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Synthesis of reaction promoters for epoxy polymerization: Enhancing storage stability and mechanical properties of one-pot epoxy systems 环氧聚合反应促进剂的合成:提高一锅环氧体系的储存稳定性和机械性能
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-10-22 DOI: 10.1002/app.56265
Da Young Lee, Hye-Jin Kim, Hyeon-Gook Kim, Meysam Tayebi, Jong-Hyun Kim, Seoyoon Yu, Ildoo Chung, Choong-Sun Lim, Bongkuk Seo

One-pot epoxy formulations, containing uncured resin, curing agent, and promoter, require the promoter to be insoluble in the resin at room temperature to prevent premature polymerization. Here, we introduce three novel reaction promoters synthesized by reacting amino propyl imidazole (API) and various diisocyanates such as HMDI, IPDI, or MDI. We evaluate the impact of these promoters on the physical properties, storage stability, and curing kinetics of the resulting epoxy formulations. The results of the kinetic study showed that the compositions containing each synthesized promoter acted as reaction promoters, as evidenced by the lower activation energy in the differential scanning calorimetry (DSC) experiment. The results of the mechanical properties showed that HMDI-API promoter improved both tensile and flexural strength, while exhibiting high storage stability. The findings provide valuable insights for selecting suitable promoters for specific applications in one-pot epoxy systems.

含有未固化树脂、固化剂和促进剂的单锅环氧配方要求促进剂在室温下不溶于树脂,以防止过早聚合。在此,我们介绍了通过氨基丙基咪唑(API)和各种二异氰酸酯(如 HMDI、IPDI 或 MDI)反应合成的三种新型反应促进剂。我们评估了这些促进剂对所得环氧配方的物理性质、储存稳定性和固化动力学的影响。动力学研究结果表明,含有每种合成促进剂的组合物都起到了反应促进剂的作用,这从差示扫描量热仪(DSC)实验中较低的活化能可以得到证明。机械性能结果表明,HMDI-API 促进剂提高了拉伸和弯曲强度,同时表现出较高的储存稳定性。这些发现为在一锅环氧体系中选择适合特定应用的促进剂提供了宝贵的见解。
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引用次数: 0
Correction to “Investigating the changing dynamics of processing, temperature-based mechanics, and flame retardancy in the transfer of ammonium polyphosphate/inorganic silicate flame retardants from epoxy resins to glass fiber composites” 更正 "研究从环氧树脂向玻璃纤维复合材料转移聚磷酸铵/无机硅酸盐阻燃剂过程中的加工、温度力学和阻燃性的动态变化"
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-10-18 DOI: 10.1002/app.56329

S. Sunder, M. Jauregui Rozo, S. Inasu, B. Schartel, H. Ruckdäschel, J. Appl. Polym. Sci. 2024, 141(39), e55988. https://doi.org/10.1002/app.55988 .

We apologize for this error.

S.Sunder, M. Jauregui Rozo, S. Inasu, B. Schartel, H. Ruckdäschel, J. Appl.2024, 141(39), e55988. https://doi.org/10.1002/app.55988 .我们对此错误表示歉意。
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引用次数: 0
Design of a bio-based flame-retardant epoxy/amine cross-linked coatings 设计生物基阻燃环氧/胺交联涂料
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-27 DOI: 10.1002/app.56279
Siavash Mansouri, Raj Shankar Hazra, Shanti Swarup, Mohiuddin Quadir

Epoxy cross-linked coatings are widely used to protect and beautify many surfaces all around us. However, these coatings possess a dense carbonaceous structure, rendering them susceptible to ignition, spread, and propagation of flames. Therefore, flame-retardant (FR) materials are added into these coatings as additives to improve flame resistance properties. Many of the commercially available FR additives are halogenated, metal oxide, and alkyl phosphate-based compounds, often originating from nonrenewable resources. Some of these compounds produce undesirable toxic fumes and byproducts upon combustion. To overcome these challenges, we tested bio-based phytic acid (PA) as an FR additive in epoxy resin, cross-linked with bio-based phenalkamine (NX)—a material derived from cashew oil nutshell. Our findings demonstrate that the incorporation of PA into an NX-cross-linked epoxy coating system significantly enhances the FR properties of the coatings while preserving their physico-mechanical characteristics such as solvent resistance and hardness. Additionally, the inclusion of PA markedly enhances the FR performance of the coatings by reducing flame spread rate, minimizing dripping, and suppressing ignition temperature. Moreover, upon addition of 10% w/w PA increases the ignition time, decreases peak heat release rate (PHRR) by more than 25%, reduces total heat release (THR) by the similar amount, and suppresses total smoke production by >40% compared to the coatings containing FR- agents based on metal oxides and alkyl phosphates. Our work clearly demonstrates the feasibility of using PA as the FR additive for producing eco-friendly and low-flammable epoxy cross-linked coatings.

