Dissociative electron attachment and Ar+ reaction with chromium hexacarbonyl, 296-400 K.

IF 3.1 2区化学 Q3 CHEMISTRY, PHYSICAL Journal of Chemical Physics Pub Date : 2024-09-28 DOI:10.1063/5.0232322

Thomas M Miller, Virginia G Rodriguez, Shaun G Ard, Albert A Viggiano, Nicholas S Shuman

引用次数: 0

Abstract

Dissociative electron attachment rate constants have been measured for Cr(CO)6 under thermal conditions, 296-400 K, yielding Cr(CO)5- product. At 296 K, 2.92 ± 0.70 cm3 s-1 was measured and a small decrease with temperature was observed (2.72 ± 0.70 cm3 s-1 at 400 K). We additionally determined the cation products of Ar+ reacting with Cr(CO)6.

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离解电子附着和 Ar+与六羰基铬的反应，296-400 K。

在 296-400 K 的热条件下测量了 Cr(CO)6 产生 Cr(CO)5- 产物的分离电子附着速率常数。在 296 K 时，测量值为 2.92 ± 0.70 cm3 s-1，随着温度的升高，测量值略有下降（400 K 时为 2.72 ± 0.70 cm3 s-1）。我们还测定了 Ar+ 与 Cr(CO)6 反应的阳离子产物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Chemical Physics 物理-物理：原子、分子和化学物理

CiteScore

7.40

自引率

15.90%

发文量

1615

审稿时长

2 months

期刊介绍： The Journal of Chemical Physics publishes quantitative and rigorous science of long-lasting value in methods and applications of chemical physics. The Journal also publishes brief Communications of significant new findings, Perspectives on the latest advances in the field, and Special Topic issues. The Journal focuses on innovative research in experimental and theoretical areas of chemical physics, including spectroscopy, dynamics, kinetics, statistical mechanics, and quantum mechanics. In addition, topical areas such as polymers, soft matter, materials, surfaces/interfaces, and systems of biological relevance are of increasing importance. Topical coverage includes: Theoretical Methods and Algorithms Advanced Experimental Techniques Atoms, Molecules, and Clusters Liquids, Glasses, and Crystals Surfaces, Interfaces, and Materials Polymers and Soft Matter Biological Molecules and Networks.