N/C also presents impressive water splitting performance. This study indicates that rare earth doping can be used as an efficient strategy to control the local electronic structure of phosphides precisely, which can also be extended to other electrocatalysts.</p>","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142231817","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Self-regulating heating and self-powered flexibility are pivotal for future wearable devices. However, the low energy-conversion rate of wearable devices at low temperatures limits their application in plateaus and other environments. This study introduces an azopolymer with remarkable semicrystallinity and reversible photoinduced solid-liquid transition ability that is obtained through copolymerization of azobenzene (Azo) monomers and styrene. A composite of one such copolymer with an Azo: styrene molar ratio of 9:1 (copolymer is denoted as PAzo9:1-co-polystyrene (PS)) and nylon fabrics (NFs) is prepared (composite is denoted as PAzo9:1-co-PS@NF). PAzo9:1-co-PS@NF exhibits hydrophobicity and high wear resistance. Moreover, it shows good responsiveness (0.624 s−1) during isomerization under solid ultraviolet (UV) light (365 nm) with an energy density of 70.6 kJ kg−1. In addition, the open-circuit voltage, short-circuit current and quantity values of PAzo9:1-co-PS@NF exhibit small variations in a temperature range of -20 °C to 25 °C and remain at 170 V, 5 μA, and 62 nC, respectively. Notably, the involved NFs were cut and sewn into gloves to be worn on a human hand model. When the model was exposed to both UV radiation and friction, the temperature of the finger coated with PAzo9:1-co-PS was approximately 6.0°C higher than that of the other parts. Therefore, developing triboelectric nanogenerators based on the in situ photothermal cycles of Azo in wearable devices is important to develop low-temperature self-regulating heating and self-powered flexible devices for extreme environments.
{"title":"Self-regulating heating and self-powered flexible fiber fabrics at low temperature","authors":"Xuewen Zheng, Xingyi Dai, Jing Ge, Xiaoyu Yang, Ping Yang, Yiyu Feng, Long-Biao Huang, Wei Feng","doi":"10.1016/j.jmst.2024.08.047","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.08.047","url":null,"abstract":"<p>Self-regulating heating and self-powered flexibility are pivotal for future wearable devices. However, the low energy-conversion rate of wearable devices at low temperatures limits their application in plateaus and other environments. This study introduces an azopolymer with remarkable semicrystallinity and reversible photoinduced solid-liquid transition ability that is obtained through copolymerization of azobenzene (Azo) monomers and styrene. A composite of one such copolymer with an Azo: styrene molar ratio of 9:1 (copolymer is denoted as PAzo<sub>9:1</sub>-<em>co</em>-polystyrene (PS)) and nylon fabrics (NFs) is prepared (composite is denoted as PAzo<sub>9:1</sub>-<em>co</em>-PS@NF). PAzo<sub>9:1</sub>-<em>co</em>-PS@NF exhibits hydrophobicity and high wear resistance. Moreover, it shows good responsiveness (0.624 s<sup>−1</sup>) during isomerization under solid ultraviolet (UV) light (365 nm) with an energy density of 70.6 kJ kg<sup>−1</sup>. In addition, the open-circuit voltage, short-circuit current and quantity values of PAzo<sub>9:1</sub>-<em>co-</em>PS@NF exhibit small variations in a temperature range of -20 °C to 25 °C and remain at 170 V, 5 μA, and 62 nC, respectively. Notably, the involved NFs were cut and sewn into gloves to be worn on a human hand model. When the model was exposed to both UV radiation and friction, the temperature of the finger coated with PAzo<sub>9:1</sub>-<em>co</em>-PS was approximately 6.0°C higher than that of the other parts. Therefore, developing triboelectric nanogenerators based on the <em>in situ</em> photothermal cycles of Azo in wearable devices is important to develop low-temperature self-regulating heating and self-powered flexible devices for extreme environments.</p>","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142231818","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-14DOI: 10.1016/j.jmst.2024.07.055
