The Properties of Glass Fiber Reinforced Polypropylene Filaments Recycled from Fishing Gear

Garrett Russell
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Abstract

Plastic pollution, mainly from lost fishing gear composed of high-density polyethylene (HDPE) and polypropylene (PP), poses a significant environmental obstacle. This study evaluates the potential of recycling PP from fishnet/rope and reinforcing it with glass fiber (GF) in the form of 3D printer filaments as a way to reduce/prevent ocean plastic. Two materials, one virgin (vPP-GF) and one made up of recycled polypropylene and virgin glass fibers (rPP-GF), were analyzed using differential scanning calorimetry, tensile, and Charpy impact tests. From the results, it was found that rPP-GF often outperformed vPP-GF. rPP-GF had a higher melting and crystallization point, likely a higher crystallinity, and could withstand a higher tensile stress, while vPP-GF could withstand a higher tensile strain. Further analysis revealed the potential presence of HDPE within the rPP-GF composite, which was not reported by the manufacturer. This significantly affected the Charpy test and made it difficult to draw conclusions from the resulting data. Nevertheless, their comparability in terms of mechanical and material properties indicates the strong potential of recycling polypropylene fishnet/rope and reinforcing it with glass fibers to extend their lifespan and reduce ocean plastic.
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从渔具中回收的玻璃纤维增强聚丙烯纤维的特性
塑料污染主要来自由高密度聚乙烯(HDPE)和聚丙烯(PP)组成的遗失渔具,对环境造成了严重危害。本研究评估了从鱼网/绳索中回收聚丙烯,并用玻璃纤维(GF)以 3D 打印机丝的形式对其进行增强的潜力,以此减少/防止海洋塑料的产生。使用差示扫描量热仪、拉伸和夏比冲击试验分析了两种材料,一种是原生材料(vPP-GF),另一种是由回收聚丙烯和原生玻璃纤维组成的材料(rPP-GF)。结果发现,rPP-GF 的性能往往优于 vPP-GF。rPP-GF 的熔点和结晶点更高,结晶度可能更高,能承受更大的拉伸应力,而 vPP-GF 能承受更大的拉伸应变。进一步的分析表明,在 rPP-GF 复合材料中可能存在高密度聚乙烯(HDPE),但生产商并未报告。这严重影响了夏比试验,使我们难以从所得数据中得出结论。尽管如此,它们在机械和材料特性方面的可比性表明,回收聚丙烯鱼网/绳并用玻璃纤维进行增强以延长其使用寿命和减少海洋塑料的潜力巨大。
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