Hydro-Thermal Degradation: A New and Rapid Method for Evaluating the Bio-degradation Performance of Poly(lactic acid)

IF 1 4区 化学 Q4 POLYMER SCIENCE Polymer Science, Series B Pub Date : 2024-09-13 DOI:10.1134/S156009042460089X
Qiang Peng, Rongqiu Li, Sijie Yin, Qiaolin Tang, Rong Sun, Guanjun Chang, Ming Kang
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Abstract

In order to evaluate the bio-degradation performance of different kinds of poly(lactic acid) (PLA) rapidly, a new method, called hydro-thermal degradation was developed. Four kinds of commercial grade PLA were analyzed by both bio-degradation and hydro-thermal degradation with their degradation performance investigated via weight loss (%), infrared spectra (IR), size-exclusion chromatography (SEC), and X‑ray diffraction measurements (XRD). The experimental results showed that the bio-degradation performance, which would take several years to degrade totally, could degrade in a short time (2 h) at 170°C by the hydro-thermal degradation. The order of the degradation rate is Revode101 > Revode210 > Revode190 > Revode290, corresponding with the structure characteristics of them. Thus, this new method provides a simple and effective way to degrade the PLA rapidly and to evaluate its bio-degradation performance.

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水热降解:评估聚(乳酸)生物降解性能的新型快速方法
摘要 为了快速评估不同种类聚乳酸(PLA)的生物降解性能,开发了一种称为水热降解的新方法。通过生物降解和水热降解两种方法对四种商业级聚乳酸进行了分析,并通过失重(%)、红外光谱(IR)、尺寸排阻色谱(SEC)和 X 射线衍射测量(XRD)对其降解性能进行了研究。实验结果表明,生物降解性能需要数年才能完全降解,而通过水热降解,在 170°C 温度下,短时间内(2 小时)就能降解。降解速率的顺序为 Revode101 > Revode210 > Revode190 > Revode290,与它们的结构特征相对应。因此,这种新方法为快速降解聚乳酸并评估其生物降解性能提供了一种简单有效的途径。
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来源期刊
Polymer Science, Series B
Polymer Science, Series B 化学-高分子科学
CiteScore
1.80
自引率
8.30%
发文量
58
审稿时长
>0 weeks
期刊介绍: Polymer Science, Series B is a journal published in collaboration with the Russian Academy of Sciences. Series B experimental and theoretical papers and reviews dealing with the synthesis, kinetics, catalysis, and chemical transformations of macromolecules, supramolecular structures, and polymer matrix-based composites (6 issues a year). All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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