N. Gao, X.W. Liu, Z.H. Yin, Y.S. Wang, K. Wang, Y.F. Zhao, Z.M. Li
Grain boundaries (GBs) are often known as intergranular cracking sources in alloys at high temperatures, resulting in limited high-temperature strength and ductility. Here, we propose a GB-dual-carbide (denoted as GB-DC) strengthening strategy and have developed a high-performance (NiCoFeCr)99Nb0.5C0.5 high-entropy alloy (HEA) with exceptional strength-ductility synergy at 1073 K. Chain-like coherent M23C6 carbides have been successfully introduced at GBs and remain a cube parallel crystallographic orientation with the face-centered cubic (FCC) matrix during deformation. Nano-scale NbC particles are distributed alternatively between M23C6 carbides and inhibit their coarsening. Both strength and ductility of the GB-DC HEA increase dramatically at strain rates ranging from 10−4 to 10−2 s−1 at 1073 K, compared with those of the single-phase NiCoFeCr HEA. Specifically, yield strength of 142 MPa, ultimate tensile strength of 283 MPa, and elongation of 34% were obtained, which are twice that of the reference NiCoFeCr HEA (82 MPa, 172 MPa, and 18%, respectively). EBSD investigations demonstrated that chain-like carbides enhance the GB cohesion at high temperature, and TEM analysis revealed that dislocations can go through the coherent phase boundaries (CPBs) and activate dipoles inner M23C6 carbides, which weakened the stress concentration in GBs. This substantially reduces the critical stress for dislocation generation and transmission to a stress level lower than that required for intergranular fracture. Theoretical estimation suggests that carbides result in a much higher activation energy (∼510 kJ/mol) for GB sliding and a rather low interface energy (∼101 mJ/m2) compared with the GB energy (1000 mJ/m2), which rationalizes the enhanced GB cohesion by carbides.
晶界(GB)通常是合金在高温下的晶间开裂源,导致合金的高温强度和延展性受到限制。在此,我们提出了一种 GB 双碳化物(简称 GB-DC)强化策略,并开发出一种在 1073 K 下具有优异强度-韧性协同作用的高性能 (NiCoFeCr)99Nb0.5C0.5 高熵合金 (HEA)。在 GB 处成功引入了链状相干 M23C6 碳化物,并在变形过程中与面心立方(FCC)基体保持立方体平行晶体学取向。纳米级 NbC 粒子交替分布在 M23C6 碳化物之间,抑制了它们的粗化。与单相镍钴铁铬合金 HEA 相比,在 1073 K 条件下,GB-DC HEA 在应变速率为 10-4 到 10-2 s-1 时的强度和延展性都有显著提高。具体来说,屈服强度为 142 兆帕、极限拉伸强度为 283 兆帕,伸长率为 34%,分别是参考镍钴铁铬 HEA 的两倍(82 兆帕、172 兆帕和 18%)。EBSD 研究表明,链状碳化物在高温下增强了 GB 的内聚力,而 TEM 分析表明,位错可以穿过相干相界(CPB)并激活 M23C6 碳化物内部的偶极子,从而削弱了 GB 中的应力集中。这大大降低了位错产生和传递的临界应力,使其低于晶间断裂所需的应力水平。理论估算表明,与 GB 能量(1000 mJ/m2)相比,碳化物导致 GB 滑动的活化能(∼510 kJ/mol)高得多,而界面能(∼101 mJ/m2)却相当低,这说明碳化物增强了 GB 的内聚力。
{"title":"Concurrent dramatic enhancement of high-temperature strength and ductility in a high-entropy alloy via chain-like dual-carbides at grain boundaries","authors":"N. Gao, X.W. Liu, Z.H. Yin, Y.S. Wang, K. Wang, Y.F. Zhao, Z.M. Li","doi":"10.1016/j.jmst.2024.07.055","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.07.055","url":null,"abstract":"<p>Grain boundaries (GBs) are often known as intergranular cracking sources in alloys at high temperatures, resulting in limited high-temperature strength and ductility. Here, we propose a GB-dual-carbide (denoted as GB-DC) strengthening strategy and have developed a high-performance (NiCoFeCr)<sub>99</sub>Nb<sub>0.5</sub>C<sub>0.5</sub> high-entropy alloy (HEA) with exceptional strength-ductility synergy at 1073 K. Chain-like coherent M<sub>23</sub>C<sub>6</sub> carbides have been successfully introduced at GBs and remain a cube parallel crystallographic orientation with the face-centered cubic (FCC) matrix during deformation. Nano-scale NbC particles are distributed alternatively between M<sub>23</sub>C<sub>6</sub> carbides and inhibit their coarsening. Both strength and ductility of the GB-DC HEA increase dramatically at strain rates ranging from 10<sup>−4</sup> to 10<sup>−2</sup> s<sup>−1</sup> at 1073 K, compared with those of the single-phase NiCoFeCr HEA. Specifically, yield strength of 142 MPa, ultimate tensile strength of 283 MPa, and elongation of 34% were obtained, which are twice that of the reference NiCoFeCr HEA (82 MPa, 172 MPa, and 18%, respectively). EBSD investigations demonstrated that chain-like carbides enhance