环氧交联涂料被广泛用于保护和美化我们周围的许多表面。然而,这些涂料具有致密的碳质结构,容易被火焰点燃、蔓延和传播。因此,阻燃(FR)材料作为添加剂被添加到这些涂料中,以提高阻燃性能。许多市售的阻燃添加剂都是卤化、金属氧化物和烷基磷酸盐基化合物,通常来自不可再生资源。其中一些化合物在燃烧时会产生不良的有毒烟雾和副产品。为了克服这些挑战,我们测试了将生物基植酸(PA)作为环氧树脂的阻燃添加剂,并与生物基酚醛胺(NX)--一种从腰果壳中提取的材料--交联。我们的研究结果表明,在 NX 交联环氧树脂涂料体系中加入 PA 能显著提高涂料的阻燃性能,同时保持涂料的物理机械特性,如耐溶剂性和硬度。此外,加入 PA 还能降低火焰蔓延率、减少滴落和抑制点火温度,从而显著提高涂料的阻燃性能。此外,与含有基于金属氧化物和烷基磷酸盐的阻燃剂的涂料相比,添加 10% w/w PA 可延长点火时间,降低 25% 以上的峰值热释放率(PHRR),减少相同数量的总热释放率(THR),并将总烟雾产生量抑制 40%。我们的工作清楚地证明了使用 PA 作为阻燃添加剂生产环保型低易燃环氧交联涂料的可行性。
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引用次数: 0
Novel black TiO2-MIP cartridge for the selective and enhanced removal of NSAIDs under LED light irradiation 新型黑色 TiO2-MIP 筒,用于在 LED 光照射下选择性地增强去除非甾体抗炎药的能力
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-26 DOI: 10.1002/app.56292
Asma Aliyari, Mohammad Rafiee, Bahareh Heidari, Roya Sedghi, Akbar Eslami, Mansour Sarafraz

A multi-template molecularly imprinted photocatalyst based on Black TiO2 was used for selective and simultaneous adsorption and degradation of Non-steroidal anti-inflammatory drugs (NSAIDs) under LED irradiation from aqueous solutions. diclofenac (DCF) and ibuprofen (IBP) were chosen as the target chemicals and the performance of the Black TiO2-MIP nanocomposite in removing these pollutants was investigated. The imprinting procedure was confirmed by characterization tests of the nanocomposite. The synthesized mesoporous nanocomposite exhibited excellent fit with the pseudo-second-order kinetic model (R2 ≥ 0.99). Moreover the experimental data demonstrated a good fit with the Langmuir isotherm model (R2 = 0.99). The findings imply that the binding sites are homogeneous and indicate monolayer chemical adsorption on the adsorbent. Toxicity assessment of targeted chemicals and their by-products, worked out using the Ecological Structure–Activity Relationships (ECOSAR) program, revealed a significant decrease in the toxicity of the target compounds during photocatalytic degradation. In addition, the use of Black TiO2-MIP nanocomposite in the cartridge structure led to notable removal efficiencies, 98.7% and 97.6% for DCF and IBP, respectively. The findings also provided evidence that the use of Black TiO2-MIP in the cartridge structure not only facilitated the removal of target pollutants but also addressed challenges related to the collection and separation of the nanocomposite from the aqueous solution. The results implied that the integration of molecular imprinting and photocatalysis processes exhibits high effectiveness in the simultaneous and selective removal of contaminants. This approach holds promise as an effective solution for addressing the challenge of drug residues in aqueous samples.

