High-temperature resistant SnSe/MSN film for thermal runaway prevention in lithium-ion batteries

Abstract

Recent years have witnessed an accelerated development of electric vehicles (EVs) driven by the pressing need to curb carbon emissions. Lithium-ion batteries (LIBs) stand out as preferred energy storage solutions owing to their high energy density and extended cycle life. Nonetheless, the persistent threat of thermal runaway (TR) remains a critical safety concern. This study endeavors to tackle this issue by introducing a novel composite insulating film tailored to function as a thermal barrier within LIBs. Comprising exfoliated SnSe (tin selenide) and mesoporous silica bonded via Zn ion gelation, the composite showcases a low thermal conductivity of 0.131 W/mK alongside a robust tensile strength of 52.7 MPa. These attributes stem from the distinctive amalgamation of materials and the robust interfacial interactions facilitated by Zn ion gelation, thus enhancing thermal stability and mechanical resilience. The devised DGEBA/SnSe-MSN composite exhibits notable flame retardant properties and superior thermal management capabilities, positioning it as a promising candidate to bolster the safety and dependability of LIBs. This research introduces a promising approach for crafting high-performance insulating films applicable across diverse industries, particularly in the realm of lithium-ion battery technology, leveraging SnSe as an insulating material—a departure from its prior application as a thermoelectric material.