the GB cohesion at high temperature, and TEM analysis revealed that dislocations can go through the coherent phase boundaries (CPBs) and activate dipoles inner M<sub>23</sub>C<sub>6</sub> carbides, which weakened the stress concentration in GBs. This substantially reduces the critical stress for dislocation generation and transmission to a stress level lower than that required for intergranular fracture. Theoretical estimation suggests that carbides result in a much higher activation energy (∼510 kJ/mol) for GB sliding and a rather low interface energy (∼101 mJ/m<sup>2</sup>) compared with the GB energy (1000 mJ/m<sup>2</sup>), which rationalizes the enhanced GB cohesion by carbides.</p>","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142233530","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-09-14DOI: 10.1016/j.jmst.2024.08.046
C. Yang, B. Liu, L.L. Pan, Y. Yang, Y. Zhou, W.S. Cai, Le-hua. Liu
Texture formation is frequently observed in parts produced by Laser Powder Bed Fusion (L-PBF), which can induce anisotropy and may potentially degrade plasticity. In this study, we introduce a laser remelting strategy to mitigate these adverse effects. By employing experimental observations and numerical simulations, we established the relationship between melt pool thermal history, variant selection, and mechanical properties. Our results indicate that the strengthening of texture can be prevented by disrupting the variant selection memory effect when there is a difference in scanning speeds between the printing and remelting lasers. The achieved random variant orientation is attributed to the altered cooling rates and temperature gradient directions during solidification across different layers. The optimized Ti-6Al-4V alloy demonstrates high strength (1211.5 ± 13 MPa) and significant elongation (12.3% ± 0.8%), exhibiting a superior strength-ductility synergy compared to samples produced by direct printing or laser remelting with consistent parameters, as well as most reported L-PBF processed Ti-6Al-4V alloys. Our findings provide new insights into phase transformation kinetics in L-PBF of Ti-6Al-4V alloys and facilitate the optimization of this process for manufacturing high-performance components.
{"title":"Disrupting variant selection memory effect in laser powder bed fusion to improve strength-ductility synergy of Ti-6Al-4V alloys","authors":"C. Yang, B. Liu, L.L. Pan, Y. Yang, Y. Zhou, W.S. Cai, Le-hua. Liu","doi":"10.1016/j.jmst.2024.08.046","DOIUrl":"https://doi.org/10.1016/j.jmst.2024.08.046","url":null,"abstract":"<p>Texture formation is frequently observed in parts produced by Laser Powder Bed Fusion (L-PBF), which can induce anisotropy and may potentially degrade plasticity. In this study, we introduce a laser remelting strategy to mitigate these adverse effects. By employing experimental observations and numerical simulations, we established the relationship between melt pool thermal history, variant selection, and mechanical properties. Our results indicate that the strengthening of texture can be prevented by disrupting the variant selection memory effect when there is a difference in scanning speeds between the printing and remelting lasers. The achieved random variant orientation is attributed to the altered cooling rates and temperature gradient directions during solidification across different layers. The optimized Ti-6Al-4V alloy demonstrates high strength (1211.5 ± 13 MPa) and significant elongation (12.3% ± 0.8%), exhibiting a superior strength-ductility synergy compared to samples produced by direct printing or laser remelting with consistent parameters, as well as most reported L-PBF processed Ti-6Al-4V alloys. Our findings provide new insights into phase transformation kinetics in L-PBF of Ti-6Al-4V alloys and facilitate the optimization of this process for manufacturing high-performance components.</p>","PeriodicalId":16154,"journal":{"name":"Journal of Materials Science & Technology","volume":null,"pages":null},"PeriodicalIF":10.9,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142233547","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}