Comparison of the Effects of Stirring and Standing on Chemical Reactions

IF 1.7 4区 化学 Q3 CHEMISTRY, ORGANIC Synlett Pub Date : 2024-09-18 DOI:10.1055/a-2384-7220
Xianting Huang, Jianyou Zhao, Qingxu Wang, Pengkai Fang, Wei Xie, Meng Chen, Hongliang Han, Lanlan Zhang, Jiatai Zhang, Fan Wang, Zhong-Quan Liu
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Abstract

For hundreds of years, it seems that people have needed stirring to conduct chemical experiments. This operation can be seen everywhere in chemical, pharmaceutical, and materials laboratories and factories. People generally believe that stirring helps with processes such as material dispersion, dissolution, and collision, thereby enabling more-efficient reactions. However, why do chemical reactions that occur in Nature not require stirring? What are the facts? For this purpose, we investigated a total of 329 organic chemical reactions in eight categories and 25 types, including 26 chemical reactions magnified to gram or even kilogram levels. Under the same conditions of temperature, humidity, pressure, and reaction time, we compared the reaction yields under stirring and standing conditions. More than 600 results showed that stirring or not stirring had almost no effect on the efficiency of chemical reactions in solution. If most chemists performing reactions turned off the agitator, it would not be difficult to imagine how much electricity could be saved!

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搅拌和静置对化学反应影响的比较
数百年来,人们似乎一直需要搅拌来进行化学实验。在化学、制药、材料实验室和工厂中,这种操作随处可见。人们普遍认为,搅拌有助于物质的分散、溶解和碰撞等过程,从而提高反应效率。然而,为什么自然界中发生的化学反应不需要搅拌呢?事实究竟如何?为此,我们调查了 8 类 25 种共 329 个有机化学反应,其中包括 26 个放大到克级甚至公斤级的化学反应。在相同的温度、湿度、压力和反应时间条件下,我们比较了搅拌和静置条件下的反应产率。600 多项结果表明,搅拌与否对溶液中化学反应的效率几乎没有影响。如果大多数进行反应的化学家关闭搅拌器,不难想象可以节省多少电力!
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来源期刊
Synlett
Synlett 化学-有机化学
CiteScore
3.40
自引率
5.00%
发文量
369
审稿时长
1 months
期刊介绍: SYNLETT is an international journal reporting research results and current trends in chemical synthesis in short personalized reviews and preliminary communications. It covers all fields of scientific endeavor that involve organic synthesis, including catalysis, organometallic, medicinal, biological, and photochemistry, but also related disciplines and offers the possibility to publish scientific primary data.
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