选择双氯芬酸 (DCF) 和布洛芬 (IBP) 作为目标化学物质,研究了黑色 TiO2-MIP 纳米复合材料去除这些污染物的性能。纳米复合材料的表征测试证实了压印过程。合成的介孔纳米复合材料与伪二阶动力学模型(R2 ≥ 0.99)非常吻合。此外,实验数据与 Langmuir 等温线模型(R2 = 0.99)也非常吻合。研究结果表明,吸附剂上的结合位点是均匀的,表明吸附剂上存在单层化学吸附。利用生态结构-活性关系(ECOSAR)程序对目标化学品及其副产品进行的毒性评估显示,在光催化降解过程中,目标化合物的毒性显著降低。此外,在筒式结构中使用 Black TiO2-MIP 纳米复合材料还能显著提高去除率,对 DCF 和 IBP 的去除率分别为 98.7% 和 97.6%。研究结果还证明,在滤芯结构中使用 Black TiO2-MIP 不仅有助于去除目标污染物,还解决了纳米复合材料从水溶液中收集和分离的难题。研究结果表明,分子印迹和光催化过程的整合在同时选择性去除污染物方面具有很高的效率。这种方法有望成为应对水样中药物残留挑战的有效解决方案。
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引用次数: 0
Dual drug co-encapsulation of bevacizumab and pemetrexed clocked polymeric nanoparticles improves antiproliferative activity and apoptosis induction in liver cancer cells 贝伐珠单抗和培美曲塞双药共包合的时钟聚合物纳米颗粒提高了肝癌细胞的抗增殖活性和凋亡诱导能力
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-25 DOI: 10.1002/app.56262
Subbulakshmi Ganesan, Vijay J. Upadhye, Damanjeet Aulakh, Sunita Bishnoi, Arunachalam Chinnathambi, Tahani Awad Alahmadi, Suha Mujahed Abudoleh, Palanisamy Arulselvan, Indumathi Thangavelu

Nanoparticle (NP) enabled approaches have been employed for chemotherapeutic administration due to their capacity to regulate drug release and reduce side effects. Additionally, these methods can use several drugs concurrently and impede the proliferation of cancer cells that have developed resistance. Bevacizumab (BVZ) and pemetrexed (PEM) have demonstrated encouraging outcomes in the treatment and management of cancer. This work investigates the combined antiproliferative efficacy of BVZ and PEM co-loaded PLGA-PEG NPs (BVZ/PEM@PLGA-PEG NPs) against HepG2 liver cancerous cells. The BVZ/PEM@PLGA-PEG exhibited a sphere-shaped and consistent nanosized distribution. In addition, we evaluated the potential mechanisms for inhibiting cell growth and inducing apoptosis using DAPI staining and cell cycle study. The beneficial combined antiproliferative activity and the apoptosis pathway were detected in the HepG2 cells exposed to BVZ/PEM@PLGA-PEG NPs. Our study determined that the combinational drug treatment of BVZ/PEM@PLGA-PEG NPs has a significant effect on promoting the effectiveness of liver cancer treatment.

由于纳米粒子(NP)具有调节药物释放和减少副作用的能力,因此已被用于化疗给药。此外,这些方法还能同时使用多种药物,并抑制产生抗药性的癌细胞的增殖。贝伐单抗(BVZ)和培美曲塞(PEM)在癌症治疗和管理方面取得了令人鼓舞的成果。本研究探讨了 BVZ 和 PEM 共负载 PLGA-PEG NPs(BVZ/PEM@PLGA-PEG NPs)对 HepG2 肝癌细胞的联合抗增殖功效。BVZ/PEM@PLGA-PEG呈现出球形和一致的纳米级分布。此外,我们还利用 DAPI 染色和细胞周期研究评估了抑制细胞生长和诱导细胞凋亡的潜在机制。在暴露于 BVZ/PEM@PLGA-PEG NPs 的 HepG2 细胞中检测到了有益的联合抗增殖活性和凋亡途径。我们的研究确定,BVZ/PEM@PLGA-PEG NPs 的联合药物治疗对促进肝癌治疗效果具有显著作用。
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引用次数: 0
Sustainable preparation of nano monodispered ATP based color master batch and its application in PA6 基于 ATP 的纳米单二色色母的可持续制备及其在 PA6 中的应用
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-25 DOI: 10.1002/app.56297
Bo He, Jianuo Ma, Luobing Xiang, Han Wang, Xi Wang, Chunwang Yi

