{"title":"Local and electronic structures of NaNbO3, AgNbO3, and KNbO3","authors":"Yasuhiro Yoneda, Tohru Kobayashi, Takuya Tsuji, Daiju Matsumura, Yuji Saitoh and Yuji Noguchi","doi":"10.35848/1347-4065/ad72fc","DOIUrl":null,"url":null,"abstract":"NaNbO3, AgNbO3, and KNbO3 with ABO3-type perovskite systems are known to possess good ferroelectric properties. In their traditional average structure, a change in the A-site ion size changes the involved tolerance factor. Herein, we directly determined the rattling space of each atom through local structure analysis. By combining a pair distribution function and an extended X-ray absorption fine structure, this analysis revealed that the bonding sites with large fluctuations varied with varying ion sizes. Experimental evidence including soft X-ray absorption spectroscopy, indicates that the A-site ions are hybridized with oxygen.","PeriodicalId":14741,"journal":{"name":"Japanese Journal of Applied Physics","volume":"3 1","pages":""},"PeriodicalIF":1.5000,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Japanese Journal of Applied Physics","FirstCategoryId":"101","ListUrlMain":"https://doi.org/10.35848/1347-4065/ad72fc","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"PHYSICS, APPLIED","Score":null,"Total":0}
引用次数: 0
Abstract
NaNbO3, AgNbO3, and KNbO3 with ABO3-type perovskite systems are known to possess good ferroelectric properties. In their traditional average structure, a change in the A-site ion size changes the involved tolerance factor. Herein, we directly determined the rattling space of each atom through local structure analysis. By combining a pair distribution function and an extended X-ray absorption fine structure, this analysis revealed that the bonding sites with large fluctuations varied with varying ion sizes. Experimental evidence including soft X-ray absorption spectroscopy, indicates that the A-site ions are hybridized with oxygen.
期刊介绍：
The Japanese Journal of Applied Physics (JJAP) is an international journal for the advancement and dissemination of knowledge in all fields of applied physics. JJAP is a sister journal of the Applied Physics Express (APEX) and is published by IOP Publishing Ltd on behalf of the Japan Society of Applied Physics (JSAP).
JJAP publishes articles that significantly contribute to the advancements in the applications of physical principles as well as in the understanding of physics in view of particular applications in mind. Subjects covered by JJAP include the following fields:
• Semiconductors, dielectrics, and organic materials
• Photonics, quantum electronics, optics, and spectroscopy
• Spintronics, superconductivity, and strongly correlated materials
• Device physics including quantum information processing
• Physics-based circuits and systems
• Nanoscale science and technology
• Crystal growth, surfaces, interfaces, thin films, and bulk materials
• Plasmas, applied atomic and molecular physics, and applied nuclear physics
• Device processing, fabrication and measurement technologies, and instrumentation
• Cross-disciplinary areas such as bioelectronics/photonics, biosensing, environmental/energy technologies, and MEMS
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