Ionic liquid-polymeric membranes for CO2 separation: A new perspective on membrane integrity under pressure

IF 2.7 3区 化学 Q2 POLYMER SCIENCE Journal of Applied Polymer Science Pub Date : 2024-09-12 DOI:10.1002/app.56273
Henrique Z. Ferrari, Bárbara Polesso, João Victor Gonzaga, Franciele Bernard, Guilherme Dias, Sandra Einloft
{"title":"Ionic liquid-polymeric membranes for CO2 separation: A new perspective on membrane integrity under pressure","authors":"Henrique Z. Ferrari,&nbsp;Bárbara Polesso,&nbsp;João Victor Gonzaga,&nbsp;Franciele Bernard,&nbsp;Guilherme Dias,&nbsp;Sandra Einloft","doi":"10.1002/app.56273","DOIUrl":null,"url":null,"abstract":"<p>Membrane-based CO<sub>2</sub> separation is a promising technology compared to traditional processes, presenting advantages such as superior energy efficiency and reduced operational costs. This study investigates the enhancement of CO₂/N₂ separation performance by incorporating ionic liquid [hmim][Tf₂N] into polysulfone membranes. The membranes were produced with 5, 10, and 20 wt% IL, and their permeability was measured at 25°C under pressures of 1 and 4 bar. Stability tests were also conducted. At 1 bar, the membrane with 20 wt% IL exhibited the highest CO₂ permeability of 342.27 Barrer, while the membrane with 5 wt% IL demonstrated the best ideal selectivity for CO₂/N₂ of 27.87. At 4 bar, the membrane with 5 wt% IL showed the highest ideal selectivity for CO₂/N₂ of 40.81, with a CO₂ permeability of 144.26 Barrer. Leaching tests indicated potential integrity loss in ionic liquid composite polymer membranes at high pressures. Specifically, the CO₂ permeability of the PSF-[hmim][Tf₂N] 5 wt% membrane increased continuously post-testing due to IL leaching. However, the performance of the membranes remained stable at lower pressures (1 bar). These findings suggest that the produced membranes achieve higher permeability, CO₂/N₂ selectivity, and CO₂ diffusivity, making them suitable for post-combustion gas separation applications.</p>","PeriodicalId":183,"journal":{"name":"Journal of Applied Polymer Science","volume":"141 47","pages":""},"PeriodicalIF":2.7000,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Applied Polymer Science","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/app.56273","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0

Abstract

Membrane-based CO2 separation is a promising technology compared to traditional processes, presenting advantages such as superior energy efficiency and reduced operational costs. This study investigates the enhancement of CO₂/N₂ separation performance by incorporating ionic liquid [hmim][Tf₂N] into polysulfone membranes. The membranes were produced with 5, 10, and 20 wt% IL, and their permeability was measured at 25°C under pressures of 1 and 4 bar. Stability tests were also conducted. At 1 bar, the membrane with 20 wt% IL exhibited the highest CO₂ permeability of 342.27 Barrer, while the membrane with 5 wt% IL demonstrated the best ideal selectivity for CO₂/N₂ of 27.87. At 4 bar, the membrane with 5 wt% IL showed the highest ideal selectivity for CO₂/N₂ of 40.81, with a CO₂ permeability of 144.26 Barrer. Leaching tests indicated potential integrity loss in ionic liquid composite polymer membranes at high pressures. Specifically, the CO₂ permeability of the PSF-[hmim][Tf₂N] 5 wt% membrane increased continuously post-testing due to IL leaching. However, the performance of the membranes remained stable at lower pressures (1 bar). These findings suggest that the produced membranes achieve higher permeability, CO₂/N₂ selectivity, and CO₂ diffusivity, making them suitable for post-combustion gas separation applications.

Abstract Image

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
用于二氧化碳分离的离子液体聚合物膜:压力下膜完整性的新视角
与传统工艺相比,基于膜的二氧化碳分离技术具有能源效率高、运行成本低等优点,是一项前景广阔的技术。本研究探讨了通过在聚砜膜中加入离子液体 [hmim][Tf₂N]来提高 CO₂/N₂ 的分离性能。这些膜的离子液体含量分别为 5、10 和 20 wt%,并在 25°C 和 1 和 4 bar 的压力下测量了它们的渗透性。同时还进行了稳定性测试。在 1 巴压力下,20 wt% IL 膜的 CO₂ 渗透率最高,达到 342.27 巴,而 5 wt% IL 膜对 CO₂/N₂ 的理想选择性最好,达到 27.87。在 4 巴压力下,5 wt% IL 膜对 CO₂/N₂ 的理想选择性最高,为 40.81,CO₂ 渗透率为 144.26 巴。浸出测试表明,离子液体复合聚合物膜在高压下可能会失去完整性。具体来说,由于 IL 的浸出,PSF-[hmim][Tf₂N] 5 wt%膜的 CO₂ 渗透率在测试后持续上升。然而,在较低的压力(1 巴)下,膜的性能保持稳定。这些研究结果表明,所生产的膜具有更高的渗透性、CO₂/N₂选择性和 CO₂ 扩散性,使其适用于燃烧后气体分离应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Journal of Applied Polymer Science
Journal of Applied Polymer Science 化学-高分子科学
CiteScore
5.70
自引率
10.00%
发文量
1280
审稿时长
2.7 months
期刊介绍: The Journal of Applied Polymer Science is the largest peer-reviewed publication in polymers, #3 by total citations, and features results with real-world impact on membranes, polysaccharides, and much more.
期刊最新文献
Editorial Board, Aims & Scope, Table of Contents Editorial Board, Aims & Scope, Table of Contents Editorial Board, Aims & Scope, Table of Contents Synthesis of reaction promoters for epoxy polymerization: Enhancing storage stability and mechanical properties of one-pot epoxy systems Editorial Board, Aims & Scope, Table of Contents
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1