As a representative of dope-dye, the color masterbatch method has been widely applied in modern dyeing processes, while it has difficulties in solving the dispersibility of inorganic pigments color master batch in the polymer matrix. In this work, attapulgite (ATP) was used as the adsorption carrier of inorganic pigments to prepare color-dyed attapulgite (CD-ATP). The selected environmentally friendly inorganic pigments were well adsorbed by ATP in KOH aqueous solution, and could stably be monodispersed in KOH aqueous solution for more than 168 h. Moreover, the KOH aqueous solution could be reused repeatedly, thereby, a sustainable method to prepare novel CD-ATP was realized. By blending the as-prepared CD-ATP with polyamide-6 (PA6), a series of dope-dyed colorful PA6 composites was prepared. Scanning electron microscope (SEM) results indicated that the CD-ATP was still monodispersed in the PA6 matrix, and endowed PA6 with a vivid color. Further studies show that the adding of CD-ATP had little influence on the properties of PA6, but significantly reduced the water adsorption. This novel color-dyed ATP has potential implications in making paper-making blankets and is highly expected to have more extensive applications in many fields of life.

色母粒法作为掺杂染料的代表,在现代染色工艺中得到了广泛应用,但它在解决无机颜料色母粒在聚合物基体中的分散性方面存在困难。本研究以阿塔蓬石(ATP)作为无机颜料的吸附载体,制备了色母染色阿塔蓬石(CD-ATP)。所选的环保型无机颜料在KOH水溶液中被ATP很好地吸附,并能在KOH水溶液中稳定地单分散168小时以上,而且KOH水溶液可以重复使用,从而实现了一种可持续的新型CD-ATP制备方法。通过将制备的 CD-ATP 与聚酰胺-6(PA6)混合,制备出了一系列掺杂染色的彩色 PA6 复合材料。扫描电子显微镜(SEM)结果表明,CD-ATP 仍然单分散在 PA6 基体中,并赋予 PA6 鲜艳的色彩。进一步的研究表明,CD-ATP 的加入对 PA6 的性能影响不大,但能显著降低吸水性。这种新型染色 ATP 在造纸毯方面具有潜在的意义,并有望在生活的许多领域得到更广泛的应用。
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引用次数: 0
Integrating the in vitro antioxidant activity of polyacrylonitrile/polyindole composites 整合聚丙烯腈/聚吲哚复合材料的体外抗氧化活性
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-24 DOI: 10.1002/app.56290
Naci Ömer Alayunt, Cengiz Soykan

In this study, five compounds belonging to the Polymer composites (PCs) family, have been prepared with different amounts of polyacrylonitrile and polyindole in the composite. The PCs have inherently bactericidal activity, owing to the nitrile and indole groups. Antioxidant activity was assessed by using reducing power activity, superoxide radical scavenging activity and hydroxyl radical scavenging activity. In our study, butylated hydroxy toluene (BHT), ascorbic acid and α-tocopherol, which are considered synthetic standard antioxidants, were used to compare antioxidant activity. In addition, since it is known that the MDA levels resulting from the oxidation of fats in Saccharomyces cerevisiae yeast cells are inversely proportional to the antioxidant properties, it gave an idea about the in vitro antioxidant properties of the new synthesized PCs. Reducing force capacity, superoxide radical scavenging activity and hydroxyl radical scavenging activity were found to be higher at 100 μg mL−1 concentration compared to 50 μg mL−1 concentration.

本研究制备了五种属于聚合物复合材料(PCs)家族的化合物,复合材料中含有不同量的聚丙烯腈和聚吲哚。由于含有腈基和吲哚基,这些 PC 本身就具有杀菌活性。抗氧化活性通过还原力活性、超氧自由基清除活性和羟自由基清除活性进行评估。在我们的研究中,使用了被认为是合成标准抗氧化剂的丁基羟基甲苯(BHT)、抗坏血酸和α-生育酚来比较抗氧化活性。此外,众所周知,脂肪在酿酒酵母细胞中氧化产生的 MDA 含量与抗氧化性成反比,因此可以了解新合成 PCs 的体外抗氧化性。与 50 μg mL-1 浓度相比,100 μg mL-1 浓度下的还原力、超氧自由基清除活性和羟自由基清除活性更高。
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引用次数: 0
Catalyst-free epoxy resins with high-performance and excellent healing efficiency via interpenetrating networks 通过互穿网络实现高性能和卓越愈合效率的无催化剂环氧树脂
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-24 DOI: 10.1002/app.56286
Chenxin Li, Zhengyong Huang, Senyuan Yang, Yingfan Zhang, Chaofan Wang, Jian Li

