Porosity and permeability optimization of PEMFC cathode gas diffusion layer based on topology algorithm

IF 1.3 4区 化学 Q4 ELECTROCHEMISTRY International Journal of Electrochemical Science Pub Date : 2024-09-18 DOI:10.1016/j.ijoes.2024.100803
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Abstract

The gas diffusion layer (GDL) is a crucial component in proton exchange membrane fuel cells (PEMFCs), significantly affecting mass transport and overall cell performance. Due to the pronounced pressure gradients and uneven mass transfer between the inlet and outlet of the serpentine flow field, this study proposes the design of a GDL with a concentration gradient to optimize performance. Leveraging topological optimization algorithms, the research focuses on enhancing the mass transport properties and improving cell efficiency. The optimization process considers the pressure distribution, oxygen concentration, and water content within the serpentine flow field as boundary conditions. By optimizing the porosity and permeability of the GDL in different regions, the study aims to enhance the GDL's mass transport capabilities. Simulation results demonstrate that initializing the porosity at 1 provides superior optimization, significantly enhancing mass transfer and overall cell performance. Although increased permeability contributes to improved mass transport, its impact is less significant compared to porosity optimization. Therefore, GDL porosity is identified as the dominant factor in enhancing cell performance, while permeability adjustments play a secondary role.
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基于拓扑算法优化 PEMFC 阴极气体扩散层的孔隙率和渗透率
气体扩散层(GDL)是质子交换膜燃料电池(PEMFC)中的关键部件,对质量传输和电池整体性能有重大影响。由于蛇形流场的入口和出口之间存在明显的压力梯度和不均匀的质量传输,本研究提出设计具有浓度梯度的 GDL,以优化性能。利用拓扑优化算法,研究重点是增强质量传输特性和提高电池效率。优化过程将蛇形流场中的压力分布、氧气浓度和含水量作为边界条件。通过优化 GDL 不同区域的孔隙率和渗透率,该研究旨在增强 GDL 的质量传输能力。仿真结果表明,将孔隙率初始化为 1 的优化效果更佳,可显著提高质量传输和电池的整体性能。虽然增加渗透率有助于改善质量传输,但与孔隙率优化相比,其影响并不显著。因此,GDL 孔隙率被认为是提高电池性能的主要因素,而渗透性调整则起次要作用。
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来源期刊
CiteScore
3.00
自引率
20.00%
发文量
714
审稿时长
2.6 months
期刊介绍: International Journal of Electrochemical Science is a peer-reviewed, open access journal that publishes original research articles, short communications as well as review articles in all areas of electrochemistry: Scope - Theoretical and Computational Electrochemistry - Processes on Electrodes - Electroanalytical Chemistry and Sensor Science - Corrosion - Electrochemical Energy Conversion and Storage - Electrochemical Engineering - Coatings - Electrochemical Synthesis - Bioelectrochemistry - Molecular Electrochemistry
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