{"title":"Metal ion-driven formation of 2H-silolides and -germolides†‡","authors":"Chenghuan Liu , Marc Schmidtmann , Thomas Müller","doi":"10.1039/d4cc03984j","DOIUrl":null,"url":null,"abstract":"<div><div>The synthesis of potassio-1<em>H</em>-silolides and -germolides substituted with an amidinate-stabilized silylene is reported. Both anions undergo a thermal rearrangement to the 2<em>H</em>-isomer yielding cyclic sila- and germavinyl anions. The reaction is driven by complex formation with metal ions.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"60 80","pages":"Pages 11295-11298"},"PeriodicalIF":4.2000,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/cc/d4cc03984j?page=search","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1359734524018986","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/8/30 0:00:00","PubModel":"Epub","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The synthesis of potassio-1H-silolides and -germolides substituted with an amidinate-stabilized silylene is reported. Both anions undergo a thermal rearrangement to the 2H-isomer yielding cyclic sila- and germavinyl anions. The reaction is driven by complex formation with metal ions.
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