The difficult recycling and degradation in cured epoxy resins can be solved by introducing dynamic covalent bonds. However, the introduction of dynamic bonds degrades the properties of epoxy resins. In this paper, the dual-cured epoxy resin with high mechanical properties and high healing efficiency were obtained by constructing interpenetrating networks (IPNs). The effect of IPNs on the recyclability of epoxy resins was investigated. The performance is as follows, the flexural and tensile strengths is 89 and 54.2 MPa, respectively, and the breakdown strength is 32.5 kV/mm. In addition, the recyclability and high healing efficiency of the dual-cured epoxy resin were verified, and the effect of the hot-pressing temperature and time on the properties of the recycled samples were investigated. Under certain hot-pressing conditions, the flexural and tensile strengths of the recycled samples were recovered to 95.06% and 85.28%, respectively, and the breakdown strength was recovered to 83.6%.

固化环氧树脂难以回收和降解的问题可以通过引入动态共价键来解决。然而,动态键的引入会降低环氧树脂的性能。本文通过构建互穿网络(IPN),获得了具有高机械性能和高愈合效率的双固化环氧树脂。研究了 IPN 对环氧树脂可回收性的影响。其性能如下:弯曲强度和拉伸强度分别为 89 和 54.2 兆帕,击穿强度为 32.5 千伏/毫米。此外,还验证了双固化环氧树脂的可回收性和高愈合效率,并研究了热压温度和时间对回收样品性能的影响。在一定的热压条件下,回收样品的抗弯强度和拉伸强度分别恢复到 95.06% 和 85.28%,击穿强度恢复到 83.6%。
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引用次数: 0
High rate capability and ultra-long cycling life: Electrochemical synthesis of PEDOT based electrode material doped with AMPS and its supercapacitor application 高倍率能力和超长循环寿命:掺杂 AMPS 的 PEDOT 基电极材料的电化学合成及其超级电容器应用
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-23 DOI: 10.1002/app.56298
Sibel Yazar, Sıla Melahat Yilmaz, Gülten Atun

Poly(3,4-ethylene dioxythiophene) (PEDOT) is a conducting polymer that can be used in flexible bioelectronic devices. The electrode/electrolyte interface interaction is one of the most important factors in improving the electrochemical performance of energy storage materials, and these polymers are often combined with a negatively charged poly(styrene sulfonate) (PSS) chain to improve their interaction with alkali metal cations such as sodium and potassium. In this work, we performed a one-step electrochemical synthesis of PEDOT on carbon fabric using the molecule 2-acrylamido-2-methyl-1-propane sulfonic acid (AMPS) to create highly effective materials for supercapacitor electrodes. The electrode had a significant increase in capacitance value, measured 16.4 times higher than that of the PEDOT electrode. The 2-electrode system exhibited a specific capacitance value of 495.2 F g−1 at a scan rate of 5 mV s−1. It exhibited a high operating voltage of 2.3 V in aqueous electrolyte system. It showed a significant energy density of 109.0 Wh kg−1 when operating at 6.1 kW kg−1 power density and 85.2 Wh kg−1 when operating at 30.6 kW kg−1 power density. Recent findings reveal that the capacitance retention performance value of the device increased significantly to 113.9% after 25,000 cycles in 3.0 M NaCl aqueous electrolyte, demonstrating its outstanding long-term durability. Thus, the creation of the synthesized supercapacitor electrode is a significant advance in the study of conducting polymers, which often have a limited lifetime in real-world electronic applications.

