High Performance MXene/MnCo2O4 Supercapacitor Device for Powering Small Robotics

IF 5.4 3区 材料科学 Q2 CHEMISTRY, PHYSICAL ACS Applied Energy Materials Pub Date : 2024-09-18 DOI:10.1021/acsaelm.4c01204
Nanasaheb M. Shinde, Martin Pumera
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Abstract

The development of advanced energy storage devices is critical for various applications including robotics and portable electronics. The energy storage field faces significant challenges in designing devices that can operate effectively for extended periods while maintaining exceptional electrochemical performance. Supercapacitors, which bridge the gap between batteries and conventional capacitors, offer a promising solution due to their high power density and rapid charge–discharge capabilities. This study focuses on the fabrication and evaluation of a MXene/MnCo2O4 nanocomposite supercapacitor electrode using a simple and cost-effective electrodeposition method on a copper substrate. The MXene/MnCo2O4 nanocomposite exhibits superior electrochemical properties, including a specific capacitance of 668 F g–1, high energy density (35 Wh kg–1), and excellent cycling stability (94.6% retention over 5000 cycles). The combination of MXene and MnCo2O4 enhances the redox activity, electronic conductivity, and structural integrity of the electrode. An asymmetric supercapacitor device, incorporating MXene/MnCo2O4 as the positive electrode and Bi2O3 as the negative electrode, demonstrates remarkable performance in powering small robotics and small electronics. This work underscores the potential of MXene-based nanocomposites for high-performance supercapacitor applications, paving the way for future advancements in energy storage technologies.

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为小型机器人供电的高性能 MXene/MnCo2O4 超级电容器装置
先进储能设备的开发对于包括机器人和便携式电子产品在内的各种应用至关重要。在设计既能长时间有效运行又能保持优异电化学性能的设备方面,储能领域面临着巨大挑战。超级电容器在电池和传统电容器之间架起了一座桥梁,由于其功率密度高、充放电速度快,因此是一种很有前途的解决方案。本研究的重点是在铜基底上采用简单、经济高效的电沉积方法制造和评估 MXene/MnCo2O4 纳米复合超级电容器电极。MXene/MnCo2O4 纳米复合材料具有优异的电化学性能,包括 668 F g-1的比电容、高能量密度(35 Wh kg-1)和出色的循环稳定性(5000 次循环后保持率为 94.6%)。MXene 和 MnCo2O4 的结合增强了电极的氧化还原活性、电子导电性和结构完整性。以 MXene/MnCo2O4 为正极、Bi2O3 为负极的不对称超级电容器器件在为小型机器人和小型电子设备供电方面表现出了卓越的性能。这项研究强调了基于 MXene 的纳米复合材料在高性能超级电容器应用方面的潜力,为未来储能技术的发展铺平了道路。
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来源期刊
ACS Applied Energy Materials
ACS Applied Energy Materials Materials Science-Materials Chemistry
CiteScore
10.30
自引率
6.20%
发文量
1368
期刊介绍: ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.
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