2,3-Bis(2-pyridyl)thieno[3,4-b]pyrazine and its ruthenium(ii) complexes: a new bidentate bridging ligand for enhanced metal–metal communication†

IF 4.3 3区 材料科学 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC ACS Applied Electronic Materials Pub Date : 2024-09-27 DOI:10.1039/D4DT02495H
Kristine L. Konkol, Wyatt D. Wilcox and Seth C. Rasmussen
{"title":"2,3-Bis(2-pyridyl)thieno[3,4-b]pyrazine and its ruthenium(ii) complexes: a new bidentate bridging ligand for enhanced metal–metal communication†","authors":"Kristine L. Konkol, Wyatt D. Wilcox and Seth C. Rasmussen","doi":"10.1039/D4DT02495H","DOIUrl":null,"url":null,"abstract":"<p >A new bidentate bridging ligand, bis(2-pyridyl)thieno[3,4-<em>b</em>]pyrazine is reported, along with its mono- and bi-metallic Ru(<small>II</small>) complexes as representative examples. Spectroscopic, electrochemical and X-ray crystallographic characterization of these species is reported, with the separation of the two Ru(<small>III</small>)/Ru(<small>II</small>) couples of the bimetallic complex suggesting better metal–metal communication than classical polypyridyl analogues.</p>","PeriodicalId":3,"journal":{"name":"ACS Applied Electronic Materials","volume":null,"pages":null},"PeriodicalIF":4.3000,"publicationDate":"2024-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2024/dt/d4dt02495h?page=search","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Electronic Materials","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/dt/d4dt02495h","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ELECTRICAL & ELECTRONIC","Score":null,"Total":0}
引用次数: 0

Abstract

A new bidentate bridging ligand, bis(2-pyridyl)thieno[3,4-b]pyrazine is reported, along with its mono- and bi-metallic Ru(II) complexes as representative examples. Spectroscopic, electrochemical and X-ray crystallographic characterization of these species is reported, with the separation of the two Ru(III)/Ru(II) couples of the bimetallic complex suggesting better metal–metal communication than classical polypyridyl analogues.

Abstract Image

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
2,3-双(2-吡啶基)噻吩并[3,4-b]吡嗪及其钌(II)配合物:一种用于增强金属间通讯的新型双齿桥接配体
报告了一种新的双齿桥接配体--双(2-吡啶基)噻吩并[3,4-b]吡嗪,并以其单金属和双金属 Ru(II) 复合物为代表。报告对这些物质进行了光谱、电化学和 X 射线晶体学表征,双金属配合物的两个 Ru(III)/Ru(II) 偶联物的分离表明,金属与金属之间的交流比传统的多吡啶类似物更好。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
CiteScore
7.20
自引率
4.30%
发文量
567
期刊最新文献
Vitamin B12: prevention of human beings from lethal diseases and its food application. Current status and obstacles of narrowing yield gaps of four major crops. Cold shock treatment alleviates pitting in sweet cherry fruit by enhancing antioxidant enzymes activity and regulating membrane lipid metabolism. Removal of proteins and lipids affects structure, in vitro digestion and physicochemical properties of rice flour modified by heat-moisture treatment. Investigating the impact of climate variables on the organic honey yield in Turkey using XGBoost machine learning.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1