Ionic liquid‐polymeric membranes for CO2 separation: A new perspective on membrane integrity under pressure

IF 2.7 3区 化学 Q2 POLYMER SCIENCE Journal of Applied Polymer Science Pub Date : 2024-09-13 DOI:10.1002/app.56273
Henrique Z. Ferrari, Bárbara Polesso, João Victor Gonzaga, Franciele Bernard, Guilherme Dias, Sandra Einloft
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Abstract

Membrane‐based CO2 separation is a promising technology compared to traditional processes, presenting advantages such as superior energy efficiency and reduced operational costs. This study investigates the enhancement of CO₂/N₂ separation performance by incorporating ionic liquid [hmim][Tf₂N] into polysulfone membranes. The membranes were produced with 5, 10, and 20 wt% IL, and their permeability was measured at 25°C under pressures of 1 and 4 bar. Stability tests were also conducted. At 1 bar, the membrane with 20 wt% IL exhibited the highest CO₂ permeability of 342.27 Barrer, while the membrane with 5 wt% IL demonstrated the best ideal selectivity for CO₂/N₂ of 27.87. At 4 bar, the membrane with 5 wt% IL showed the highest ideal selectivity for CO₂/N₂ of 40.81, with a CO₂ permeability of 144.26 Barrer. Leaching tests indicated potential integrity loss in ionic liquid composite polymer membranes at high pressures. Specifically, the CO₂ permeability of the PSF‐[hmim][Tf₂N] 5 wt% membrane increased continuously post‐testing due to IL leaching. However, the performance of the membranes remained stable at lower pressures (1 bar). These findings suggest that the produced membranes achieve higher permeability, CO₂/N₂ selectivity, and CO₂ diffusivity, making them suitable for post‐combustion gas separation applications.

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用于二氧化碳分离的离子液体聚合物膜:压力下膜完整性的新视角
与传统工艺相比,基于膜的二氧化碳分离技术具有能源效率高、运行成本低等优点,是一项前景广阔的技术。本研究探讨了通过在聚砜膜中加入离子液体 [hmim][Tf₂N]来提高 CO₂/N₂ 的分离性能。这些膜的离子液体含量分别为 5、10 和 20 wt%,并在 25°C 和 1 和 4 bar 的压力下测量了它们的渗透性。同时还进行了稳定性测试。在 1 巴压力下,20 wt% IL 膜的 CO₂ 渗透率最高,达到 342.27 巴,而 5 wt% IL 膜对 CO₂/N₂ 的理想选择性最好,达到 27.87。在 4 巴压力下,5 wt% IL 膜对 CO₂/N₂ 的理想选择性最高,为 40.81,CO₂ 渗透率为 144.26 巴。浸出测试表明,离子液体复合聚合物膜在高压下可能会失去完整性。具体来说,由于 IL 的浸出,PSF-[hmim][Tf₂N] 5 wt%膜的 CO₂ 渗透率在测试后持续上升。然而,在较低的压力(1 巴)下,膜的性能保持稳定。这些研究结果表明,所生产的膜具有更高的渗透性、CO₂/N₂选择性和 CO₂ 扩散性,使其适用于燃烧后气体分离应用。
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来源期刊
Journal of Applied Polymer Science
Journal of Applied Polymer Science 化学-高分子科学
CiteScore
5.70
自引率
10.00%
发文量
1280
审稿时长
2.7 months
期刊介绍: The Journal of Applied Polymer Science is the largest peer-reviewed publication in polymers, #3 by total citations, and features results with real-world impact on membranes, polysaccharides, and much more.
期刊最新文献
Editorial Board, Aims & Scope, Table of Contents Editorial Board, Aims & Scope, Table of Contents Editorial Board, Aims & Scope, Table of Contents Editorial Board, Aims & Scope, Table of Contents Cover Image, Volume 141, Issue 43
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