{"title":"Synthesis of new polycyclic adducts based on perhydrotetraazatetracene","authors":"E. B. Rakhimova, V. Yu. Kirsanov","doi":"10.1007/s11172-024-4353-0","DOIUrl":null,"url":null,"abstract":"<p>New <i>N,N</i>′-disubstituted perhydrohexaazadibenzo[<i>fg,op</i>]tetracenes with the (<i>R*,R*,R*,R*</i>) configuration of the chiral centers were synthesized by a one-pot catalytic heterocyclization of perhydrotetraazatetracene with formaldehyde and various primary amines as well as by the catalytic recyclization reaction of 1,3,5-trisubstituted 1,3,5-triazinanes with perhydrotetraazatetracene. The structures of all synthesized compounds were confirmed by NMR spectroscopy and high-resolution mass spectrometry.</p>","PeriodicalId":756,"journal":{"name":"Russian Chemical Bulletin","volume":null,"pages":null},"PeriodicalIF":1.7000,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Chemical Bulletin","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s11172-024-4353-0","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
New N,N′-disubstituted perhydrohexaazadibenzo[fg,op]tetracenes with the (R*,R*,R*,R*) configuration of the chiral centers were synthesized by a one-pot catalytic heterocyclization of perhydrotetraazatetracene with formaldehyde and various primary amines as well as by the catalytic recyclization reaction of 1,3,5-trisubstituted 1,3,5-triazinanes with perhydrotetraazatetracene. The structures of all synthesized compounds were confirmed by NMR spectroscopy and high-resolution mass spectrometry.
期刊介绍：
Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections:
General and Inorganic Chemistry;
Physical Chemistry;
Organic Chemistry;
Organometallic Chemistry;
Chemistry of Natural Compounds and Bioorganic Chemistry.
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