Advanced absorption-storage water molecules strategy reinforces antifouling property for stable oil/water emulsions separation

Abstract

Constructing membranes with extraordinary resistance to oil contamination under high permeation flux is a considerable challenge. Herein, an advanced absorption-storage water molecules strategy is proposed for constructing the robust hydration layers to achieve effective anti-oil fouling and stable oily wastewater purification. Specifically, metal–organic framework (MOF, UiO-66-NH₂) nanoparticles with powerful water-absorbing characteristics are preferentially adsorbed to collect water in oil/surfactant/water systems. Combining excellent water retention, the micro-/ nano-networks formed by attapulgite (APT) could store the water molecules captured by MOF. The synergistic effect of the water-absorbing/water-retaining interactions between the MOF and APT created robust hydration layers defense barriers, which enhanced the resistance of membrane to oil contamination. Furthermore, the abundant hydrophilic groups (e.g., –OH, –NH₂ and –CONH₂) of chitosan (CS) further improved the membrane surface hydrophilic coverage, permeability and hydration ability. As a result, the developed CS/APT@MOF composite membrane exhibited significant anti-oil fouling capability and realized superior purification property towards various oil-in-water emulsions stabilized by surfactants. The CS/APT@MOF composite membrane demonstrated outstanding oil repellency (flux recovery ratio > 99.6 %, total flux decline ratio < 3.8 %) over 10 cycles under large permeability (>660 L m^-2h⁻¹ bar⁻¹). Meanwhile, the constructed CS/APT@MOF composite membrane exhibited stable separation cycle capability (10 cycles) and continuous purification performance (60 min) for different oil/water emulsions. Therefore, this advanced strategy based on absorption-storage water molecules to construct robust hydration layers provides a promising insight for the development of superior antifouling and operationally stable oil/water emulsions separation membranes.