聚(3,4-乙烯二氧噻吩)(PEDOT)是一种导电聚合物,可用于柔性生物电子器件。电极/电解质界面相互作用是改善储能材料电化学性能的最重要因素之一,这些聚合物通常与带负电荷的聚(苯乙烯磺酸盐)(PSS)链相结合,以改善它们与钠、钾等碱金属阳离子的相互作用。在这项工作中,我们利用分子 2-丙烯酰胺基-2-甲基-1-丙烷磺酸(AMPS)一步电化学合成了碳织物上的 PEDOT,从而制造出了用于超级电容器电极的高效材料。该电极的电容值显著增加,测量值是 PEDOT 电极的 16.4 倍。在 5 mV s-1 的扫描速率下,双电极系统的比电容值为 495.2 F g-1。它在水性电解质系统中的工作电压高达 2.3 V。当以 6.1 kW kg-1 功率密度工作时,它的能量密度高达 109.0 Wh kg-1;当以 30.6 kW kg-1 功率密度工作时,能量密度高达 85.2 Wh kg-1。最近的研究结果表明,在 3.0 M NaCl 水电解液中循环 25,000 次后,该器件的电容保持性能值显著增加到 113.9%,显示出其出色的长期耐用性。因此,合成超级电容器电极是导电聚合物研究领域的一项重大进展,而在实际电子应用中,导电聚合物的使用寿命通常是有限的。
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引用次数: 0
Tailoring thin film composite membranes for enhanced removal of heavy metals from water 定制薄膜复合膜,提高去除水中重金属的能力
IF 2.7 3区 化学 Q2 POLYMER SCIENCE Pub Date : 2024-09-21 DOI: 10.1002/app.56295
Tooba Sahar, Rahma Tamime, Muhammad Usman, Hamad AlMohamadi, R. Nawaz, Tanzila Anjum, Asim Laeeq Khan

In response to the pressing need for effective removal of heavy metals from water sources, this study focuses on the optimization of Thin Film Composite nanofiltration membranes, known for their porous polymer support and selective ultrathin layers. The objective was to enhance the rejection of heavy metal ions, a critical issue in water treatment. The parameters of the interfacial polymerization (IP) process, including monomer concentration, reaction time, curing temperature, and curing duration, were tailored to determine the most effective membrane configuration. Polyimide (P84) was employed as the support material, with the IP involving trimesoyl chloride (TMC) and piperazine (PIP). Comprehensive characterization through Fourier Transform Infrared (FTIR) spectroscopy, Scanning Electron Microscopy (SEM), and water contact angle measurements provided information on the functional groups, surface and cross-sectional morphologies, and hydrophilic properties of the membranes. The optimized fabrication conditions, involving 0.2 w/v% TMC and 2.0 w/v% PIP monomer concentrations, a 2-minute IP reaction time, and a 40°C curing temperature for 10 minutes, led to the membranes achieving arsenic and chromium rejections of 89.7% and 99%, respectively. This was accomplished while maintaining a high pure water permeability of approximately 16.9 Lm−2h−1bar−1. These promising results highlight the potential of these optimized nanofiltration membranes for industrial applications, addressing a critical environmental challenge.

为满足有效去除水源中重金属的迫切需求,本研究重点关注薄膜复合纳滤膜的优化,该膜以其多孔聚合物支撑和选择性超薄层而闻名。目的是提高重金属离子的去除率,这是水处理中的一个关键问题。界面聚合(IP)工艺的参数,包括单体浓度、反应时间、固化温度和固化持续时间,都经过了定制,以确定最有效的膜配置。聚酰亚胺(P84)被用作支撑材料,IP 涉及三甲基甲酰氯(TMC)和哌嗪(PIP)。通过傅立叶变换红外光谱(FTIR)、扫描电子显微镜(SEM)和水接触角测量进行的综合表征提供了有关膜的官能团、表面和横截面形态以及亲水性能的信息。优化的制造条件包括 0.2 w/v% 的 TMC 和 2.0 w/v% 的 PIP 单体浓度、2 分钟的 IP 反应时间和 10 分钟的 40°C 固化温度,使膜的砷和铬去除率分别达到 89.7% 和 99%。同时还保持了约 16.9 Lm-2h-1bar-1 的高纯水渗透率。这些充满希望的结果凸显了这些优化纳滤膜在工业应用中的潜力,解决了一个关键的环境挑战。
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引用次数: 0
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